**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 529-33-9 |1,2,3,4-Tetrahydro-1-Naphthol | 85+% | 208-459-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 529-33-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Viscous liquid
Color: clear, colorless - slightly brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 102 - 104 deg C @ 2.00mm Hg
Freezing/Melting Point: 28 - 32 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0900g
Molecular Formula: C10H12O
Molecular Weight: 148.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 529-33-9: QL5075000
LD50/LC50:
CAS# 529-33-9: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 1620 mg/kg.
Carcinogenicity:
1,2,3,4-Tetrahydro-1-Naphthol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 529-33-9: 2
Canada
CAS# 529-33-9 is listed on Canada's NDSL List.
CAS# 529-33-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 529-33-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/08/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Dimethylamino-2-Propyne
| 7223-38-3 |
|
(R)-(-)-3-Hydroxynonanal Dimethyl Acetal
| 272122-72-2 |
|
(R)-(-)-1,3-Nonanediol
| 23433-07-0 |
|
(R)-(+)-4-Hexyl-2,2-dimethyl-[1,3]-dioxane
| 139008-44-9 |
|
N,N''-(Methylenedi-4,1-phenylene)bis[N',2-(2-ethoxy)ethanol]urea
| 0-01-1 |
|
4-Cyano-Phenylglyoxylic Acid Ethyl Ester
| 302912-31-8 |
|
trans-beta-Styrenesulfonyl Chloride
| 52147-97-4 |
|
1-[1-(4-Chlorophenyl)Cyclobutyl]-3-Methylisobutylamine Citrate
| 84467-54-9 |
|
1,2,3,4-Tetrahydro-1-Naphthol, 85+%
| 529-33-9 |
|
3-Chloropropiophenone, 95%
| 936-59-4 |
|
Harmol hydrochloride monohydrate, 98%
| 40580-83-4 |
|
Di(1-benzotriazolyl)carbonate, 65%, 1,1,2-trichloroethane, 35%
| 79-00-5 |
|
6-Chloroimidazo[2,1-b]thiazole
| 23576-81-0 |
|
Bis-(6-carboxy-HOBt)-N-(2-aminoethyl) PS resin, 1% DVB, 1.3-1.7
| 00-01-1 |
|
(+/-)-NH4-4-Furyl-3-hydroxy-azetidin-2-one
| 00-01-1 |
|
4-N-FMOC-Amino-4-Carboxy-1,1-Dioxa-Tetrahydrothiopyran
| 369402-96-0 |
|
N-BOC-Amino-(3-Thienyl)Acetic Acid
| 40512-57-0 |
|
3-N-BOC-Amino-3-(4-fluorophenyl)propionic acid
| 284493-72-7 |
|
3-N-FMOC-Amino-3-(3-t-Butoxyphenyl)Propionic Acid
| 372144-16-6 |
|
N-FMOC-Amino-4-Ketocyclohexylcarboxylic Acid
| 285996-74-9 |
|
1-(3,5-DICHLOROPHENYL)-2-HYDROXYETHYLAMINE
| 372144-00-8 |
|
Chloroform
| 67-66-3 |
|
3-N-FMOC-AMINO-3-(2-T-BUTOXYPHENYL)PROPIONIC ACID
| 372144-18-8 |
|
3-N-BOC-AMINO-3-(3-CHLOROPHENYL)PROPIONIC ACID
| 284493-67-0 |
|
3-N-BOC-Amino-3-(4-methoxyphenyl)propionic acid
| 96363-20-1 |
|
N-BOC-AMINO-(4-N-FMOC-PIPERIDINYL)CARBOXYLIC ACID
| 368866-07-3 |
|
1-(3-PYRIDINYL)-2-HYDROXYETHYLAMINE
| 372144-01-9 |
|
2-Ethylhexanoic anhydride, 95+%
| 36765-89-6 |
|
N-BOC-AMINO-PIPERIDINYL-1,1-CARBOXYLIC ACID
| 252720-31-3 |
|
Cholesteryl Acetate, 97%
| 604-35-3 |
|
N-BOC-AMINO-(4-HYDROXYCYCLOHEXYL)CARBOXYLIC ACID
| 369403-08-7 |
|
Poly(titanium(iv)n-butoxide)
| 71-36-3 |
|
2-Bromo-3-methylbutyric acid, 98%
| 565-74-2 |
|
(R,R)-(-)-alpha,alpha'-Bis(trifluoromethyl)-9,10
| 00-01-1 |
|
(S,S)-(+)-alpha,alpha'-Bis(trifluoromethyl)-9,10
| 00-01-1 |
|
1-Hydroxybenzotriazole AM resin, 1% DVB, 0.8-1.2 mmol/g, 100-200 mesh
| 00-01-1 |
|
L-Diacetyltartaric acid AM resin, 1% crosslinked with DVB, 0.9-1.1
| 00-01-1 |
|
L-Tartaric acid methyl ester AM resin, 1% DVB, 0.9-1.1 mmol/g,
| 00-01-1 |
|
N-Cyclohexylcarbodiimide PS resin, 1% DVB, 0.8-1.2 mmol/g, 100-200
| 00-01-1 |
|
L(+)-Arabinose
| 87-72-9 |
|
3,4-Dimethyl-1,2-Cyclopentanedione, 97%
| 13494-06-9 |
|
2-Chloro-6-(diphenylphosphino)pyridine
| 162753-00-6 |
|
Dichloro(cycloocta-1,5-diene)ruthenium(II) polymer
| 50982-13-3 |
|
Dibromo-bis(diphenylphosphino)ethane ruthenium(II) dimer
| 00-01-1 |
|
5-Methoxyindole, 99%
| 1006-94-6 |
|
2,6-Bis(diphenylphosphino)pyridine
| 64741-27-1 |
|
Ammonium hexachlororhodate(iii), 99.99%
| 15336-18-2 |
|
Bis(diphenylphosphino)ethane-bis(2-methylallyl)ruthenium(II)
| 139060-44-9 |
|
HATU, 99%
| 148893-10-1 |
|
Sodium cyanoborohydride, 95%
| 25895-60-7 |
|
|