**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 832-53-1 |Pentafluorobenzenesulfonyl chloride | 99 | 212-620-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Effects of contact may be delayed.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause severe respiratory tract irritation and possible burns.
Effects of inhalation may be delayed.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Discard contaminated clothing
in a manner which limits further exposure. Remove contaminated
clothing and shoes. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid. Some
oxidizers may react explosively with hydrocarbons(fuel). Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For small fires,
use dry chemical, carbon dioxide, or water spray. For large fires,
use dry chemical, carbon dioxide, alcohol-resistant foam, or water
spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Remove all
sources of ignition. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not get on skin or in eyes. Do not ingest or
inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 832-53-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 210.0 - 211.0 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 90 deg C ( 194.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6ClF5O2S
Molecular Weight: 266.57
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride
gas, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 832-53-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Pentafluorobenzenesulfonyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 832-53-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 832-53-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 832-53-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/09/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butanol
| 75-65-0 |
|
2-Chloro-2-methylpropane
| 507-20-0 |
|
1,2-Dihydro-1-Methyl-2-Phenacylidene- Naphtho(1,2-d)Thiazole, 97%
| 1042-84-8 |
|
Saccharin, 98+%
| 81-07-2 |
|
2,5-Dichlorobenzenesulfonyl Chloride, 98%
| 5402-73-3 |
|
Sodium Sulfide Nonahydrate, Reagent ACS (Crystals)
| 1313-84-4 |
|
3-Nitrophthalic Acid, 95%(TLC)
| 603-11-2 |
|
4-Amino-2,2,5,5-Tetramethyl-3-Imidazoli-ne-1-yloxy, Free Radical, 99%
| 69826-42-2 |
|
3-Cyclopentyl-1-Propanol, 99%
| 767-05-5 |
|
3-(2-Bromoacetamido-methyl)-proxyl, free radical
| 84233-52-3 |
|
Methylcyclopentadiene dimer, 95%
| 26472-00-4 |
|
2,4-Dinitrobenzenesulfonic acid dihydrate 98%
| 89-02-1 |
|
1-(3-Hydroxyphenyl)-Urea, 98%
| 701-82-6 |
|
2,2'-Thiodiethanol, 99% (GC)
| 111-48-8 |
|
l-(-)-Menthol 99.7%
| 2216-51-5 |
|
Silver atomic absorption standard solution 1 mg/ml Ag in 0.5N HNO3
| 7440-22-4 |
|
1-Cyclohexylpiperazine, 98%
| 17766-28-8 |
|
2,6-Dichloropyridine, 98%
| 2402-78-0 |
|
Hexamethylphosphoramide, 98%
| 680-31-9 |
|
Methyl Cyclopropanecarboxylate, 98%
| 2868-37-3 |
|
Dichlorodiphenylsilane, 97+%
| 80-10-4 |
|
1-Bromotridecane, 99%
| 765-09-3 |
|
2,3-Dimethylcyclohexanol (Mixture of Isomers), 99%
| 1502-24-5 |
|
2',3',4',5',6'-Pentafluoroacetophenone,97%
| 652-29-9 |
|
Procaine hydrochloride, 99%
| 51-05-8 |
|
2-Phenylquinoline
| 612-96-4 |
|
Scandium Trifluoride, 99.5%
| 13709-47-2 |
|
Tert.-Amyl Alcohol
| 75-85-4 |
|
Tetrabutylammonium Hydroxide Solution (0.4M to 1M)
| 2052-49-5 |
|
Alpha-Bromo-P-Tolunitrile, 98%
| 17201-43-3 |
|
3-Hydroxybenzaldehyde, 98.5%
| 100-83-4 |
|
Diethoxymethane, 99% (GC)
| 462-95-3 |
|
Tris(4-methoxyphenyl)phosphine
| 855-38-9 |
|
Papain, Proteolytic Activity 46000-50000 nfu/mg
| 9001-73-4 |
|
Ellagic Acid Dihydrate, 97%
| 476-66-4 |
|
L(+)-Potassium hydrogen tartrate, 99%
| 868-14-4 |
|
Ethyl orange sodium salt, 92%
| 62758-12-7 |
|
l-Serine methyl ester hydrochloride, 98%
| 5680-80-8 |
|
1,2,4,5-Tetrakis(Bromomethyl)Benzene 98%
| 15442-91-8 |
|
Tetraethylammonium Bromide
| 71-91-0 |
|
Suberic Acid Monomethyl Ester, 97%
| 3946-32-5 |
|
5,8-Dihydro-1-Naphthol, 85%, Remainder 5,6,7,8-Tetrahydronaphthol
| 27673-48-9 |
|
4,5,8-Trimethylpsoralen
| 3902-71-4 |
|
Methyl 2-Trifluoromethylbenzoylacetate
| 0-01-1 |
|
d-Arginine, 99%
| 157-06-2 |
|
Pentafluorobenzenesulfonyl chloride, 99%
| 832-53-1 |
|
Benzo-15-crown-5, 99%
| 14098-44-3 |
|
Tetrahydrofuran (inhibited)
| 109-99-9 |
|
Tetrahydrofuran (uninhibited)
| 109-99-9 |
|
3,5-Dichloropyridine, 98%
| 2457-47-8 |
|
|