**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7440-22-4 |Silver | 0.1 | 231-131-3 |
|----------------|--------------------------------------|----------|-----------|
| 7697-37-2 |Nitric acid | 3.15 | 231-714-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 96.75 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 37/38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to respiratory system and skin. Risk of serious damage to
eyes.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use with adequate
ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7440-22-4:
United Kingdom, WEL - TWA: 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: 0.3 mg/m3 STEL
United States OSHA: 0.01 mg/m3 TWA
Belgium - TWA: 0.1 mg/m3 VLE
France - VME: 0.1 mg/m3 VME
Germany: 0.1 mg/m3 TWA (inhalable fraction)
Japan: 0.01 mg/m3 OEL
Malaysia: 0.1 mg/m3 TWA
Netherlands: 0.1 mg/m3 MAC (as Ag)
Russia: 1 mg/m3 TWA
Spain: 0.1 mg/m3 VLA-ED
CAS# 7697-37-2:
United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA
United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL
United States OSHA: 2 ppm TWA; 5 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 4 ppm VLE; 10 mg/m3 VLE
Germany: 2 ppm TWA; 5.2 mg/m3 TWA
Japan: 2 ppm OEL; 5.2 mg/m3 OEL
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL
Russia: 2 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED
Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: Unknown
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, oxidizers.
Incompatibilities with Other Materials:
Alkali metals, alcohols, brass, copper, copper alloys, finely
powdered metals, galvanized iron, organic materials, amines.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, nitrogen,
silver fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-22-4: VW3500000
CAS# 7697-37-2: QU5775000 QU5900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation,
rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Silver -
Not listed by ACGIH, IARC, or NTP.
Nitric acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
IMO
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
RID/ADR
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing group: II
USA RQ: CAS# 7440-22-4: 1000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7440-22-4: 0
CAS# 7697-37-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-22-4 is listed on Canada's DSL List.
CAS# 7697-37-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7440-22-4 is listed on Canada's Ingredient Disclosure List.
CAS# 7697-37-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-22-4 is listed on the TSCA inventory.
CAS# 7697-37-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 11/09/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butanol
| 75-65-0 |
|
2-Chloro-2-methylpropane
| 507-20-0 |
|
1,2-Dihydro-1-Methyl-2-Phenacylidene- Naphtho(1,2-d)Thiazole, 97%
| 1042-84-8 |
|
Saccharin, 98+%
| 81-07-2 |
|
2,5-Dichlorobenzenesulfonyl Chloride, 98%
| 5402-73-3 |
|
Sodium Sulfide Nonahydrate, Reagent ACS (Crystals)
| 1313-84-4 |
|
3-Nitrophthalic Acid, 95%(TLC)
| 603-11-2 |
|
4-Amino-2,2,5,5-Tetramethyl-3-Imidazoli-ne-1-yloxy, Free Radical, 99%
| 69826-42-2 |
|
3-Cyclopentyl-1-Propanol, 99%
| 767-05-5 |
|
3-(2-Bromoacetamido-methyl)-proxyl, free radical
| 84233-52-3 |
|
Methylcyclopentadiene dimer, 95%
| 26472-00-4 |
|
2,4-Dinitrobenzenesulfonic acid dihydrate 98%
| 89-02-1 |
|
1-(3-Hydroxyphenyl)-Urea, 98%
| 701-82-6 |
|
2,2'-Thiodiethanol, 99% (GC)
| 111-48-8 |
|
l-(-)-Menthol 99.7%
| 2216-51-5 |
|
Silver atomic absorption standard solution 1 mg/ml Ag in 0.5N HNO3
| 7440-22-4 |
|
1-Cyclohexylpiperazine, 98%
| 17766-28-8 |
|
2,6-Dichloropyridine, 98%
| 2402-78-0 |
|
Hexamethylphosphoramide, 98%
| 680-31-9 |
|
Methyl Cyclopropanecarboxylate, 98%
| 2868-37-3 |
|
Dichlorodiphenylsilane, 97+%
| 80-10-4 |
|
1-Bromotridecane, 99%
| 765-09-3 |
|
2,3-Dimethylcyclohexanol (Mixture of Isomers), 99%
| 1502-24-5 |
|
2',3',4',5',6'-Pentafluoroacetophenone,97%
| 652-29-9 |
|
Procaine hydrochloride, 99%
| 51-05-8 |
|
2-Phenylquinoline
| 612-96-4 |
|
Scandium Trifluoride, 99.5%
| 13709-47-2 |
|
Tert.-Amyl Alcohol
| 75-85-4 |
|
Tetrabutylammonium Hydroxide Solution (0.4M to 1M)
| 2052-49-5 |
|
Alpha-Bromo-P-Tolunitrile, 98%
| 17201-43-3 |
|
3-Hydroxybenzaldehyde, 98.5%
| 100-83-4 |
|
Diethoxymethane, 99% (GC)
| 462-95-3 |
|
Tris(4-methoxyphenyl)phosphine
| 855-38-9 |
|
Papain, Proteolytic Activity 46000-50000 nfu/mg
| 9001-73-4 |
|
Ellagic Acid Dihydrate, 97%
| 476-66-4 |
|
L(+)-Potassium hydrogen tartrate, 99%
| 868-14-4 |
|
Ethyl orange sodium salt, 92%
| 62758-12-7 |
|
l-Serine methyl ester hydrochloride, 98%
| 5680-80-8 |
|
1,2,4,5-Tetrakis(Bromomethyl)Benzene 98%
| 15442-91-8 |
|
Tetraethylammonium Bromide
| 71-91-0 |
|
Suberic Acid Monomethyl Ester, 97%
| 3946-32-5 |
|
5,8-Dihydro-1-Naphthol, 85%, Remainder 5,6,7,8-Tetrahydronaphthol
| 27673-48-9 |
|
4,5,8-Trimethylpsoralen
| 3902-71-4 |
|
Methyl 2-Trifluoromethylbenzoylacetate
| 0-01-1 |
|
d-Arginine, 99%
| 157-06-2 |
|
Pentafluorobenzenesulfonyl chloride, 99%
| 832-53-1 |
|
Benzo-15-crown-5, 99%
| 14098-44-3 |
|
Tetrahydrofuran (inhibited)
| 109-99-9 |
|
Tetrahydrofuran (uninhibited)
| 109-99-9 |
|
3,5-Dichloropyridine, 98%
| 2457-47-8 |
|
|