**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 17201-43-3 |Alpha-Bromo-P-Tolunitrile | 98.0 | 241-246-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Keep container tightly closed. Do
not get on skin or in eyes. Do not ingest or inhale. Use with
adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 17201-43-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 113.00 - 115.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C8H6BrN
Molecular Weight: 196.05
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen bromide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 17201-43-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Alpha-Bromo-P-Tolunitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.33-1.03 mg/L; 5,15,30
minutes; Microtox test; 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 17201-43-3: No information available.
Canada
CAS# 17201-43-3 is listed on Canada's DSL List.
CAS# 17201-43-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 17201-43-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butanol
| 75-65-0 |
|
2-Chloro-2-methylpropane
| 507-20-0 |
|
1,2-Dihydro-1-Methyl-2-Phenacylidene- Naphtho(1,2-d)Thiazole, 97%
| 1042-84-8 |
|
Saccharin, 98+%
| 81-07-2 |
|
2,5-Dichlorobenzenesulfonyl Chloride, 98%
| 5402-73-3 |
|
Sodium Sulfide Nonahydrate, Reagent ACS (Crystals)
| 1313-84-4 |
|
3-Nitrophthalic Acid, 95%(TLC)
| 603-11-2 |
|
4-Amino-2,2,5,5-Tetramethyl-3-Imidazoli-ne-1-yloxy, Free Radical, 99%
| 69826-42-2 |
|
3-Cyclopentyl-1-Propanol, 99%
| 767-05-5 |
|
3-(2-Bromoacetamido-methyl)-proxyl, free radical
| 84233-52-3 |
|
Methylcyclopentadiene dimer, 95%
| 26472-00-4 |
|
2,4-Dinitrobenzenesulfonic acid dihydrate 98%
| 89-02-1 |
|
1-(3-Hydroxyphenyl)-Urea, 98%
| 701-82-6 |
|
2,2'-Thiodiethanol, 99% (GC)
| 111-48-8 |
|
l-(-)-Menthol 99.7%
| 2216-51-5 |
|
Silver atomic absorption standard solution 1 mg/ml Ag in 0.5N HNO3
| 7440-22-4 |
|
1-Cyclohexylpiperazine, 98%
| 17766-28-8 |
|
2,6-Dichloropyridine, 98%
| 2402-78-0 |
|
Hexamethylphosphoramide, 98%
| 680-31-9 |
|
Methyl Cyclopropanecarboxylate, 98%
| 2868-37-3 |
|
Dichlorodiphenylsilane, 97+%
| 80-10-4 |
|
1-Bromotridecane, 99%
| 765-09-3 |
|
2,3-Dimethylcyclohexanol (Mixture of Isomers), 99%
| 1502-24-5 |
|
2',3',4',5',6'-Pentafluoroacetophenone,97%
| 652-29-9 |
|
Procaine hydrochloride, 99%
| 51-05-8 |
|
2-Phenylquinoline
| 612-96-4 |
|
Scandium Trifluoride, 99.5%
| 13709-47-2 |
|
Tert.-Amyl Alcohol
| 75-85-4 |
|
Tetrabutylammonium Hydroxide Solution (0.4M to 1M)
| 2052-49-5 |
|
Alpha-Bromo-P-Tolunitrile, 98%
| 17201-43-3 |
|
3-Hydroxybenzaldehyde, 98.5%
| 100-83-4 |
|
Diethoxymethane, 99% (GC)
| 462-95-3 |
|
Tris(4-methoxyphenyl)phosphine
| 855-38-9 |
|
Papain, Proteolytic Activity 46000-50000 nfu/mg
| 9001-73-4 |
|
Ellagic Acid Dihydrate, 97%
| 476-66-4 |
|
L(+)-Potassium hydrogen tartrate, 99%
| 868-14-4 |
|
Ethyl orange sodium salt, 92%
| 62758-12-7 |
|
l-Serine methyl ester hydrochloride, 98%
| 5680-80-8 |
|
1,2,4,5-Tetrakis(Bromomethyl)Benzene 98%
| 15442-91-8 |
|
Tetraethylammonium Bromide
| 71-91-0 |
|
Suberic Acid Monomethyl Ester, 97%
| 3946-32-5 |
|
5,8-Dihydro-1-Naphthol, 85%, Remainder 5,6,7,8-Tetrahydronaphthol
| 27673-48-9 |
|
4,5,8-Trimethylpsoralen
| 3902-71-4 |
|
Methyl 2-Trifluoromethylbenzoylacetate
| 0-01-1 |
|
d-Arginine, 99%
| 157-06-2 |
|
Pentafluorobenzenesulfonyl chloride, 99%
| 832-53-1 |
|
Benzo-15-crown-5, 99%
| 14098-44-3 |
|
Tetrahydrofuran (inhibited)
| 109-99-9 |
|
Tetrahydrofuran (uninhibited)
| 109-99-9 |
|
3,5-Dichloropyridine, 98%
| 2457-47-8 |
|
|