**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 676-97-1 |Methylphosphonic dichloride | 98% | 211-634-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Causes
burns.The toxicological properties of this material have not been
fully investigated.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns. The
toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Not flammable, but reacts with most metals to form
flammable hydrogen gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Handle under an inert atmosphere. Use only in a
chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 676-97-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 760 mm Hg @ 163
Viscosity: Not available.
Boiling Point: 163 deg C @ 760.00mm Hg
Freezing/Melting Point: 35 - 37 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4680g/cm3
Molecular Formula: CH3Cl2OP
Molecular Weight: 132.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases - strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus,
carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 676-97-1: TA1840000
LD50/LC50:
CAS# 676-97-1: Inhalation, rat: LC50 = 26 ppm/4H.
Carcinogenicity:
Methylphosphonic dichloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.*
Hazard Class: 6.1 (8)
UN Number: 2928
Packing Group: I
IMO
Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1 (8)
UN Number: 2928
Packing Group: I
RID/ADR
Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2928
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 676-97-1: No information available.
Canada
CAS# 676-97-1 is listed on Canada's NDSL List.
CAS# 676-97-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 676-97-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Penten-2-Ol, 96%, Predominatly Trans
| 1569-50-2 |
|
4-Fluoro-3-Nitrobenzoic Acid, 98%
| 453-71-4 |
|
Thymoquinone, 99%
| 490-79-9 |
|
1-Methallyl-3-Methyl-2-Thiourea, 98%
| 21018-38-2 |
|
3,4-Diethoxy-3-Cyclobutene-1,2-Dione, 98%
| 5231-87-8 |
|
4-Propoxybenzoic Acid, 98%
| 5438-19-7 |
|
N-METHYLPHTHALIMIDE, 98%
| 550-44-7 |
|
2,3-Dimethylhydroquinone, 99%
| 608-43-5 |
|
N-(2-Carboxyphenyl)glycine, 97%
| 612-42-0 |
|
3,3,5-Trimethylhexahydroazepine, 98%, mixture of isomers
| 35466-89-8 |
|
Triphosgene, 99% (Titr.)
| 32315-10-9 |
|
2,2-Dichloropropionic Acid, Tech., 90%
| 75-99-0 |
|
2-Phenylbenzoxazole, 99%
| 833-50-1 |
|
5-Chloro-1-Methylimidazole, 98%
| 872-49-1 |
|
2-Allylcyclohexanone, 97%
| 94-66-6 |
|
1,2-bis(dimethylphosphino)ethane, 97%
| 23936-60-9 |
|
Trans-1,2-Bis(Diphenylphosphino)Ethylene, 97%
| 983-81-3 |
|
1,3-Bis(Diphenylphosphino)Propane, 97%
| 6737-42-4 |
|
Bis(2-Oxo-3-Oxazolidinyl)phosphinic Chloride, 97%
| 68641-49-6 |
|
o-(tert-Butyldimethylsilyl)hydroxylamine, 95%
| 41879-39-4 |
|
Diethylphenylphosphine, 98%
| 1605-53-4 |
|
Diethylphosphoramidous Dichloride, 97%
| 1069-08-5 |
|
Dimethylphenylphosphine, 97%
| 672-66-2 |
|
Terbium(iii,iv)-oxide, 99.999%
| 12037-01-3 |
|
Dimethylphosphinic Acid, 97%
| 3283-12-3 |
|
Diphenylphosphine Oxide, 97%
| 4559-70-0 |
|
Diethyl (2-Chloroethyl)phosphonate, 95%
| 10419-79-1 |
|
Tributylgermane, 99%
| 998-39-0 |
|
Methylphosphonic dichloride, 98%
| 676-97-1 |
|
Propylphosphonic acid, 95%
| 4672-38-2 |
|
DIPHENYL(TRIMETHYLSILYL)PHOSPHINE, TECH.
| 17154-34-6 |
|
Sodium Sulfide
| 1313-82-2 |
|
Germanium(iv)ethoxide, 99.95+%
| 14165-55-0 |
|
Dimethyl(4r,5r)-1,3,2-dioxathiolane-4,5- dicarboxylate 2,2-dioxide,
| 117470-90-3 |
|
(s)-(+)-Phenylglycinol, 98%
| 20989-17-7 |
|
(1s,2s)-(+)-1,2-Diaminocyclohexane, 98%
| 21436-03-3 |
|
1- Phenylisatin
| 723-89-7 |
|
(+)-Menthoxyacetic Acid, 98%
| 94133-41-2 |
|
Trans-Chrysanthemyl Alcohol,98%, Mixture of ca. 10% Cis and ca.90%
| 5617-92-5 |
|
Neocyanine, 99% (UV-VIS)
| 4846-34-8 |
|
2-Isopropoxyphenol, 97%
| 4812-20-8 |
|
4,6-Dihydroxy-5-Nitropyrimidine, 95%
| 2164-83-2 |
|
Dehydrocholic acid, 98%
| 81-23-2 |
|
2-Thiophenecarboxamide, 99%
| 5813-89-8 |
|
Lactobionic acid, 97%
| 96-82-2 |
|
4,4'-Diacetylbiphenyl, 98%
| 787-69-9 |
|
4-Hexylaniline, Tech., 90%
| 33228-45-4 |
|
2-Bromo-4'-Nitroacetophenone, Tech., 83% (GC)
| 99-81-0 |
|
Vinblastine sulfate, 96.0-102.0% (hplc)
| 143-67-9 |
|
2,3-Dimethyl-6-Nitroaniline, 97%
| 59146-96-2 |
|
|