**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2302-80-9 |Butylphosphonic dichloride | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode if exposed to fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Use with
adequate ventilation. Use and store under nitrogen. Discard
contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area. Store protected
from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2302-80-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 96 - 97 deg C @ 15.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2410g/cm3
Molecular Formula: CH3(CH2)3P(O)Cl2
Molecular Weight: 175.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus,
carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2302-80-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Butylphosphonic dichloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2302-80-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2302-80-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2302-80-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Amino-1-Naphthol Hydrochloride, Tech. 90%
| 5959-56-8 |
|
2,6-Diisopropylphenyl Isocyanate, 98%
| 28178-42-9 |
|
3-Bromophenyl isocyanate, 97%
| 23138-55-8 |
|
3,5-Dichlorophenyl Isocyanate, 96%
| 34893-92-0 |
|
4-Fluoro-3-Nitrophenyl Isocyanate, 98%
| 65303-82-4 |
|
3,5-Dimethylphenyl isocyanate, 99%
| 54132-75-1 |
|
3,5-Bis(trifluoromethyl)phenyl isocyanate, 98%
| 16588-74-2 |
|
3-Cyanophenyl Isocyanate, 97%
| 16413-26-6 |
|
4-(Methylthio)phenyl Isocyanate, 97%
| 1632-84-4 |
|
n-Propyl nitrate, 97%
| 627-13-4 |
|
Gallic Acid Ethyl Ester, 99%
| 831-61-8 |
|
2-Ethylphenyl Isocyanate, 99%
| 40411-25-4 |
|
2,6-Dimethylphenyl isocyanate, 99%
| 28556-81-2 |
|
Alpha, Alpha, Alpha-Trifluoro-p-Tolyl Isocyanate, 99%
| 1548-13-6 |
|
1-Cyanothioformanilide, 97%
| 4955-82-2 |
|
1-Cyano-N-methylthioformamide, 95%
| 13621-47-1 |
|
Tert-Octyl Isothiocyanate, 94%
| 17701-76-7 |
|
2,3-Dichlorophenyl isocyanate, 97%
| 41195-90-8 |
|
2-Chloro-6-Methylphenyl Isocyanate, 97%
| 40398-01-4 |
|
4-Methyl-3-Nitrophenyl Isocyanate, 98%
| 13471-69-7 |
|
Benzoyl isocyanate, tech., 90%
| 4461-33-0 |
|
2,4-Dimethoxyphenyl Isocyanate, 97%
| 84370-87-6 |
|
Chloroacetyl isocyanate
| 4461-30-7 |
|
Ethoxycarbonyl Isocyanate, Tech., 90%
| 19617-43-7 |
|
Pentyl Isocyanate, 98%
| 3954-13-0 |
|
Hexadecyl isocyanate, 97%
| 1943-84-6 |
|
Heptyl Isocyanate, 97%
| 4747-81-3 |
|
4-(Chloromethyl)Phenyl Isocyanate, 97%
| 29173-65-7 |
|
1-Adamantyl isocyanate, 98%
| 4411-25-0 |
|
1-Chloromethyl-2,4-Diisocyanatobenzene, 98%
| 51979-57-8 |
|
1,4-Diisocyanatobutane, 97%
| 4538-37-8 |
|
trans-1,4-Cyclohexane diisocyanate, 97%
| 7517-76-2 |
|
1,8-Diisocyanatooctane, 98%
| 10124-86-4 |
|
1,12-Diisocyanatododecane, 97%
| 13879-35-1 |
|
4-Isocyanaobenzoyl Chloride, 98%
| 3729-21-3 |
|
3-(Chloromethyl)Benzoyl Chloride, 98%
| 63024-77-1 |
|
4-(Chloromethyl)Benzoyl Chloride, 97%
| 876-08-4 |
|
3-(Dichloromethyl)benzoyl Chloride, 96%
| 36747-51-0 |
|
1-Chloroethyl Chloroformate, 99%
| 50893-53-3 |
|
1-Chloro-2-Methylpropyl Chloroformate, 98%
| 92600-11-8 |
|
(+/-)-1,2,2,2-Tetrachloroethyl chloroformate, 98%
| 98015-53-3 |
|
4-Chlorobutyl chloroformate, 97%
| 37693-18-8 |
|
Triethylene glycol bis(chloroformate), 97%
| 17134-17-7 |
|
(+)-Menthyl chloroformate
| 7635-54-3 |
|
Diisopropylcarbamoyl Chloride, 98%
| 19009-39-3 |
|
Ethylphosphonic dichloride, 98%
| 1066-50-8 |
|
Butylphosphonic Dichloride, 98%
| 2302-80-9 |
|
Octyl chloroformate, 97%
| 7452-59-7 |
|
P-Tolyl Chloroformate, 97%
| 937-62-2 |
|
4-Methoxyphenyl Chloroformate, 98%
| 7693-41-6 |
|
|