**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4672-38-2 |Propylphosphonic acid | 95% | 225-121-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Hygroscopic.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 67 - 71 deg C
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C3H9O3P
Molecular Weight: 124.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4672-38-2: TA0420000
LD50/LC50:
Not available.
Carcinogenicity:
Propylphosphonic acid -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Dangerous Goods Code: 8(39B)
UN Number: 3261
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 4672-38-2: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 4672-38-2 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 4672-38-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/14/1996 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Penten-2-Ol, 96%, Predominatly Trans
| 1569-50-2 |
|
4-Fluoro-3-Nitrobenzoic Acid, 98%
| 453-71-4 |
|
Thymoquinone, 99%
| 490-79-9 |
|
1-Methallyl-3-Methyl-2-Thiourea, 98%
| 21018-38-2 |
|
3,4-Diethoxy-3-Cyclobutene-1,2-Dione, 98%
| 5231-87-8 |
|
4-Propoxybenzoic Acid, 98%
| 5438-19-7 |
|
N-METHYLPHTHALIMIDE, 98%
| 550-44-7 |
|
2,3-Dimethylhydroquinone, 99%
| 608-43-5 |
|
N-(2-Carboxyphenyl)glycine, 97%
| 612-42-0 |
|
3,3,5-Trimethylhexahydroazepine, 98%, mixture of isomers
| 35466-89-8 |
|
Triphosgene, 99% (Titr.)
| 32315-10-9 |
|
2,2-Dichloropropionic Acid, Tech., 90%
| 75-99-0 |
|
2-Phenylbenzoxazole, 99%
| 833-50-1 |
|
5-Chloro-1-Methylimidazole, 98%
| 872-49-1 |
|
2-Allylcyclohexanone, 97%
| 94-66-6 |
|
1,2-bis(dimethylphosphino)ethane, 97%
| 23936-60-9 |
|
Trans-1,2-Bis(Diphenylphosphino)Ethylene, 97%
| 983-81-3 |
|
1,3-Bis(Diphenylphosphino)Propane, 97%
| 6737-42-4 |
|
Bis(2-Oxo-3-Oxazolidinyl)phosphinic Chloride, 97%
| 68641-49-6 |
|
o-(tert-Butyldimethylsilyl)hydroxylamine, 95%
| 41879-39-4 |
|
Diethylphenylphosphine, 98%
| 1605-53-4 |
|
Diethylphosphoramidous Dichloride, 97%
| 1069-08-5 |
|
Dimethylphenylphosphine, 97%
| 672-66-2 |
|
Terbium(iii,iv)-oxide, 99.999%
| 12037-01-3 |
|
Dimethylphosphinic Acid, 97%
| 3283-12-3 |
|
Diphenylphosphine Oxide, 97%
| 4559-70-0 |
|
Diethyl (2-Chloroethyl)phosphonate, 95%
| 10419-79-1 |
|
Tributylgermane, 99%
| 998-39-0 |
|
Methylphosphonic dichloride, 98%
| 676-97-1 |
|
Propylphosphonic acid, 95%
| 4672-38-2 |
|
DIPHENYL(TRIMETHYLSILYL)PHOSPHINE, TECH.
| 17154-34-6 |
|
Sodium Sulfide
| 1313-82-2 |
|
Germanium(iv)ethoxide, 99.95+%
| 14165-55-0 |
|
Dimethyl(4r,5r)-1,3,2-dioxathiolane-4,5- dicarboxylate 2,2-dioxide,
| 117470-90-3 |
|
(s)-(+)-Phenylglycinol, 98%
| 20989-17-7 |
|
(1s,2s)-(+)-1,2-Diaminocyclohexane, 98%
| 21436-03-3 |
|
1- Phenylisatin
| 723-89-7 |
|
(+)-Menthoxyacetic Acid, 98%
| 94133-41-2 |
|
Trans-Chrysanthemyl Alcohol,98%, Mixture of ca. 10% Cis and ca.90%
| 5617-92-5 |
|
Neocyanine, 99% (UV-VIS)
| 4846-34-8 |
|
2-Isopropoxyphenol, 97%
| 4812-20-8 |
|
4,6-Dihydroxy-5-Nitropyrimidine, 95%
| 2164-83-2 |
|
Dehydrocholic acid, 98%
| 81-23-2 |
|
2-Thiophenecarboxamide, 99%
| 5813-89-8 |
|
Lactobionic acid, 97%
| 96-82-2 |
|
4,4'-Diacetylbiphenyl, 98%
| 787-69-9 |
|
4-Hexylaniline, Tech., 90%
| 33228-45-4 |
|
2-Bromo-4'-Nitroacetophenone, Tech., 83% (GC)
| 99-81-0 |
|
Vinblastine sulfate, 96.0-102.0% (hplc)
| 143-67-9 |
|
2,3-Dimethyl-6-Nitroaniline, 97%
| 59146-96-2 |
|
|