**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16588-74-2 |3,5-Bis(trifluoromethyl)phenyl isocyan| 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found. Lachrymator (substance which increases the flow of
tears).
Skin:
No information regarding skin irritation and other potential effects
was found. Organic isocyanates can cause local irritation and
allergic reactions.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. At high concentrations, isocyanates affect mucous
membranes of the respiratory tract and may lead to fatal pulmonary
edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back.
Combustible liquid.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 16588-74-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 62 deg C @ 2 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4700 g/cm3
Molecular Formula: C9H3F6NO
Molecular Weight: 255.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Moisture.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 16588-74-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,5-Bis(trifluoromethyl)phenyl isocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 16588-74-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16588-74-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16588-74-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/13/1998 Revision #3 Date: 7/22/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Amino-1-Naphthol Hydrochloride, Tech. 90%
| 5959-56-8 |
|
2,6-Diisopropylphenyl Isocyanate, 98%
| 28178-42-9 |
|
3-Bromophenyl isocyanate, 97%
| 23138-55-8 |
|
3,5-Dichlorophenyl Isocyanate, 96%
| 34893-92-0 |
|
4-Fluoro-3-Nitrophenyl Isocyanate, 98%
| 65303-82-4 |
|
3,5-Dimethylphenyl isocyanate, 99%
| 54132-75-1 |
|
3,5-Bis(trifluoromethyl)phenyl isocyanate, 98%
| 16588-74-2 |
|
3-Cyanophenyl Isocyanate, 97%
| 16413-26-6 |
|
4-(Methylthio)phenyl Isocyanate, 97%
| 1632-84-4 |
|
n-Propyl nitrate, 97%
| 627-13-4 |
|
Gallic Acid Ethyl Ester, 99%
| 831-61-8 |
|
2-Ethylphenyl Isocyanate, 99%
| 40411-25-4 |
|
2,6-Dimethylphenyl isocyanate, 99%
| 28556-81-2 |
|
Alpha, Alpha, Alpha-Trifluoro-p-Tolyl Isocyanate, 99%
| 1548-13-6 |
|
1-Cyanothioformanilide, 97%
| 4955-82-2 |
|
1-Cyano-N-methylthioformamide, 95%
| 13621-47-1 |
|
Tert-Octyl Isothiocyanate, 94%
| 17701-76-7 |
|
2,3-Dichlorophenyl isocyanate, 97%
| 41195-90-8 |
|
2-Chloro-6-Methylphenyl Isocyanate, 97%
| 40398-01-4 |
|
4-Methyl-3-Nitrophenyl Isocyanate, 98%
| 13471-69-7 |
|
Benzoyl isocyanate, tech., 90%
| 4461-33-0 |
|
2,4-Dimethoxyphenyl Isocyanate, 97%
| 84370-87-6 |
|
Chloroacetyl isocyanate
| 4461-30-7 |
|
Ethoxycarbonyl Isocyanate, Tech., 90%
| 19617-43-7 |
|
Pentyl Isocyanate, 98%
| 3954-13-0 |
|
Hexadecyl isocyanate, 97%
| 1943-84-6 |
|
Heptyl Isocyanate, 97%
| 4747-81-3 |
|
4-(Chloromethyl)Phenyl Isocyanate, 97%
| 29173-65-7 |
|
1-Adamantyl isocyanate, 98%
| 4411-25-0 |
|
1-Chloromethyl-2,4-Diisocyanatobenzene, 98%
| 51979-57-8 |
|
1,4-Diisocyanatobutane, 97%
| 4538-37-8 |
|
trans-1,4-Cyclohexane diisocyanate, 97%
| 7517-76-2 |
|
1,8-Diisocyanatooctane, 98%
| 10124-86-4 |
|
1,12-Diisocyanatododecane, 97%
| 13879-35-1 |
|
4-Isocyanaobenzoyl Chloride, 98%
| 3729-21-3 |
|
3-(Chloromethyl)Benzoyl Chloride, 98%
| 63024-77-1 |
|
4-(Chloromethyl)Benzoyl Chloride, 97%
| 876-08-4 |
|
3-(Dichloromethyl)benzoyl Chloride, 96%
| 36747-51-0 |
|
1-Chloroethyl Chloroformate, 99%
| 50893-53-3 |
|
1-Chloro-2-Methylpropyl Chloroformate, 98%
| 92600-11-8 |
|
(+/-)-1,2,2,2-Tetrachloroethyl chloroformate, 98%
| 98015-53-3 |
|
4-Chlorobutyl chloroformate, 97%
| 37693-18-8 |
|
Triethylene glycol bis(chloroformate), 97%
| 17134-17-7 |
|
(+)-Menthyl chloroformate
| 7635-54-3 |
|
Diisopropylcarbamoyl Chloride, 98%
| 19009-39-3 |
|
Ethylphosphonic dichloride, 98%
| 1066-50-8 |
|
Butylphosphonic Dichloride, 98%
| 2302-80-9 |
|
Octyl chloroformate, 97%
| 7452-59-7 |
|
P-Tolyl Chloroformate, 97%
| 937-62-2 |
|
4-Methoxyphenyl Chloroformate, 98%
| 7693-41-6 |
|
|