**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-66-3 |Chloroform | 100 | 200-663-8
|----------------|--------------------------------------|----------|-----------|
| 25377-72-4 |Amylene | <1.0 | 246-916-6
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38 40 48/20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Limited evidence of a
carcinogenic effect. Harmful : danger of serious damage to health by
prolonged exposure through inhalation and if swallowed.Light
sensitive.
Potential Health Effects
Eye:
Causes moderate eye irritation. Contact with liquid causes
immediate burning pain, tearing, and reddening of the conjunctiva.
Skin:
Causes mild skin irritation. Prolonged or repeated contact may
dry/defat the skin and cause irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver damage. May cause cardiac disturbances.
Aspiration of material into the lungs may cause chemical pneumonitis,
which may be fatal. Possible aspiration hazard. May cause
hallucinations and distorted perceptions.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause cardiac sensitization and possible failure.
Inhalation of large amounts may cause respiratory stimulation,
followed by respiratory depression, convulsions and possible death
due to respiratory paralysis. May be absorbed through the lungs.
Causes irritation of the mucous membrane and upper respiratory
tract.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause dermatitis. May cause
reproductive and fetal effects. Effects may be delayed. Laboratory
experiments have resulted in mutagenic effects. Toxicity may be
increased by exposure to alcohol, steroids, and ketones. Prolonged
exposure may cause liver, kidney, and heart damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Causes cardiac sensitization to endogenous catelcholamines which may
lead to cardiac arrhythmias. Do NOT use adrenergic agents such as
epinephrine or pseudoepinephrine. Persons with liver, kidney, or
central nervous system diseases may be at increased risk from
exposure to this product. Alcoholic beverage consumption may enhance
the toxic effects of this substance. Effects may be delayed.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
nonflammable. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas. Containers may
explode when heated.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Do NOT get water inside containers. Do NOT use straight streams of
water. For small fires, use dry chemical, carbon dioxide, or water
spray. For large fires, use water spray, fog or regular foam. Cool
containers with flooding quantities of water until well after fire
is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or
gas. Do not ingest or inhale. Store protected from light.
Storage:
Do not store in direct sunlight. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not store
near alkaline substances. Separate from strong mineral acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: sweet, fruity odor - ethereal odor
pH: Not available.
Vapor Pressure: 160 mm Hg @ 20 deg C
Viscosity: 0.58 cps @ 20 deg C
Boiling Point: 60.5-61.5 deg C
Freezing/Melting Point: -63 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.492 (Water=1)
Molecular Formula: CHCl3
Molecular Weight: 119.366
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Light sensitive.
Conditions to Avoid:
High temperatures, incompatible materials, light.
Incompatibilities with Other Materials:
Sodium + methanol, acetone + alkali, aluminum, disilane, lithium,
magnesium, nitrogen tetroxide, perchloric acid + phosphorus
pentoxide, potassium-tert-butoxide, sodium methylate, sodium
potassium, dinitrogen tetraoxide, fluorine, chemically active
metals, triisopropylphosphine, sodium methoxide + methanol, caustics
(e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium
hydroxide, sodium hydroxide), strong oxidizing agents, Attacks some
forms of plastics, rubbers, and coatings..
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, carbon
dioxide, chlorine, phosgene gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-66-3: FS9100000
CAS# 25377-72-4 unlisted.
LD50/LC50:
CAS# 67-66-3: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 47702
mg/m3/4H; Oral, mouse: LD50 = 36 mg/kg; Oral, rat: LD50 = 695 mg/kg;
Skin, rabbit: LD50 = >20 gm/kg.
CAS# 25377-72-4.
Carcinogenicity:
Chloroform -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Amylene -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Channel catfish: LC50 = 75 ppm; 96 Hr; UnspecifiedFish: Rainbow
trout: LC50 = 43.8 mg/L; 96 Hr; Static bioassayFish: Fathead Minnow:
LC50 = 129.0 mg/L; 96 Hr; Static bioassay (pH = 7.6-8.3)Fish:
Bluegill/Sunfish: LC50 = 100.0 mg/L; 96 Hr; Static bioassayWater
flea Daphnia: EC50 = 28.9 mg/L; 48 Hr; Static bioassayThe majority of
the environmental releases from industrial uses are to the
atmosphere; releases to water and land will be primarily lost by
evaporation and will end up in the atmosphere. Release to the
atmosphere may be transported long distances and will photodegrade
with a half-life of a
few months. Spills and other releases on land
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 40 Limited evidence of a carcinogenic effect.
R 48/20/22 Harmful : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 67-66-3: 3
CAS# 25377-72-4: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67-66-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 25377-72-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-66-3: OEL-ARAB Republic of Egypt:TWA 10 ppm (50 mg/m3)
OEL-AUSTRALIA:TWA 10 ppm (50 mg/m3);Carcinogen
OEL-AUSTRIA:TWA 10 ppm (50 mg/m3)
OEL-BELGIUM:TWA 10 ppm (49 mg/m3);Carcinogen JAN9
OEL-CZECHOSLOVAKIA:TWA 10 mg/m3;STEL 20 mg/m3
OEL-DENMARK:TWA 2 ppm (10 mg/m3);Carcinogen
OEL-FINLAND:TWA 10 ppm (50 mg/m3);STEL 20 ppm;Skin;CAR
OEL-FRANCE:TWA 5 ppm (25 mg/m3);STEL 50 ppm (250 mg/m3);CAR
OEL-GERMANY:TWA 10 ppm (50 mg/m3);Carcinogen JAN9
OEL-HUNGARY:STEL 10 mg/m3
OEL-INDIA:TWA 10 ppm (50 mg/m3);Carcinogen
OEL-JAPAN:TWA 50 ppm (240 mg/m3);Carcinogen
OEL-THE NETHERLANDS:TWA 10 ppm (50 mg/m3)
OEL-THE PHILIPPINES:TWA 50 ppm (240 mg/m3)
OEL-POLAND:TWA 50 mg/m3
OEL-RUSSIA:TWA 50 ppm
OEL-SWEDEN:TWA 2 ppm (10 mg/m3);STEL 5 ppm (25 mg/m3);CAR
OEL-SWITZERLAND:TWA 10 ppm (50 mg/m3);STEL 20 ppm (100 mg/m3)
OEL-THAILAND:TWA 50 ppm (240 mg/m3)
OEL-TURKEY:TWA 50 ppm (240 mg/m3)
OEL-UNITED KINGDOM:TWA 10 ppm (50 mg/m3);STEL 50 ppm (225 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 67-66-3 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 25377-72-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/09/1999 Revision #7 Date: 9/11/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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