**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 503-20-8 |Fluoroacetonitrile | 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation, in contact with skin and if
swallowed.Highly flammable.The toxicological properties of this
material have not been fully investigated.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
May cause eye irritation. Lachrymator (substance which increases
the flow of tears).
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid. Get medical aid
immediately.
Skin:
Get medical aid. Get medical aid immediately. Flush skin with plenty
of water for at least 15 minutes while removing contaminated clothing
and shoes. Immediately flush skin with plenty of water for at least
15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Get medical aid immediately. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Flammable liquid and vapor. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Will be easily ignited by heat, sparks or flame.
Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 503-20-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: acetone-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 79 - 80 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -13 deg C ( 8.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0610g/cm3
Molecular Formula: C2H2FN
Molecular Weight: 59.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 503-20-8: AM0175000
LD50/LC50:
Not available.
Carcinogenicity:
Fluoroacetonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 503-20-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 503-20-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 503-20-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/23/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
o-Tolyl isocyanate, 99+%
| 614-68-6 |
|
Perfluorodecyl iodide, 97%
| 423-62-1 |
|
3-Phenoxy-1,2-Propanediol, 95%
| 538-43-2 |
|
Ethylenediaminetetraacetic Acid, Trisodium Salt Hydrate, 98%
| 150-38-9 |
|
Ethyl 2-thiopheneacetate, 98%
| 57382-97-5 |
|
4,4'-(Hexafluoroisopropylidene)diphenol, 97%
| 1478-61-1 |
|
2,2,3,3,3-Pentafluoro-1-propanol, 97%
| 422-05-9 |
|
Difluoroacetic Acid, 98%
| 381-73-7 |
|
Fluoroacetonitrile, 99%
| 503-20-8 |
|
3,3,3-Triphenylpropionic Acid, 97%
| 900-91-4 |
|
1-Phenylsemicarbazide
| 103-03-7 |
|
1-Pentyne, 99%
| 627-19-0 |
|
2-Chloropropene, 98%
| 557-98-2 |
|
2,6-Dichlorophenylhydrazine Hydrochloride
| 50709-36-9 |
|
1,2,4,5-Benzenetetracarbonitrile, 99%
| 712-74-3 |
|
4-Nitroguaiacol, 97%
| 3251-56-7 |
|
4,4'-Dinitrobibenzyl, tech., 80%
| 736-30-1 |
|
Ethyl ethoxyacetate, 98%
| 817-95-8 |
|
2,4-Dichloro-5-Sulfamoylbenzoic Acid, 98%
| 2736-23-4 |
|
m-Toluamide, 99%
| 618-47-3 |
|
Methyl 3,5-dinitrobenzoate, 99%
| 2702-58-1 |
|
5-Hydroxyanthranilic acid, 99%
| 394-31-0 |
|
4-Bromo-1,2-(Methylenedioxy)benzene, 97%
| 2635-13-4 |
|
Cis-1,2-Cyclopentanediol, 98%
| 5057-98-7 |
|
Tetramethyl-1,3-Cyclobutanedione, 99%
| 933-52-8 |
|
3-(Isothiocyanatomethyl)-PROXYL, free radical
| 78140-52-0 |
|
4-Undecyloxybenzoic acid, 98%
| 15872-43-2 |
|
Benzyl phenyl ether, 98%
| 945-51-7 |
|
9-Phenyl-9-fluorenol, 99%
| 25603-67-2 |
|
Ethyl cyanoglyoxylate-2-oxime, 97%
| 3849-21-6 |
|
Methyl dichlorophosphate, 97%
| 677-24-7 |
|
Cis-1,2-Cyclohexanediol, 99%
| 1792-81-0 |
|
2-Norbornanecarbonitrile, 98%, Mixture of Endo and Exo
| 2234-26-6 |
|
Hexanes, c.p.
| 110-54-3 |
|
2',4'-Dimethylacetophenone, 96%
| 89-74-7 |
|
3,4-Dimethoxy-3-Cyclobutene-1,2-Dione, 99%
| 5222-73-1 |
|
5-Fluoro-2-methylbenzoic acid, 99%
| 33184-16-6 |
|
6-Fluoro-4-Chromanone, 99%
| 66892-34-0 |
|
beta-D-Lactose, ca 80% beta and 20% alpha
| 5965-66-2 |
|
Phenylmaleic Anhydride, 99%
| 36122-35-7 |
|
Dichloromethylphosphine, tech., 90%
| 676-83-5 |
|
4-Bromo-2,6-Di-Tert-Butylphenol, 98%
| 1139-52-2 |
|
2-Chloro-4-fluorobenzonitrile, 99%
| 60702-69-4 |
|
4,5-Dimethoxy-2-Nitrocinnamic Acid, 97%
| 20567-38-8 |
|
4-Hydroxy-2(5h)-furanone, 98%
| 541-57-1 |
|
Diethyl meso-2,5-dibromoadipate
| 869-10-3 |
|
2-Methyl-6-isopropylaniline, 97%
| 5266-85-3 |
|
1,8-Diphenyl-1,3,5,7-octatetraene
| 3029-40-1 |
|
3-Cyanoindole, 98%
| 5457-28-3 |
|
Methyl 4-(bromomethyl)benzoate, 98%
| 2417-72-3 |
|
|