**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 97-77-8 |Tetraethylthiuram disulfide | 97.0 | 202-607-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 97-77-8:
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 2 mg/m3 TWA (inhalable fraction)
Malaysia: 2 mg/m3 TWA
Netherlands: 1 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 2 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder and Pellets
Color: off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 71.00 - 72.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: chloroform
Specific Gravity/Density:
Molecular Formula: C10H20N2S4
Molecular Weight: 296.51
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 97-77-8: JO1225000
LD50/LC50:
CAS# 97-77-8: Draize test, rabbit, eye: 100 mg Mild; Oral, mouse:
LD50 = 1.013 mg/kg; Oral, rabbit: LD50 = 1800 mg/kg; Oral, rat: LD50
= 500 mg/kg.
orl-man LDLo:150 mg/kg
Carcinogenicity:
Tetraethylthiuram disulfide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 97-77-8: 2
Canada
CAS# 97-77-8 is listed on Canada's DSL List.
CAS# 97-77-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 97-77-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichloromethane, extra dry, with molecular sieve, water < 50 ppm
| 75-09-2 |
|
Potassium Carbonate Sesquihydrate
| 584-08-7 |
|
Urazole, 97%
| 3229-73-0 |
|
(4S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
| 17016-83-0 |
|
DL-5-Hydroxytryptophan, 99%
| 114-03-4 |
|
(4R)-(+)-4-Isopropyl-2-Oxazolidinone, 98%
| 95530-58-8 |
|
Ethyl 4-etoxybenzoate, 97%
| 23676-09-7 |
|
2,2,4-Trimethyl-1,3-pentanediol, 96% (gc)
| 144-19-4 |
|
Phenylmercuric nitrate, 62.5 - 64.0% Mercury
| 8003-05-2 |
|
Toluidine Blue O
| 92-31-9 |
|
Bentonite
| 1302-78-9 |
|
Nitrilotris(Methylene)Triphosphonic Acid 50 wt% Solution in Water
| 6419-19-8 |
|
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride
| 72287-26-4 |
|
1,3-Dimethylcyclohexane, mixture of cis and trans, 90%
| 591-21-9 |
|
3-(Dimethylamino)acrylonitrile
| 2407-68-3 |
|
Adenine, 99%
| 73-24-5 |
|
2,4-Dimethyl-2,6-heptadien-1-ol, mixture of isomers, 96%
| 80192-56-9 |
|
Cyclopropyl [4-(1,1-Dimethylethyl)Phenyl]- Methanone
| 38675-79-5 |
|
2,6-Dithiopurine
| 5437-25-2 |
|
N-Carbobenzyloxy-L-isoleucine, 97%
| 3160-59-6 |
|
4,4'-Dichlorobenzhydrol
| 90-97-1 |
|
1-Aminobenzotriazole, 98%
| 1614-12-6 |
|
Succinimide, 98%
| 123-56-8 |
|
N,N'-Dicyclohexylcarbodiimide, 25% solution in acetone
| 67-64-1 |
|
Cyclopropylamine, 80% solution in water, special grade for Novartis
| 765-30-0 |
|
4-Methylcatechol, 95%
| 452-86-8 |
|
N-(2-Hydroxyethyl)ethylenediaminetriacetic acid trisodium salt
| 139-89-9 |
|
Gallocyanine, chloride free
| 524-26-5 |
|
tert.-Butyl methyl sulfide, 97%
| 6163-64-0 |
|
5-Methylquinoxaline, 98%
| 13708-12-8 |
|
2-Methyl-3-propylpyrazine, 97%
| 15986-80-8 |
|
3-Acetyl-2,5-Dimethylfuran, 98%
| 10599-70-9 |
|
(s,s)-chiraphos, 97%
| 64896-28-2 |
|
cis-4-Hydroxy-D-proline, 99%
| 2584-71-6 |
|
Benzene
| 71-43-2 |
|
Tetraethylthiuram disulfide, 97%
| 97-77-8 |
|
1,2-Bis(trimethylsilyloxy)cyclobutene
| 17082-61-0 |
|
6-Hydroxy-2-naphthoic acid
| 16712-64-4 |
|
4-Hydroxypyridine
| 626-64-2 |
|
2,4,6-Trifluorobenzoyl chloride
| 79538-29-7 |
|
2,3,5,6-Tetrafluorobenzoyl chloride, 98%
| 107535-73-9 |
|
2,3-Dihydroxypyridine, 98%
| 16867-04-2 |
|
2,3,4,5-Tetrafluorobenzaldehyde
| 0-01-1 |
|
2,3,4-Trifluorobenzoyl chloride
| 157373-08-5 |
|
2,3,5,6-Tetrafluorobenzaldehyde
| 19842-76-3 |
|
2,3,5,6-Tetrafluorobenzoic acid
| 652-18-6 |
|
4-Bromo-2-fluorobenzoic acid
| 164149-28-4 |
|
2-Chloro-4-fluorobenzoic acid
| 2252-51-9 |
|
3-Mercapto-1-hexanol, 98%
| 51755-83-0 |
|
2-Isopropyl-4-methylthiazole, 99%
| 15679-13-7 |
|
|