**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 6419-19-8 |Nitrilotris(Methylene)Triphosphonic Ac| 50% | 229-146-5 |
| |id | | |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 50% | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause cardiac disturbances. May cause central nervous
system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. May cause central
nervous system effects including vertigo, anxiety, depression,
muscle incoordination, and emotional instability. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated. Non-combustible,
substance itself does not burn but may decompose upon heating to
produce irritating, corrosive and/or toxic fumes. Runoff from fire
control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is
noncombustible; use agent most appropriate to extinguish surrounding
fire. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Exposure Limits
CAS# 6419-19-8:
Russia: 2 mg/m3 TWA
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3000g/cm3
Molecular Formula: N??CH2P(O)(OH)2!3
Molecular Weight: 299.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6419-19-8: SZ9860000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 6419-19-8: Draize test, rabbit, eye: 100 mg Moderate; Draize
test, rabbit, skin: 500 mg/24H; Oral, rat: LD50 = 2100 mg/kg; Skin,
rabbit: LD50 = >6310 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Nitrilotris(Methylene)Triphosphonic Acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6419-19-8: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 6419-19-8 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 6419-19-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6419-19-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichloromethane, extra dry, with molecular sieve, water < 50 ppm
| 75-09-2 |
|
Potassium Carbonate Sesquihydrate
| 584-08-7 |
|
Urazole, 97%
| 3229-73-0 |
|
(4S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
| 17016-83-0 |
|
DL-5-Hydroxytryptophan, 99%
| 114-03-4 |
|
(4R)-(+)-4-Isopropyl-2-Oxazolidinone, 98%
| 95530-58-8 |
|
Ethyl 4-etoxybenzoate, 97%
| 23676-09-7 |
|
2,2,4-Trimethyl-1,3-pentanediol, 96% (gc)
| 144-19-4 |
|
Phenylmercuric nitrate, 62.5 - 64.0% Mercury
| 8003-05-2 |
|
Toluidine Blue O
| 92-31-9 |
|
Bentonite
| 1302-78-9 |
|
Nitrilotris(Methylene)Triphosphonic Acid 50 wt% Solution in Water
| 6419-19-8 |
|
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride
| 72287-26-4 |
|
1,3-Dimethylcyclohexane, mixture of cis and trans, 90%
| 591-21-9 |
|
3-(Dimethylamino)acrylonitrile
| 2407-68-3 |
|
Adenine, 99%
| 73-24-5 |
|
2,4-Dimethyl-2,6-heptadien-1-ol, mixture of isomers, 96%
| 80192-56-9 |
|
Cyclopropyl [4-(1,1-Dimethylethyl)Phenyl]- Methanone
| 38675-79-5 |
|
2,6-Dithiopurine
| 5437-25-2 |
|
N-Carbobenzyloxy-L-isoleucine, 97%
| 3160-59-6 |
|
4,4'-Dichlorobenzhydrol
| 90-97-1 |
|
1-Aminobenzotriazole, 98%
| 1614-12-6 |
|
Succinimide, 98%
| 123-56-8 |
|
N,N'-Dicyclohexylcarbodiimide, 25% solution in acetone
| 67-64-1 |
|
Cyclopropylamine, 80% solution in water, special grade for Novartis
| 765-30-0 |
|
4-Methylcatechol, 95%
| 452-86-8 |
|
N-(2-Hydroxyethyl)ethylenediaminetriacetic acid trisodium salt
| 139-89-9 |
|
Gallocyanine, chloride free
| 524-26-5 |
|
tert.-Butyl methyl sulfide, 97%
| 6163-64-0 |
|
5-Methylquinoxaline, 98%
| 13708-12-8 |
|
2-Methyl-3-propylpyrazine, 97%
| 15986-80-8 |
|
3-Acetyl-2,5-Dimethylfuran, 98%
| 10599-70-9 |
|
(s,s)-chiraphos, 97%
| 64896-28-2 |
|
cis-4-Hydroxy-D-proline, 99%
| 2584-71-6 |
|
Benzene
| 71-43-2 |
|
Tetraethylthiuram disulfide, 97%
| 97-77-8 |
|
1,2-Bis(trimethylsilyloxy)cyclobutene
| 17082-61-0 |
|
6-Hydroxy-2-naphthoic acid
| 16712-64-4 |
|
4-Hydroxypyridine
| 626-64-2 |
|
2,4,6-Trifluorobenzoyl chloride
| 79538-29-7 |
|
2,3,5,6-Tetrafluorobenzoyl chloride, 98%
| 107535-73-9 |
|
2,3-Dihydroxypyridine, 98%
| 16867-04-2 |
|
2,3,4,5-Tetrafluorobenzaldehyde
| 0-01-1 |
|
2,3,4-Trifluorobenzoyl chloride
| 157373-08-5 |
|
2,3,5,6-Tetrafluorobenzaldehyde
| 19842-76-3 |
|
2,3,5,6-Tetrafluorobenzoic acid
| 652-18-6 |
|
4-Bromo-2-fluorobenzoic acid
| 164149-28-4 |
|
2-Chloro-4-fluorobenzoic acid
| 2252-51-9 |
|
3-Mercapto-1-hexanol, 98%
| 51755-83-0 |
|
2-Isopropyl-4-methylthiazole, 99%
| 15679-13-7 |
|
|