**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 557-98-2 |2-Chloropropene | 98 | 209-187-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F+
Risk Phrases: 12 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. Harmful by inhalation, in contact with skin and
if swallowed.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause liver and
kidney damage. The toxicological properties of this substance have
not been fully investigated. May cause central nervous system
depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Exposure produces
central nervous system depression. Vapors may cause dizziness or
suffocation. Exposure may cause coughing, breathing difficulty, and
possible pulmonary edema.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Extremely flammable liquid and vapor. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire. Will be easily ignited by heat, sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. If water is the only media
available, use in flooding amounts. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 557-98-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: chlorine-like
pH: Not available.
Vapor Pressure: 819 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 22.5 - 22.8 deg C
Freezing/Melting Point: -138.6 deg C
Autoignition Temperature: Not available.
Flash Point: <-34 deg C
Explosion Limits, lower: 4.5%
Explosion Limits, upper: 16%
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8990g/cm3
Molecular Formula: C3H5Cl
Molecular Weight: 76.53
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 557-98-2: UC7200000
LD50/LC50:
CAS# 557-98-2: Inhalation, mouse: LC50 = 267 gm/m3.
Carcinogenicity:
2-Chloropropene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2-CHLOROPROPENE
Hazard Class: 3
UN Number: 2456
Packing Group: I
IMO
Shipping Name: 2-CHLOROPROPENE
Hazard Class: 3.1
UN Number: 2456
Packing Group: I
RID/ADR
Shipping Name: 2-CHLOROPROPENE
Hazard Class: 3
UN Number: 2456
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F+
Risk Phrases:
R 12 Extremely flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 557-98-2: No information available.
Canada
CAS# 557-98-2 is listed on Canada's NDSL List.
CAS# 557-98-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 557-98-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/22/1999 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
o-Tolyl isocyanate, 99+%
| 614-68-6 |
|
Perfluorodecyl iodide, 97%
| 423-62-1 |
|
3-Phenoxy-1,2-Propanediol, 95%
| 538-43-2 |
|
Ethylenediaminetetraacetic Acid, Trisodium Salt Hydrate, 98%
| 150-38-9 |
|
Ethyl 2-thiopheneacetate, 98%
| 57382-97-5 |
|
4,4'-(Hexafluoroisopropylidene)diphenol, 97%
| 1478-61-1 |
|
2,2,3,3,3-Pentafluoro-1-propanol, 97%
| 422-05-9 |
|
Difluoroacetic Acid, 98%
| 381-73-7 |
|
Fluoroacetonitrile, 99%
| 503-20-8 |
|
3,3,3-Triphenylpropionic Acid, 97%
| 900-91-4 |
|
1-Phenylsemicarbazide
| 103-03-7 |
|
1-Pentyne, 99%
| 627-19-0 |
|
2-Chloropropene, 98%
| 557-98-2 |
|
2,6-Dichlorophenylhydrazine Hydrochloride
| 50709-36-9 |
|
1,2,4,5-Benzenetetracarbonitrile, 99%
| 712-74-3 |
|
4-Nitroguaiacol, 97%
| 3251-56-7 |
|
4,4'-Dinitrobibenzyl, tech., 80%
| 736-30-1 |
|
Ethyl ethoxyacetate, 98%
| 817-95-8 |
|
2,4-Dichloro-5-Sulfamoylbenzoic Acid, 98%
| 2736-23-4 |
|
m-Toluamide, 99%
| 618-47-3 |
|
Methyl 3,5-dinitrobenzoate, 99%
| 2702-58-1 |
|
5-Hydroxyanthranilic acid, 99%
| 394-31-0 |
|
4-Bromo-1,2-(Methylenedioxy)benzene, 97%
| 2635-13-4 |
|
Cis-1,2-Cyclopentanediol, 98%
| 5057-98-7 |
|
Tetramethyl-1,3-Cyclobutanedione, 99%
| 933-52-8 |
|
3-(Isothiocyanatomethyl)-PROXYL, free radical
| 78140-52-0 |
|
4-Undecyloxybenzoic acid, 98%
| 15872-43-2 |
|
Benzyl phenyl ether, 98%
| 945-51-7 |
|
9-Phenyl-9-fluorenol, 99%
| 25603-67-2 |
|
Ethyl cyanoglyoxylate-2-oxime, 97%
| 3849-21-6 |
|
Methyl dichlorophosphate, 97%
| 677-24-7 |
|
Cis-1,2-Cyclohexanediol, 99%
| 1792-81-0 |
|
2-Norbornanecarbonitrile, 98%, Mixture of Endo and Exo
| 2234-26-6 |
|
Hexanes, c.p.
| 110-54-3 |
|
2',4'-Dimethylacetophenone, 96%
| 89-74-7 |
|
3,4-Dimethoxy-3-Cyclobutene-1,2-Dione, 99%
| 5222-73-1 |
|
5-Fluoro-2-methylbenzoic acid, 99%
| 33184-16-6 |
|
6-Fluoro-4-Chromanone, 99%
| 66892-34-0 |
|
beta-D-Lactose, ca 80% beta and 20% alpha
| 5965-66-2 |
|
Phenylmaleic Anhydride, 99%
| 36122-35-7 |
|
Dichloromethylphosphine, tech., 90%
| 676-83-5 |
|
4-Bromo-2,6-Di-Tert-Butylphenol, 98%
| 1139-52-2 |
|
2-Chloro-4-fluorobenzonitrile, 99%
| 60702-69-4 |
|
4,5-Dimethoxy-2-Nitrocinnamic Acid, 97%
| 20567-38-8 |
|
4-Hydroxy-2(5h)-furanone, 98%
| 541-57-1 |
|
Diethyl meso-2,5-dibromoadipate
| 869-10-3 |
|
2-Methyl-6-isopropylaniline, 97%
| 5266-85-3 |
|
1,8-Diphenyl-1,3,5,7-octatetraene
| 3029-40-1 |
|
3-Cyanoindole, 98%
| 5457-28-3 |
|
Methyl 4-(bromomethyl)benzoate, 98%
| 2417-72-3 |
|
|