**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 75-99-0 |2,2-Dichloropropionic Acid | 90% | 200-923-0 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22 38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Risk of serious damage to
eyes.Moisture sensitive.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. May cause headache. May cause nausea and
vomiting.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. The toxicological properties of this substance have
not been fully investigated. Inhalation may be fatal as a result of
spasm, inflammation, edema of the larynx and bronchi, chemical
pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Do NOT get water inside
containers. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Do not allow contact with water. Keep from contact with
moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-99-0:
Belgium - TWA: 1 ppm VLE; 5.9 mg/m3 VLE
France - VME: 1 ppm VME; 6 mg/m3 VME
Germany: 1 ppm TWA; 5.9 mg/m3 TWA
Malaysia: 1 ppm TWA; 5.8 mg/m3 TWA
Netherlands: 1 ppm MAC; 6 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 1 ppm VLA-ED; 5.9 mg/m3 VLA-ED
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: faint yellow - colorless
Odor: acrid odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 190 deg C
Freezing/Melting Point: 20 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.3890g/cm3
Molecular Formula: C3H4Cl2O2
Molecular Weight: 142.97
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, exposure to moist air
or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-99-0: UF0690000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 75-99-0: Skin, rat: LD50 = >5 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
2,2-Dichloropropionic Acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
USA RQ: CAS# 75-99-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 75-99-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 75-99-0 is listed on Canada's NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 75-99-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-99-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 3/17/1999 Revision #3 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Penten-2-Ol, 96%, Predominatly Trans
| 1569-50-2 |
|
4-Fluoro-3-Nitrobenzoic Acid, 98%
| 453-71-4 |
|
Thymoquinone, 99%
| 490-79-9 |
|
1-Methallyl-3-Methyl-2-Thiourea, 98%
| 21018-38-2 |
|
3,4-Diethoxy-3-Cyclobutene-1,2-Dione, 98%
| 5231-87-8 |
|
4-Propoxybenzoic Acid, 98%
| 5438-19-7 |
|
N-METHYLPHTHALIMIDE, 98%
| 550-44-7 |
|
2,3-Dimethylhydroquinone, 99%
| 608-43-5 |
|
N-(2-Carboxyphenyl)glycine, 97%
| 612-42-0 |
|
3,3,5-Trimethylhexahydroazepine, 98%, mixture of isomers
| 35466-89-8 |
|
Triphosgene, 99% (Titr.)
| 32315-10-9 |
|
2,2-Dichloropropionic Acid, Tech., 90%
| 75-99-0 |
|
2-Phenylbenzoxazole, 99%
| 833-50-1 |
|
5-Chloro-1-Methylimidazole, 98%
| 872-49-1 |
|
2-Allylcyclohexanone, 97%
| 94-66-6 |
|
1,2-bis(dimethylphosphino)ethane, 97%
| 23936-60-9 |
|
Trans-1,2-Bis(Diphenylphosphino)Ethylene, 97%
| 983-81-3 |
|
1,3-Bis(Diphenylphosphino)Propane, 97%
| 6737-42-4 |
|
Bis(2-Oxo-3-Oxazolidinyl)phosphinic Chloride, 97%
| 68641-49-6 |
|
o-(tert-Butyldimethylsilyl)hydroxylamine, 95%
| 41879-39-4 |
|
Diethylphenylphosphine, 98%
| 1605-53-4 |
|
Diethylphosphoramidous Dichloride, 97%
| 1069-08-5 |
|
Dimethylphenylphosphine, 97%
| 672-66-2 |
|
Terbium(iii,iv)-oxide, 99.999%
| 12037-01-3 |
|
Dimethylphosphinic Acid, 97%
| 3283-12-3 |
|
Diphenylphosphine Oxide, 97%
| 4559-70-0 |
|
Diethyl (2-Chloroethyl)phosphonate, 95%
| 10419-79-1 |
|
Tributylgermane, 99%
| 998-39-0 |
|
Methylphosphonic dichloride, 98%
| 676-97-1 |
|
Propylphosphonic acid, 95%
| 4672-38-2 |
|
DIPHENYL(TRIMETHYLSILYL)PHOSPHINE, TECH.
| 17154-34-6 |
|
Sodium Sulfide
| 1313-82-2 |
|
Germanium(iv)ethoxide, 99.95+%
| 14165-55-0 |
|
Dimethyl(4r,5r)-1,3,2-dioxathiolane-4,5- dicarboxylate 2,2-dioxide,
| 117470-90-3 |
|
(s)-(+)-Phenylglycinol, 98%
| 20989-17-7 |
|
(1s,2s)-(+)-1,2-Diaminocyclohexane, 98%
| 21436-03-3 |
|
1- Phenylisatin
| 723-89-7 |
|
(+)-Menthoxyacetic Acid, 98%
| 94133-41-2 |
|
Trans-Chrysanthemyl Alcohol,98%, Mixture of ca. 10% Cis and ca.90%
| 5617-92-5 |
|
Neocyanine, 99% (UV-VIS)
| 4846-34-8 |
|
2-Isopropoxyphenol, 97%
| 4812-20-8 |
|
4,6-Dihydroxy-5-Nitropyrimidine, 95%
| 2164-83-2 |
|
Dehydrocholic acid, 98%
| 81-23-2 |
|
2-Thiophenecarboxamide, 99%
| 5813-89-8 |
|
Lactobionic acid, 97%
| 96-82-2 |
|
4,4'-Diacetylbiphenyl, 98%
| 787-69-9 |
|
4-Hexylaniline, Tech., 90%
| 33228-45-4 |
|
2-Bromo-4'-Nitroacetophenone, Tech., 83% (GC)
| 99-81-0 |
|
Vinblastine sulfate, 96.0-102.0% (hplc)
| 143-67-9 |
|
2,3-Dimethyl-6-Nitroaniline, 97%
| 59146-96-2 |
|
|