**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 92600-11-8 |1-Chloro-2-Methylpropyl Chloroformate | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 20/21/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Causes burns.Moisture sensitive.Corrosive.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Use water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Avoid ingestion and inhalation. Do not allow
contact with water. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Keep under a nitrogen blanket. Store in a cool,
dry, well-ventilated area away from incompatible substances.
Flammables-area. Keep refrigerated. (Store below 4C/39F.) Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 92600-11-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: chloroform-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 53 deg C ( 127.40 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1730g/cm3
Molecular Formula: ClCO2CH(Cl)CH(CH3)2
Molecular Weight: 171.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 92600-11-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Chloro-2-Methylpropyl Chloroformate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S
.
Hazard Class: 6.1 (3)
UN Number: 2742
Packing Group: II
IMO
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S
.
Hazard Class: 6.1 (3)
UN Number: 2742
Packing Group: II
RID/ADR
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S
.
Hazard Class: 6.1 (3)
UN Number: 2742
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 92600-11-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 92600-11-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 92600-11-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Amino-1-Naphthol Hydrochloride, Tech. 90%
| 5959-56-8 |
|
2,6-Diisopropylphenyl Isocyanate, 98%
| 28178-42-9 |
|
3-Bromophenyl isocyanate, 97%
| 23138-55-8 |
|
3,5-Dichlorophenyl Isocyanate, 96%
| 34893-92-0 |
|
4-Fluoro-3-Nitrophenyl Isocyanate, 98%
| 65303-82-4 |
|
3,5-Dimethylphenyl isocyanate, 99%
| 54132-75-1 |
|
3,5-Bis(trifluoromethyl)phenyl isocyanate, 98%
| 16588-74-2 |
|
3-Cyanophenyl Isocyanate, 97%
| 16413-26-6 |
|
4-(Methylthio)phenyl Isocyanate, 97%
| 1632-84-4 |
|
n-Propyl nitrate, 97%
| 627-13-4 |
|
Gallic Acid Ethyl Ester, 99%
| 831-61-8 |
|
2-Ethylphenyl Isocyanate, 99%
| 40411-25-4 |
|
2,6-Dimethylphenyl isocyanate, 99%
| 28556-81-2 |
|
Alpha, Alpha, Alpha-Trifluoro-p-Tolyl Isocyanate, 99%
| 1548-13-6 |
|
1-Cyanothioformanilide, 97%
| 4955-82-2 |
|
1-Cyano-N-methylthioformamide, 95%
| 13621-47-1 |
|
Tert-Octyl Isothiocyanate, 94%
| 17701-76-7 |
|
2,3-Dichlorophenyl isocyanate, 97%
| 41195-90-8 |
|
2-Chloro-6-Methylphenyl Isocyanate, 97%
| 40398-01-4 |
|
4-Methyl-3-Nitrophenyl Isocyanate, 98%
| 13471-69-7 |
|
Benzoyl isocyanate, tech., 90%
| 4461-33-0 |
|
2,4-Dimethoxyphenyl Isocyanate, 97%
| 84370-87-6 |
|
Chloroacetyl isocyanate
| 4461-30-7 |
|
Ethoxycarbonyl Isocyanate, Tech., 90%
| 19617-43-7 |
|
Pentyl Isocyanate, 98%
| 3954-13-0 |
|
Hexadecyl isocyanate, 97%
| 1943-84-6 |
|
Heptyl Isocyanate, 97%
| 4747-81-3 |
|
4-(Chloromethyl)Phenyl Isocyanate, 97%
| 29173-65-7 |
|
1-Adamantyl isocyanate, 98%
| 4411-25-0 |
|
1-Chloromethyl-2,4-Diisocyanatobenzene, 98%
| 51979-57-8 |
|
1,4-Diisocyanatobutane, 97%
| 4538-37-8 |
|
trans-1,4-Cyclohexane diisocyanate, 97%
| 7517-76-2 |
|
1,8-Diisocyanatooctane, 98%
| 10124-86-4 |
|
1,12-Diisocyanatododecane, 97%
| 13879-35-1 |
|
4-Isocyanaobenzoyl Chloride, 98%
| 3729-21-3 |
|
3-(Chloromethyl)Benzoyl Chloride, 98%
| 63024-77-1 |
|
4-(Chloromethyl)Benzoyl Chloride, 97%
| 876-08-4 |
|
3-(Dichloromethyl)benzoyl Chloride, 96%
| 36747-51-0 |
|
1-Chloroethyl Chloroformate, 99%
| 50893-53-3 |
|
1-Chloro-2-Methylpropyl Chloroformate, 98%
| 92600-11-8 |
|
(+/-)-1,2,2,2-Tetrachloroethyl chloroformate, 98%
| 98015-53-3 |
|
4-Chlorobutyl chloroformate, 97%
| 37693-18-8 |
|
Triethylene glycol bis(chloroformate), 97%
| 17134-17-7 |
|
(+)-Menthyl chloroformate
| 7635-54-3 |
|
Diisopropylcarbamoyl Chloride, 98%
| 19009-39-3 |
|
Ethylphosphonic dichloride, 98%
| 1066-50-8 |
|
Butylphosphonic Dichloride, 98%
| 2302-80-9 |
|
Octyl chloroformate, 97%
| 7452-59-7 |
|
P-Tolyl Chloroformate, 97%
| 937-62-2 |
|
4-Methoxyphenyl Chloroformate, 98%
| 7693-41-6 |
|
|