**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 71-36-3 |n-Butanol | <1% | 200-751-6 |
|----------------|--------------------------------------|----------|-----------|
| 92045-53-9 |Nafta | <1% | 295-434-2 |
|----------------|--------------------------------------|----------|-----------|
| 162303-51-7 |Poly(titanium(IV)n-butoxide) | >98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 10 38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to skin. Risk of serious damage to
eyes.Moisture sensitive.
Potential Health Effects
Eye:
Risk of serious damage to eyes.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
May cause nausea, dizziness, and headache.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 71-36-3:
United Kingdom, WEL - STEL: 50 ppm STEL; 154 mg/m3 STEL
United States OSHA: 100 ppm TWA; 300 mg/m3 TWA
Belgium - TWA: 50 ppm VLE; 154 mg/m3 VLE
France - VLE: 50 ppm VLE; 150 mg/m3 VLE
Germany: 100 ppm TWA; 310 mg/m3 TWA
Japan: 50 ppm Ceiling; 150 mg/m3 Ceiling
Malaysia: 50 ppm Ceiling; 152 mg/m3 Ceiling
Netherlands: 15 ppm STEL; 45 mg/m3 STEL
Russia: 10 mg/m3 TWA
Spain: 50 ppm VLA-EC; 154 mg/m3 VLA-EC
CAS# 92045-53-9:
CAS# 162303-51-7:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to pale yellow
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 1400 mPa.s @25 deg C
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 45 deg C ( 113.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.110
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water, temperatures above 40C.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71-36-3: EO1400000
CAS# 92045-53-9 unlisted.
CAS# 162303-51-7 unlisted.
LD50/LC50:
CAS# 71-36-3: Draize test, rabbit, eye: 2 mg Severe; Draize test,
rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 405 mg/24H
Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation,
rat: LC50 = 8000 ppm/4H; Inhalation, rat: LC50 = 24000 mg/m3/4H;
Oral, mouse: LD50 = 100 mg/kg; Oral, rabbit: LD50 = 3484 mg/kg;
Oral, rabbit: LD50 = 3400 mg/kg; Oral, rat: LD50 = 790 mg/kg; Oral,
rat: LD50 = 800 mg/kg; Skin, rabbit: LD50 = 3400 mg/kg.
CAS# 92045-53-9.
CAS# 162303-51-7.
Carcinogenicity:
n-Butanol -
Not listed by ACGIH, IARC, or NTP.
Nafta -
Not listed by ACGIH, IARC, or NTP.
Poly(titanium(IV)n-butoxide) -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
USA RQ: CAS# 71-36-3: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 71-36-3: 1
CAS# 92045-53-9: No information available.
CAS# 162303-51-7: No information available.
Canada
CAS# 71-36-3 is listed on Canada's DSL List.
CAS# 71-36-3 is listed on Canada's Ingredient Disclosure List.
CAS# 92045-53-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 162303-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71-36-3 is listed on the TSCA inventory.
CAS# 92045-53-9 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 162303-51-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/24/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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