**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 381-73-7 |Difluoroacetic Acid | 98 | 206-839-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe respiratory tract irritation and possible burns.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Do not ingest
or inhale. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 381-73-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 132 - 134 deg C @ 760.00mm Hg
Freezing/Melting Point: -1 deg C
Autoignition Temperature: Not available.
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.5260g/cm3
Molecular Formula: C2H2F2O2
Molecular Weight: 96.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, electrical sparks, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, explosive reaction with
fluorine + cesium fluoride.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 381-73-7: AG9900000
LD50/LC50:
Not available.
Carcinogenicity:
Difluoroacetic Acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 381-73-7: No information available.
Canada
CAS# 381-73-7 is listed on Canada's NDSL List.
CAS# 381-73-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 381-73-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
o-Tolyl isocyanate, 99+%
| 614-68-6 |
|
Perfluorodecyl iodide, 97%
| 423-62-1 |
|
3-Phenoxy-1,2-Propanediol, 95%
| 538-43-2 |
|
Ethylenediaminetetraacetic Acid, Trisodium Salt Hydrate, 98%
| 150-38-9 |
|
Ethyl 2-thiopheneacetate, 98%
| 57382-97-5 |
|
4,4'-(Hexafluoroisopropylidene)diphenol, 97%
| 1478-61-1 |
|
2,2,3,3,3-Pentafluoro-1-propanol, 97%
| 422-05-9 |
|
Difluoroacetic Acid, 98%
| 381-73-7 |
|
Fluoroacetonitrile, 99%
| 503-20-8 |
|
3,3,3-Triphenylpropionic Acid, 97%
| 900-91-4 |
|
1-Phenylsemicarbazide
| 103-03-7 |
|
1-Pentyne, 99%
| 627-19-0 |
|
2-Chloropropene, 98%
| 557-98-2 |
|
2,6-Dichlorophenylhydrazine Hydrochloride
| 50709-36-9 |
|
1,2,4,5-Benzenetetracarbonitrile, 99%
| 712-74-3 |
|
4-Nitroguaiacol, 97%
| 3251-56-7 |
|
4,4'-Dinitrobibenzyl, tech., 80%
| 736-30-1 |
|
Ethyl ethoxyacetate, 98%
| 817-95-8 |
|
2,4-Dichloro-5-Sulfamoylbenzoic Acid, 98%
| 2736-23-4 |
|
m-Toluamide, 99%
| 618-47-3 |
|
Methyl 3,5-dinitrobenzoate, 99%
| 2702-58-1 |
|
5-Hydroxyanthranilic acid, 99%
| 394-31-0 |
|
4-Bromo-1,2-(Methylenedioxy)benzene, 97%
| 2635-13-4 |
|
Cis-1,2-Cyclopentanediol, 98%
| 5057-98-7 |
|
Tetramethyl-1,3-Cyclobutanedione, 99%
| 933-52-8 |
|
3-(Isothiocyanatomethyl)-PROXYL, free radical
| 78140-52-0 |
|
4-Undecyloxybenzoic acid, 98%
| 15872-43-2 |
|
Benzyl phenyl ether, 98%
| 945-51-7 |
|
9-Phenyl-9-fluorenol, 99%
| 25603-67-2 |
|
Ethyl cyanoglyoxylate-2-oxime, 97%
| 3849-21-6 |
|
Methyl dichlorophosphate, 97%
| 677-24-7 |
|
Cis-1,2-Cyclohexanediol, 99%
| 1792-81-0 |
|
2-Norbornanecarbonitrile, 98%, Mixture of Endo and Exo
| 2234-26-6 |
|
Hexanes, c.p.
| 110-54-3 |
|
2',4'-Dimethylacetophenone, 96%
| 89-74-7 |
|
3,4-Dimethoxy-3-Cyclobutene-1,2-Dione, 99%
| 5222-73-1 |
|
5-Fluoro-2-methylbenzoic acid, 99%
| 33184-16-6 |
|
6-Fluoro-4-Chromanone, 99%
| 66892-34-0 |
|
beta-D-Lactose, ca 80% beta and 20% alpha
| 5965-66-2 |
|
Phenylmaleic Anhydride, 99%
| 36122-35-7 |
|
Dichloromethylphosphine, tech., 90%
| 676-83-5 |
|
4-Bromo-2,6-Di-Tert-Butylphenol, 98%
| 1139-52-2 |
|
2-Chloro-4-fluorobenzonitrile, 99%
| 60702-69-4 |
|
4,5-Dimethoxy-2-Nitrocinnamic Acid, 97%
| 20567-38-8 |
|
4-Hydroxy-2(5h)-furanone, 98%
| 541-57-1 |
|
Diethyl meso-2,5-dibromoadipate
| 869-10-3 |
|
2-Methyl-6-isopropylaniline, 97%
| 5266-85-3 |
|
1,8-Diphenyl-1,3,5,7-octatetraene
| 3029-40-1 |
|
3-Cyanoindole, 98%
| 5457-28-3 |
|
Methyl 4-(bromomethyl)benzoate, 98%
| 2417-72-3 |
|
|