**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3320-87-4 |Benzene, 1-Isocyanato-3-Nitro- | ca 100 | 222-025-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully
investigated.Lachrymator (substance which increases the flow of
tears).Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Organic isocyanates can cause local
irritation and allergic reactions.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. At high
concentrations, isocyanates affect mucous membranes of the
respiratory tract and may lead to fatal pulmonary edema. Exposure to
low and often even unmeasurable isocyanate concentration results in
sensitization. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed. Chronic overexposure to isocyanates has been
reported to cause lung damage, including decreased lung fuction,
which may be permanent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Keep container tightly closed. Do not
allow contact with water. Wash clothing before reuse. Keep from
contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3320-87-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow crystalline powder
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 130-131C @ 11mmHg
Freezing/Melting Point: 51.00 - 53.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 109 deg C ( 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H4N2O3
Molecular Weight: 164.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3320-87-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzene, 1-Isocyanato-3-Nitro- -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3320-87-4: No information available.
Canada
CAS# 3320-87-4 is listed on Canada's NDSL List.
CAS# 3320-87-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3320-87-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/29/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl 2-aminocyclohepta[b]thiophene-3-carboxylate, 99+%
| 0-01-1 |
|
(1R,2S)-(-)-Ephedrine hydrochloride, 99.0-101.0% (dry subst.)
| 50-98-6 |
|
Ir-125, Laser Grade
| 3599-32-4 |
|
Trimethyl(phenylseleno)silane, tech., ca 90% (gc)
| 3386-17-5 |
|
Guanosine 2'(3')-monophosphate, disodium salt monohydrate, mixed
| 14200-70-5 |
|
Diisobutylamine, 99%
| 110-96-3 |
|
4-Phenolsulfonic acid, sodium salt dihydrate, 99%
| 825-90-1 |
|
(R)-(-)-2-Amino-3-hydroxy-3-methylbutanoic acid
| 2280-48-0 |
|
3,4-Diaminopyridine, 98%
| 54-96-6 |
|
Pentafluorophenol, 99+%
| 771-61-9 |
|
Methyl 2-butynoate, ca 97 %
| 23326-27-4 |
|
Sodium Carbonate Decahydrate, C.P.
| 6132-02-1 |
|
3-Pentanone, 98%
| 96-22-0 |
|
2-Amino-5-Nitrobenzophenone, 98%
| 1775-95-7 |
|
Ethyl Oleate
| 111-62-6 |
|
4-Nitrobenzotrifluoride, 96%
| 402-54-0 |
|
4-Vinyl-1-cyclohexene, 99%,stabilized with 50-200 ppm bht
| 100-40-3 |
|
3-Nitrophenyl Isocyanate (Pract)
| 3320-87-4 |
|
Hydrazine Acetate, 99% (titr.)
| 7335-65-1 |
|
3-Iodoanisole, 97%
| 766-85-8 |
|
Vinyltrimethoxysilane, 98%
| 2768-02-7 |
|
(1S)-Chrysanthemolactone, 99+%
| 14087-71-9 |
|
2,5-Dimethylbenzaldehyde, 96%
| 5779-94-2 |
|
N-Methyl-N-propargylbenzylamine, 97%
| 555-57-7 |
|
2,2-Dichloroacetophenone, 97%
| 2648-61-5 |
|
Tetrabutylammonium fluoride trihydrate, 99%
| 87749-50-6 |
|
Alpha-(4-Pyridyl 1-Oxide)-N-Tert-Butyl-Nitrone, 99%
| 66893-81-0 |
|
2-Mercapto-5-methyl-1,3,4-thiadiazole, 99%
| 29490-19-5 |
|
m-Phenoxytoluene, 98+%
| 3586-14-9 |
|
trans-2-Pentene, 95%
| 646-04-8 |
|
3-Phenylpropionaldehyde, 97% (GC)
| 104-53-0 |
|
4-Nitro-2,1,3-benzothiadiazole
| 6583-06-8 |
|
(2-Hydroxybenzyl)triphenylphosphonium bromide, 98%
| 70340-04-4 |
|
2-Amino-6-Fluorobenzothiazole, 99%
| 348-40-3 |
|
R(-)-1,3-Butanediol, 98%
| 6290-03-5 |
|
Dextrin (Techn)
| 9004-53-9 |
|
3-(4-Dimethylamino-1-Naphthylazo)-4-Methoxybenzenesulfonic Acid, 98%
| 62758-14-9 |
|
1-Propanesulfonic Acid, 95% (Titr.)
| 5284-66-2 |
|
1,10-Dichlorodecane, 98%
| 2162-98-3 |
|
Dibutyl sebacate, 93%
| 109-43-3 |
|
Boron trifluoride-propanol 14% bf3 w/v in propanol
| 71-23-8 |
|
Cesium Bicarbonate
| 15519-28-5 |
|
2,4-Dihydroxypyrimidine-5-Carboxylic Acid Hydrate, 98%
| 23945-44-0 |
|
cis-2-Methylcyclohexanol, 99+%
| 7443-70-1 |
|
2-Methyl-5-tert-butylthiophenol, 93% remainder isomer
| 7340-90-1 |
|
Erucylamide , tech., 90% (gc)
| 112-84-5 |
|
2-Bromo-4-fluoroanisole, 98%
| 452-08-4 |
|
Triphenylphosphine oxide, 99%
| 791-28-6 |
|
5,10,15,20-Tetrakis(Pentafluorophenyl)- 21h,23h-Porphine
| 25440-14-6 |
|
Trimethylacetic acid, 99%
| 75-98-9 |
|
|