**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 23521-49-5 |cis-1-Bromo-2-ethoxyethylene | 95 | 245-712-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May be harmful if swallowed.
Inhalation:
May be harmful if inhaled. Vapors may cause dizziness or
suffocation. Causes upper respiratory tract irritation. Causes
irritation of the mucous membrane.
Chronic:
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Will
burn if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep away from heat, sparks and flame.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 23521-49-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: gold
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 134.0 - 137.0 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 48 deg C ( 118.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4310g/cm3
Molecular Formula: C4H7BrO
Molecular Weight: 151.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 23521-49-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-1-Bromo-2-ethoxyethylene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 23521-49-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 23521-49-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 23521-49-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/04/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Triphenylmethane, 99+% (GC)
| 519-73-3 |
|
cis-1-Bromo-2-ethoxyethylene, 95%
| 23521-49-5 |
|
p-Hexylbenzaldehyde diethyl acetal, 99%
| |
|
4-Hexyloxybenzaldehyde, 99%
| 5736-94-7 |
|
3-(4-methoxybenzoyl)propionic acid, 97%
| 3153-44-4 |
|
2,5-Bis-(4-Pyridyl)-1,3,4-Thiadiazole, 95%
| 15311-09-8 |
|
Silver tetrafluoroborate, 99%
| 14104-20-2 |
|
DL-2-Bromohexanoic acid, 97%
| 616-05-7 |
|
Cytidine 5'-Triphosphate, Disodium Salt Dihydrate
| 81012-87-5 |
|
Poly(acrylic acid), 63 wt.% aqueous solution
| 7732-18-5 |
|
Ethyl DL-2-Hydroxycaproate, 97%
| 6946-90-3 |
|
4-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99%
| 10139-02-3 |
|
4-Nitroquinoline-n-oxide, 98%
| 56-57-5 |
|
2-Aminoanthracene, Tech., 92% (HPLC)
| 613-13-8 |
|
2,3-Dimethyl-1-(4-methylphenyl)-3- pyrazolin-5-one, 99+%
| 56430-08-1 |
|
n-Methylethylenediamine, 95%
| 109-81-9 |
|
2,2-Dimethyl-5-(2-Hexahydroazepinylidene)-1,3-Dioxan-4,6-Dione, 99+%
| 70912-54-8 |
|
Thiophosphoryl Chloride, 98%
| 3982-91-0 |
|
1,2,3,6-Tetrahydrobenzaldehyde, 99%
| 100-50-5 |
|
6-Aminoindazole, 97+%
| 6967-12-0 |
|
N-Cyclohexylformamide, 99%
| 766-93-8 |
|
Quinhydrone, 98%
| 106-34-3 |
|
4-Bromobenzophenone, 97%
| 90-90-4 |
|
d-alpha-Tocopheryl polyethylene glycol 1000 succinate
| 9002-96-4 |
|
Direct Yellow 27
| 10190-68-8 |
|
3,4,5-Trimethoxybenzaldehyde, 99%
| 86-81-7 |
|
2-Chloroethyl Ethyl Ether, 98+%
| 628-34-2 |
|
Isobutyraldehyde, 99+% (GC)
| 78-84-2 |
|
Potassium nitrosodisulfonate
| 14293-70-0 |
|
4-Amino-3-Methylbenzoic Acid, 98%
| 2486-70-6 |
|
3,4-Diaminobenzoic acid, 97%
| 619-05-6 |
|
3,5-Dichloroaniline, 98%
| 626-43-7 |
|
3'-Bromo-4'-Fluoropropiophenone, 98%
| 0-00-1 |
|
D-(+)-2-Amino-3-Phenyl-1-Propanol, 98%
| 5267-64-1 |
|
2-Furoic Acid, 98%
| 88-14-2 |
|
Diphenyl n-cyanocarbonimidate, 97%
| 79463-77-7 |
|
Sulfamethazine, 99%
| 57-68-1 |
|
L-Histidinol Dihydrochloride, 99%
| 1596-64-1 |
|
Vanadium atomic absorption standard solution, 1 mg/ml V in 2% HNO3
| 7440-62-2 |
|
Crotonaldehyde, 99+%
| 4170-30-3 |
|
1,6-Dicyanohexane, 99%
| 629-40-3 |
|
Azidotrimethylsilane, 97%
| 4648-54-8 |
|
2-Ethyl-3-methylbutanal, 97%
| 26239-55-4 |
|
1,2,4-Benzenetriol, 99%
| 533-73-3 |
|
Gold Atomic Absorption Standard Solution 1 mg/ml Au in 0.5N HCl
| 7440-57-5 |
|
Dimethyl Terephthalate , 99%
| 120-61-6 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt (Pract), 90%
| 7732-18-5 |
|
2,2-Diethyl-1,3-Propanediol, 99+%
| 115-76-4 |
|
2'-Deoxyadenosine Hydrate, 99%
| 16373-93-6 |
|
DL-(2-Fluorophenyl)-Alanine, 99%
| 2629-55-2 |
|
|