**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-64-1 |Acetone | 75 | 200-662-2 |
|----------------|--------------------------------------|----------|-----------|
| 538-75-0 |N,N'-Dicyclohexylcarbodiimide | 25 | 208-704-1 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T F
Risk Phrases: 11 22 24 41 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Toxic in contact with skin.
Risk of serious damage to eyes. May cause sensitization by skin
contact.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Toxic in contact with
skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause central nervous system depression, kidney damage, and liver
damage.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Do
not store in direct sunlight. Store in a tightly closed container.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 67-64-1:
United Kingdom, WEL - TWA: 500 ppm TWA; 1210 mg/m3 TWA
United Kingdom, WEL - STEL: 1500 ppm STEL; 3620 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 2400 mg/m3 TWA
Belgium - TWA: 500 ppm VLE; 1210 mg/m3 VLE
Belgium - STEL: 1000 ppm VLE; 2420 mg/m3 VLE
France - VME: 750 ppm VME; 1800 mg/m3 VME
Germany: 500 ppm TWA; 1200 mg/m3 TWA
Japan: 200 ppm OEL; 470 mg/m3 OEL
Malaysia: 500 ppm TWA; 1187 mg/m3 TWA
Netherlands: 750 ppm MAC; 1780 mg/m3 MAC
Russia: 200 mg/m3 TWA
Spain: 500 ppm VLA-ED; 1210 mg/m3 VLA-ED
CAS# 538-75-0:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -20 deg C ( -4.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H22N2
Molecular Weight: 206.1674
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-64-1: AL3150000
CAS# 538-75-0: FF2160000
LD50/LC50:
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test,
rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H
Moderate; Draize test, rabbit, eye: 10 uL Mild; Draize test, rabbit,
skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H;
Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg;
Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
CAS# 538-75-0: Dermal, guinea pig: LD50 = 10 mL/kg; Inhalation, rat:
LC50 = 159 mg/m3/6H; Oral, mouse: LD50 = >800 mg/kg; Oral, rat: LD50
= 400 mg/kg.
Carcinogenicity:
Acetone -
Not listed by ACGIH, IARC, or NTP.
N,N'-Dicyclohexylcarbodiimide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-64-1: 0
CAS# 538-75-0: 2
Canada
CAS# 67-64-1 is listed on Canada's DSL List.
CAS# 538-75-0 is listed on Canada's DSL List.
CAS# 67-64-1 is listed on Canada's Ingredient Disclosure List.
CAS# 538-75-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-64-1 is listed on the TSCA inventory.
CAS# 538-75-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 4/07/2000 Revision #1 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Dichloromethane, extra dry, with molecular sieve, water < 50 ppm
| 75-09-2 |
|
Potassium Carbonate Sesquihydrate
| 584-08-7 |
|
Urazole, 97%
| 3229-73-0 |
|
(4S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
| 17016-83-0 |
|
DL-5-Hydroxytryptophan, 99%
| 114-03-4 |
|
(4R)-(+)-4-Isopropyl-2-Oxazolidinone, 98%
| 95530-58-8 |
|
Ethyl 4-etoxybenzoate, 97%
| 23676-09-7 |
|
2,2,4-Trimethyl-1,3-pentanediol, 96% (gc)
| 144-19-4 |
|
Phenylmercuric nitrate, 62.5 - 64.0% Mercury
| 8003-05-2 |
|
Toluidine Blue O
| 92-31-9 |
|
Bentonite
| 1302-78-9 |
|
Nitrilotris(Methylene)Triphosphonic Acid 50 wt% Solution in Water
| 6419-19-8 |
|
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride
| 72287-26-4 |
|
1,3-Dimethylcyclohexane, mixture of cis and trans, 90%
| 591-21-9 |
|
3-(Dimethylamino)acrylonitrile
| 2407-68-3 |
|
Adenine, 99%
| 73-24-5 |
|
2,4-Dimethyl-2,6-heptadien-1-ol, mixture of isomers, 96%
| 80192-56-9 |
|
Cyclopropyl [4-(1,1-Dimethylethyl)Phenyl]- Methanone
| 38675-79-5 |
|
2,6-Dithiopurine
| 5437-25-2 |
|
N-Carbobenzyloxy-L-isoleucine, 97%
| 3160-59-6 |
|
4,4'-Dichlorobenzhydrol
| 90-97-1 |
|
1-Aminobenzotriazole, 98%
| 1614-12-6 |
|
Succinimide, 98%
| 123-56-8 |
|
N,N'-Dicyclohexylcarbodiimide, 25% solution in acetone
| 67-64-1 |
|
Cyclopropylamine, 80% solution in water, special grade for Novartis
| 765-30-0 |
|
4-Methylcatechol, 95%
| 452-86-8 |
|
N-(2-Hydroxyethyl)ethylenediaminetriacetic acid trisodium salt
| 139-89-9 |
|
Gallocyanine, chloride free
| 524-26-5 |
|
tert.-Butyl methyl sulfide, 97%
| 6163-64-0 |
|
5-Methylquinoxaline, 98%
| 13708-12-8 |
|
2-Methyl-3-propylpyrazine, 97%
| 15986-80-8 |
|
3-Acetyl-2,5-Dimethylfuran, 98%
| 10599-70-9 |
|
(s,s)-chiraphos, 97%
| 64896-28-2 |
|
cis-4-Hydroxy-D-proline, 99%
| 2584-71-6 |
|
Benzene
| 71-43-2 |
|
Tetraethylthiuram disulfide, 97%
| 97-77-8 |
|
1,2-Bis(trimethylsilyloxy)cyclobutene
| 17082-61-0 |
|
6-Hydroxy-2-naphthoic acid
| 16712-64-4 |
|
4-Hydroxypyridine
| 626-64-2 |
|
2,4,6-Trifluorobenzoyl chloride
| 79538-29-7 |
|
2,3,5,6-Tetrafluorobenzoyl chloride, 98%
| 107535-73-9 |
|
2,3-Dihydroxypyridine, 98%
| 16867-04-2 |
|
2,3,4,5-Tetrafluorobenzaldehyde
| 0-01-1 |
|
2,3,4-Trifluorobenzoyl chloride
| 157373-08-5 |
|
2,3,5,6-Tetrafluorobenzaldehyde
| 19842-76-3 |
|
2,3,5,6-Tetrafluorobenzoic acid
| 652-18-6 |
|
4-Bromo-2-fluorobenzoic acid
| 164149-28-4 |
|
2-Chloro-4-fluorobenzoic acid
| 2252-51-9 |
|
3-Mercapto-1-hexanol, 98%
| 51755-83-0 |
|
2-Isopropyl-4-methylthiazole, 99%
| 15679-13-7 |
|
|