**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 25895-60-7 |Sodium cyanoborohydride | 95% | 247-317-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 15 23/24/25 32 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Contact with water liberates extremely flammable
gases. Toxic by inhalation, in contact with skin and if swallowed.
Contact with acids liberates very toxic gas. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable solid. Contact with water liberates
highly flammable gases.
Extinguishing Media:
DO NOT USE WATER! Use dry powder or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Cover with sand, dry lime or soda ash and place in a closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Water free area. Keep away from acids. Store under nitrogen. Keep
away from oxidizing agents.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 25895-60-7:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white or yellow
Odor: Not available.
pH: 8-9 (10% aq. sol.)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: >242 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 212 g/100ml water (29C)
Specific Gravity/Density:
Molecular Formula: CH3BNNa
Molecular Weight: 62.84
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, acids, exposure to moist air or water,
oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents, acids.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
oxides of boron, hydrogen gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 25895-60-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium cyanoborohydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.*
Hazard Class: 4.3
UN Number: 3134
Packing Group: II
IMO
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3
UN Number: 3134
Packing Group: II
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3
UN Number: 3134
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 15 Contact with water liberates extremely
flammable gases.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 32 Contact with acids liberates very toxic gas.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 25895-60-7: 2
Canada
CAS# 25895-60-7 is listed on Canada's NDSL List.
CAS# 25895-60-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25895-60-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/20/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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(R)-(+)-4-Hexyl-2,2-dimethyl-[1,3]-dioxane
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N,N''-(Methylenedi-4,1-phenylene)bis[N',2-(2-ethoxy)ethanol]urea
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4-Cyano-Phenylglyoxylic Acid Ethyl Ester
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3-Chloropropiophenone, 95%
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| 00-01-1 |
|
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| 369402-96-0 |
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| 372144-00-8 |
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Chloroform
| 67-66-3 |
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| 372144-18-8 |
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| 284493-67-0 |
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3-N-BOC-Amino-3-(4-methoxyphenyl)propionic acid
| 96363-20-1 |
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| 368866-07-3 |
|
1-(3-PYRIDINYL)-2-HYDROXYETHYLAMINE
| 372144-01-9 |
|
2-Ethylhexanoic anhydride, 95+%
| 36765-89-6 |
|
N-BOC-AMINO-PIPERIDINYL-1,1-CARBOXYLIC ACID
| 252720-31-3 |
|
Cholesteryl Acetate, 97%
| 604-35-3 |
|
N-BOC-AMINO-(4-HYDROXYCYCLOHEXYL)CARBOXYLIC ACID
| 369403-08-7 |
|
Poly(titanium(iv)n-butoxide)
| 71-36-3 |
|
2-Bromo-3-methylbutyric acid, 98%
| 565-74-2 |
|
(R,R)-(-)-alpha,alpha'-Bis(trifluoromethyl)-9,10
| 00-01-1 |
|
(S,S)-(+)-alpha,alpha'-Bis(trifluoromethyl)-9,10
| 00-01-1 |
|
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| 00-01-1 |
|
L-Diacetyltartaric acid AM resin, 1% crosslinked with DVB, 0.9-1.1
| 00-01-1 |
|
L-Tartaric acid methyl ester AM resin, 1% DVB, 0.9-1.1 mmol/g,
| 00-01-1 |
|
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| 00-01-1 |
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| 87-72-9 |
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| 162753-00-6 |
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| 50982-13-3 |
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Dibromo-bis(diphenylphosphino)ethane ruthenium(II) dimer
| 00-01-1 |
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5-Methoxyindole, 99%
| 1006-94-6 |
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2,6-Bis(diphenylphosphino)pyridine
| 64741-27-1 |
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Ammonium hexachlororhodate(iii), 99.99%
| 15336-18-2 |
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| 25895-60-7 |
|
|