**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4648-54-8 |Azidotrimethylsilane | 97 | 225-078-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 10 23/24/25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. Ingestion of large amounts may cause
CNS depression.
Inhalation:
May cause respiratory tract irritation. May cause headache,
dizziness, blurred vision, decreased blood pressure, and slowed
pulse. Harmful if inhaled.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively. Individuals who are using
medication to control their blood pressure should not work with or
come in contact with this product. This substance can release
hydrazoic acid which is known to cause a drop in blood pressure.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Use only in a chemical fume hood. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from sources of ignition. Refrigerator/flammables. Storage
under a nitrogen blanket has been recommended. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 4648-54-8:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 52.0 - 53.0 deg C @ 175 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: 300 deg C ( 572.00 deg F)
Flash Point: 23 deg C ( 73.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 0.8680 g/cm3
Molecular Formula: C3H9N3Si
Molecular Weight: 115.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Moisture sensitive.
Conditions to Avoid:
Ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of silicon.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4648-54-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Azidotrimethylsilane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.*(Forbid.
By Air)
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2929
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4648-54-8: No information available.
Canada
CAS# 4648-54-8 is listed on Canada's NDSL List.
CAS# 4648-54-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4648-54-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/30/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
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Triphenylmethane, 99+% (GC)
| 519-73-3 |
|
cis-1-Bromo-2-ethoxyethylene, 95%
| 23521-49-5 |
|
p-Hexylbenzaldehyde diethyl acetal, 99%
| |
|
4-Hexyloxybenzaldehyde, 99%
| 5736-94-7 |
|
3-(4-methoxybenzoyl)propionic acid, 97%
| 3153-44-4 |
|
2,5-Bis-(4-Pyridyl)-1,3,4-Thiadiazole, 95%
| 15311-09-8 |
|
Silver tetrafluoroborate, 99%
| 14104-20-2 |
|
DL-2-Bromohexanoic acid, 97%
| 616-05-7 |
|
Cytidine 5'-Triphosphate, Disodium Salt Dihydrate
| 81012-87-5 |
|
Poly(acrylic acid), 63 wt.% aqueous solution
| 7732-18-5 |
|
Ethyl DL-2-Hydroxycaproate, 97%
| 6946-90-3 |
|
4-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99%
| 10139-02-3 |
|
4-Nitroquinoline-n-oxide, 98%
| 56-57-5 |
|
2-Aminoanthracene, Tech., 92% (HPLC)
| 613-13-8 |
|
2,3-Dimethyl-1-(4-methylphenyl)-3- pyrazolin-5-one, 99+%
| 56430-08-1 |
|
n-Methylethylenediamine, 95%
| 109-81-9 |
|
2,2-Dimethyl-5-(2-Hexahydroazepinylidene)-1,3-Dioxan-4,6-Dione, 99+%
| 70912-54-8 |
|
Thiophosphoryl Chloride, 98%
| 3982-91-0 |
|
1,2,3,6-Tetrahydrobenzaldehyde, 99%
| 100-50-5 |
|
6-Aminoindazole, 97+%
| 6967-12-0 |
|
N-Cyclohexylformamide, 99%
| 766-93-8 |
|
Quinhydrone, 98%
| 106-34-3 |
|
4-Bromobenzophenone, 97%
| 90-90-4 |
|
d-alpha-Tocopheryl polyethylene glycol 1000 succinate
| 9002-96-4 |
|
Direct Yellow 27
| 10190-68-8 |
|
3,4,5-Trimethoxybenzaldehyde, 99%
| 86-81-7 |
|
2-Chloroethyl Ethyl Ether, 98+%
| 628-34-2 |
|
Isobutyraldehyde, 99+% (GC)
| 78-84-2 |
|
Potassium nitrosodisulfonate
| 14293-70-0 |
|
4-Amino-3-Methylbenzoic Acid, 98%
| 2486-70-6 |
|
3,4-Diaminobenzoic acid, 97%
| 619-05-6 |
|
3,5-Dichloroaniline, 98%
| 626-43-7 |
|
3'-Bromo-4'-Fluoropropiophenone, 98%
| 0-00-1 |
|
D-(+)-2-Amino-3-Phenyl-1-Propanol, 98%
| 5267-64-1 |
|
2-Furoic Acid, 98%
| 88-14-2 |
|
Diphenyl n-cyanocarbonimidate, 97%
| 79463-77-7 |
|
Sulfamethazine, 99%
| 57-68-1 |
|
L-Histidinol Dihydrochloride, 99%
| 1596-64-1 |
|
Vanadium atomic absorption standard solution, 1 mg/ml V in 2% HNO3
| 7440-62-2 |
|
Crotonaldehyde, 99+%
| 4170-30-3 |
|
1,6-Dicyanohexane, 99%
| 629-40-3 |
|
Azidotrimethylsilane, 97%
| 4648-54-8 |
|
2-Ethyl-3-methylbutanal, 97%
| 26239-55-4 |
|
1,2,4-Benzenetriol, 99%
| 533-73-3 |
|
Gold Atomic Absorption Standard Solution 1 mg/ml Au in 0.5N HCl
| 7440-57-5 |
|
Dimethyl Terephthalate , 99%
| 120-61-6 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt (Pract), 90%
| 7732-18-5 |
|
2,2-Diethyl-1,3-Propanediol, 99+%
| 115-76-4 |
|
2'-Deoxyadenosine Hydrate, 99%
| 16373-93-6 |
|
DL-(2-Fluorophenyl)-Alanine, 99%
| 2629-55-2 |
|
|