**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 80-10-4 |Dichlorodiphenylsilane | >97 | 201-251-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Contact with liquid or vapor causes severe burns
and possible irreversible eye damage.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat as a caustic agent.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated or if contaminated
with water. Substance will react with water (some violently)
releasing flammable, toxic, or corrosive gases and runoff.
Combustible material; may burn but does not ignite readily.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam. Do
NOT get water inside containers. Do NOT use straight streams of
water. For small fires, use carbon dioxide, dry chemical, dry sand,
or alcohol-resistant foam. Most foams will react with the material
and release corrosive/toxic gases. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water on spilled
substances or inside containers. Use water spray to reduce vapors or
divert vapor cloud drift.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Wash clothing before
reuse. Discard contaminated shoes. Keep from contact with moist air
and steam.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Keep containers tightly closed. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 80-10-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: hydrochloric odor - pungent odor
pH: Not available.
Vapor Pressure: 2 mmHg @ 125 C
Viscosity: Not available.
Boiling Point: 305 deg C @ 760.00mm Hg
Freezing/Melting Point: -22 deg C
Autoignition Temperature: Not available.
Flash Point: 157 deg C ( 314.60 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: decomposes in water
Specific Gravity/Density: 1.2040g/cm3
Molecular Formula: C12H10Cl2Si
Molecular Weight: 253.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 80-10-4: VV3190000
LD50/LC50:
CAS# 80-10-4: Draize test, rabbit, eye: 5 mg/24H Severe; Draize
test, rabbit, skin: 20 mg/24H Moderate; Skin, rabbit: LD50 = 100
uL/kg.
Carcinogenicity:
Dichlorodiphenylsilane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIPHENYLDICHLOROSILANE
Hazard Class: 8
UN Number: 1769
Packing Group: II
IMO
Shipping Name: DIPHENYLDICHLOROSILANE
Hazard Class: 8
UN Number: 1769
Packing Group: II
RID/ADR
Shipping Name: DIPHENYLDICHLOROSILANE
Hazard Class: 8
UN Number: 1769
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 80-10-4: No information available.
Canada
CAS# 80-10-4 is listed on Canada's DSL List.
CAS# 80-10-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 80-10-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/09/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butanol
| 75-65-0 |
|
2-Chloro-2-methylpropane
| 507-20-0 |
|
1,2-Dihydro-1-Methyl-2-Phenacylidene- Naphtho(1,2-d)Thiazole, 97%
| 1042-84-8 |
|
Saccharin, 98+%
| 81-07-2 |
|
2,5-Dichlorobenzenesulfonyl Chloride, 98%
| 5402-73-3 |
|
Sodium Sulfide Nonahydrate, Reagent ACS (Crystals)
| 1313-84-4 |
|
3-Nitrophthalic Acid, 95%(TLC)
| 603-11-2 |
|
4-Amino-2,2,5,5-Tetramethyl-3-Imidazoli-ne-1-yloxy, Free Radical, 99%
| 69826-42-2 |
|
3-Cyclopentyl-1-Propanol, 99%
| 767-05-5 |
|
3-(2-Bromoacetamido-methyl)-proxyl, free radical
| 84233-52-3 |
|
Methylcyclopentadiene dimer, 95%
| 26472-00-4 |
|
2,4-Dinitrobenzenesulfonic acid dihydrate 98%
| 89-02-1 |
|
1-(3-Hydroxyphenyl)-Urea, 98%
| 701-82-6 |
|
2,2'-Thiodiethanol, 99% (GC)
| 111-48-8 |
|
l-(-)-Menthol 99.7%
| 2216-51-5 |
|
Silver atomic absorption standard solution 1 mg/ml Ag in 0.5N HNO3
| 7440-22-4 |
|
1-Cyclohexylpiperazine, 98%
| 17766-28-8 |
|
2,6-Dichloropyridine, 98%
| 2402-78-0 |
|
Hexamethylphosphoramide, 98%
| 680-31-9 |
|
Methyl Cyclopropanecarboxylate, 98%
| 2868-37-3 |
|
Dichlorodiphenylsilane, 97+%
| 80-10-4 |
|
1-Bromotridecane, 99%
| 765-09-3 |
|
2,3-Dimethylcyclohexanol (Mixture of Isomers), 99%
| 1502-24-5 |
|
2',3',4',5',6'-Pentafluoroacetophenone,97%
| 652-29-9 |
|
Procaine hydrochloride, 99%
| 51-05-8 |
|
2-Phenylquinoline
| 612-96-4 |
|
Scandium Trifluoride, 99.5%
| 13709-47-2 |
|
Tert.-Amyl Alcohol
| 75-85-4 |
|
Tetrabutylammonium Hydroxide Solution (0.4M to 1M)
| 2052-49-5 |
|
Alpha-Bromo-P-Tolunitrile, 98%
| 17201-43-3 |
|
3-Hydroxybenzaldehyde, 98.5%
| 100-83-4 |
|
Diethoxymethane, 99% (GC)
| 462-95-3 |
|
Tris(4-methoxyphenyl)phosphine
| 855-38-9 |
|
Papain, Proteolytic Activity 46000-50000 nfu/mg
| 9001-73-4 |
|
Ellagic Acid Dihydrate, 97%
| 476-66-4 |
|
L(+)-Potassium hydrogen tartrate, 99%
| 868-14-4 |
|
Ethyl orange sodium salt, 92%
| 62758-12-7 |
|
l-Serine methyl ester hydrochloride, 98%
| 5680-80-8 |
|
1,2,4,5-Tetrakis(Bromomethyl)Benzene 98%
| 15442-91-8 |
|
Tetraethylammonium Bromide
| 71-91-0 |
|
Suberic Acid Monomethyl Ester, 97%
| 3946-32-5 |
|
5,8-Dihydro-1-Naphthol, 85%, Remainder 5,6,7,8-Tetrahydronaphthol
| 27673-48-9 |
|
4,5,8-Trimethylpsoralen
| 3902-71-4 |
|
Methyl 2-Trifluoromethylbenzoylacetate
| 0-01-1 |
|
d-Arginine, 99%
| 157-06-2 |
|
Pentafluorobenzenesulfonyl chloride, 99%
| 832-53-1 |
|
Benzo-15-crown-5, 99%
| 14098-44-3 |
|
Tetrahydrofuran (inhibited)
| 109-99-9 |
|
Tetrahydrofuran (uninhibited)
| 109-99-9 |
|
3,5-Dichloropyridine, 98%
| 2457-47-8 |
|
|