**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 32315-10-9 |Triphosgene | 99.0 | 250-986-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.Moisture sensitive.Lachrymator (substance which
increases the flow of tears).
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Lachrymator
(substance which increases the flow of tears).
Skin:
May cause skin irritation. Toxic in contact with skin.
Ingestion:
Poison by ingestion. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. The toxicological properties of this
substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Toxic if inhaled.
Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Get medical
aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Do not allow contact with water. Keep from contact
with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 32315-10-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white to off-white
Odor: none reported
pH: Not available.
Vapor Pressure: 1010 mbar @ 206
Viscosity: Not available.
Boiling Point: 203.0 - 206.0 deg C @ 760.00m
Freezing/Melting Point: 77.00 - 80.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >350 deg C
Solubility in water: practically insoluble
Specific Gravity/Density:
Molecular Formula: C3Cl6O3
Molecular Weight: 296.75
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, acids, amines.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 32315-10-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Triphosgene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 7 Keep container tightly closed.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 32315-10-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 32315-10-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 32315-10-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1998 Revision #5 Date: 2/28/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Penten-2-Ol, 96%, Predominatly Trans
| 1569-50-2 |
|
4-Fluoro-3-Nitrobenzoic Acid, 98%
| 453-71-4 |
|
Thymoquinone, 99%
| 490-79-9 |
|
1-Methallyl-3-Methyl-2-Thiourea, 98%
| 21018-38-2 |
|
3,4-Diethoxy-3-Cyclobutene-1,2-Dione, 98%
| 5231-87-8 |
|
4-Propoxybenzoic Acid, 98%
| 5438-19-7 |
|
N-METHYLPHTHALIMIDE, 98%
| 550-44-7 |
|
2,3-Dimethylhydroquinone, 99%
| 608-43-5 |
|
N-(2-Carboxyphenyl)glycine, 97%
| 612-42-0 |
|
3,3,5-Trimethylhexahydroazepine, 98%, mixture of isomers
| 35466-89-8 |
|
Triphosgene, 99% (Titr.)
| 32315-10-9 |
|
2,2-Dichloropropionic Acid, Tech., 90%
| 75-99-0 |
|
2-Phenylbenzoxazole, 99%
| 833-50-1 |
|
5-Chloro-1-Methylimidazole, 98%
| 872-49-1 |
|
2-Allylcyclohexanone, 97%
| 94-66-6 |
|
1,2-bis(dimethylphosphino)ethane, 97%
| 23936-60-9 |
|
Trans-1,2-Bis(Diphenylphosphino)Ethylene, 97%
| 983-81-3 |
|
1,3-Bis(Diphenylphosphino)Propane, 97%
| 6737-42-4 |
|
Bis(2-Oxo-3-Oxazolidinyl)phosphinic Chloride, 97%
| 68641-49-6 |
|
o-(tert-Butyldimethylsilyl)hydroxylamine, 95%
| 41879-39-4 |
|
Diethylphenylphosphine, 98%
| 1605-53-4 |
|
Diethylphosphoramidous Dichloride, 97%
| 1069-08-5 |
|
Dimethylphenylphosphine, 97%
| 672-66-2 |
|
Terbium(iii,iv)-oxide, 99.999%
| 12037-01-3 |
|
Dimethylphosphinic Acid, 97%
| 3283-12-3 |
|
Diphenylphosphine Oxide, 97%
| 4559-70-0 |
|
Diethyl (2-Chloroethyl)phosphonate, 95%
| 10419-79-1 |
|
Tributylgermane, 99%
| 998-39-0 |
|
Methylphosphonic dichloride, 98%
| 676-97-1 |
|
Propylphosphonic acid, 95%
| 4672-38-2 |
|
DIPHENYL(TRIMETHYLSILYL)PHOSPHINE, TECH.
| 17154-34-6 |
|
Sodium Sulfide
| 1313-82-2 |
|
Germanium(iv)ethoxide, 99.95+%
| 14165-55-0 |
|
Dimethyl(4r,5r)-1,3,2-dioxathiolane-4,5- dicarboxylate 2,2-dioxide,
| 117470-90-3 |
|
(s)-(+)-Phenylglycinol, 98%
| 20989-17-7 |
|
(1s,2s)-(+)-1,2-Diaminocyclohexane, 98%
| 21436-03-3 |
|
1- Phenylisatin
| 723-89-7 |
|
(+)-Menthoxyacetic Acid, 98%
| 94133-41-2 |
|
Trans-Chrysanthemyl Alcohol,98%, Mixture of ca. 10% Cis and ca.90%
| 5617-92-5 |
|
Neocyanine, 99% (UV-VIS)
| 4846-34-8 |
|
2-Isopropoxyphenol, 97%
| 4812-20-8 |
|
4,6-Dihydroxy-5-Nitropyrimidine, 95%
| 2164-83-2 |
|
Dehydrocholic acid, 98%
| 81-23-2 |
|
2-Thiophenecarboxamide, 99%
| 5813-89-8 |
|
Lactobionic acid, 97%
| 96-82-2 |
|
4,4'-Diacetylbiphenyl, 98%
| 787-69-9 |
|
4-Hexylaniline, Tech., 90%
| 33228-45-4 |
|
2-Bromo-4'-Nitroacetophenone, Tech., 83% (GC)
| 99-81-0 |
|
Vinblastine sulfate, 96.0-102.0% (hplc)
| 143-67-9 |
|
2,3-Dimethyl-6-Nitroaniline, 97%
| 59146-96-2 |
|
|