**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2234-26-6 |2-Norbornanecarbonitrile | 98% | 218-782-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause lacrimation (tearing), blurred
vision, and photophobia. May cause chemical conjunctivitis and
corneal damage.
Skin:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. May cause skin
irritation and possible burns.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Metabolism may release cyanide, which may result in headache,
dizziness, weakness, collapse, unconsciousness and possible death.
May cause nausea, vomiting, abdominal pain, and increased salivation.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Olfactory fatigue
may occur. Can produce delayed pulmonary edema. May be metabolized to
cyanide which in turns act by inhibiting cytochrome oxidase impairing
cellular respiration. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. Effects may be
delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
May be partially metabolized to cyanide in the body.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Dusts may be combustible when exposed to heat,
flame, or oxidizing agents. Dust can be an explosion hazard when
exposed to heat or flame. Flammable solid. May burn rapidly with
flare burning effect. May re-ignite after fire is extinguished.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam. Use agent most
appropriate to extinguish fire. For large fires, use water spray, fog
or regular foam. Contact professional fire-fighters immediately. For
small fires, use dry chemical, carbon dioxide, sand, earth, water
spray or regular foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Scoop up with a nonsparking tool, then
place into a suitable container for disposal. Avoid generating dusty
conditions. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use only in a chemical fume hood. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Exposure Limits
CAS# 2234-26-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 73 - 75 deg C @ 10.00mm Hg
Freezing/Melting Point: 43 - 45 deg C
Autoignition Temperature: Not applicable.
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H11N
Molecular Weight: 121.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, oxidizing agents, reducing agents, acids,
bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2234-26-6: RB6960000
LD50/LC50:
Not available.
Carcinogenicity:
2-Norbornanecarbonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.*
Hazard Class: 4.1 (6.1)
UN Number: 2926
Packing Group: III
IMO
Shipping Name: FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.
Hazard Class: 4.1 (6.1)
UN Number: 2926
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 2926
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 2234-26-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2234-26-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2234-26-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
o-Tolyl isocyanate, 99+%
| 614-68-6 |
|
Perfluorodecyl iodide, 97%
| 423-62-1 |
|
3-Phenoxy-1,2-Propanediol, 95%
| 538-43-2 |
|
Ethylenediaminetetraacetic Acid, Trisodium Salt Hydrate, 98%
| 150-38-9 |
|
Ethyl 2-thiopheneacetate, 98%
| 57382-97-5 |
|
4,4'-(Hexafluoroisopropylidene)diphenol, 97%
| 1478-61-1 |
|
2,2,3,3,3-Pentafluoro-1-propanol, 97%
| 422-05-9 |
|
Difluoroacetic Acid, 98%
| 381-73-7 |
|
Fluoroacetonitrile, 99%
| 503-20-8 |
|
3,3,3-Triphenylpropionic Acid, 97%
| 900-91-4 |
|
1-Phenylsemicarbazide
| 103-03-7 |
|
1-Pentyne, 99%
| 627-19-0 |
|
2-Chloropropene, 98%
| 557-98-2 |
|
2,6-Dichlorophenylhydrazine Hydrochloride
| 50709-36-9 |
|
1,2,4,5-Benzenetetracarbonitrile, 99%
| 712-74-3 |
|
4-Nitroguaiacol, 97%
| 3251-56-7 |
|
4,4'-Dinitrobibenzyl, tech., 80%
| 736-30-1 |
|
Ethyl ethoxyacetate, 98%
| 817-95-8 |
|
2,4-Dichloro-5-Sulfamoylbenzoic Acid, 98%
| 2736-23-4 |
|
m-Toluamide, 99%
| 618-47-3 |
|
Methyl 3,5-dinitrobenzoate, 99%
| 2702-58-1 |
|
5-Hydroxyanthranilic acid, 99%
| 394-31-0 |
|
4-Bromo-1,2-(Methylenedioxy)benzene, 97%
| 2635-13-4 |
|
Cis-1,2-Cyclopentanediol, 98%
| 5057-98-7 |
|
Tetramethyl-1,3-Cyclobutanedione, 99%
| 933-52-8 |
|
3-(Isothiocyanatomethyl)-PROXYL, free radical
| 78140-52-0 |
|
4-Undecyloxybenzoic acid, 98%
| 15872-43-2 |
|
Benzyl phenyl ether, 98%
| 945-51-7 |
|
9-Phenyl-9-fluorenol, 99%
| 25603-67-2 |
|
Ethyl cyanoglyoxylate-2-oxime, 97%
| 3849-21-6 |
|
Methyl dichlorophosphate, 97%
| 677-24-7 |
|
Cis-1,2-Cyclohexanediol, 99%
| 1792-81-0 |
|
2-Norbornanecarbonitrile, 98%, Mixture of Endo and Exo
| 2234-26-6 |
|
Hexanes, c.p.
| 110-54-3 |
|
2',4'-Dimethylacetophenone, 96%
| 89-74-7 |
|
3,4-Dimethoxy-3-Cyclobutene-1,2-Dione, 99%
| 5222-73-1 |
|
5-Fluoro-2-methylbenzoic acid, 99%
| 33184-16-6 |
|
6-Fluoro-4-Chromanone, 99%
| 66892-34-0 |
|
beta-D-Lactose, ca 80% beta and 20% alpha
| 5965-66-2 |
|
Phenylmaleic Anhydride, 99%
| 36122-35-7 |
|
Dichloromethylphosphine, tech., 90%
| 676-83-5 |
|
4-Bromo-2,6-Di-Tert-Butylphenol, 98%
| 1139-52-2 |
|
2-Chloro-4-fluorobenzonitrile, 99%
| 60702-69-4 |
|
4,5-Dimethoxy-2-Nitrocinnamic Acid, 97%
| 20567-38-8 |
|
4-Hydroxy-2(5h)-furanone, 98%
| 541-57-1 |
|
Diethyl meso-2,5-dibromoadipate
| 869-10-3 |
|
2-Methyl-6-isopropylaniline, 97%
| 5266-85-3 |
|
1,8-Diphenyl-1,3,5,7-octatetraene
| 3029-40-1 |
|
3-Cyanoindole, 98%
| 5457-28-3 |
|
Methyl 4-(bromomethyl)benzoate, 98%
| 2417-72-3 |
|
|