**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 71-23-8 |Propanol | Balance | 200-746-9 |
|----------------|--------------------------------------|----------|-----------|
| 762-48-1 |Boron trifluoride-propanol, 14% BF3 w/| 14% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
May be fatal if absorbed through the skin. Causes skin burns.
Prolonged and/or repeated contact may cause irritation and/or
dermatitis.
Ingestion:
May be fatal if swallowed. May cause liver and kidney damage. May
cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and
possible death due to respiratory failure. Causes digestive tract
burns with immediate pain, swelling of the throat, convulsions, and
possible coma.
Inhalation:
May be fatal if inhaled. Causes severe irritation of upper
respiratory tract with coughing, burns, breathing difficulty, and
possible coma.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Store in a tightly closed container. Keep under an argon blanket.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 71-23-8:
United Kingdom, WEL - TWA: 200 ppm TWA; 500 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 625 mg/m3 STEL
United States OSHA: 200 ppm TWA; 500 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 499 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 623 mg/m3 VLE
France - VME: 200 ppm VME; 500 mg/m3 VME
Malaysia: 200 ppm TWA; 492 mg/m3 TWA
Russia: 10 mg/m3 TWA
Spain: 200 ppm VLA-ED; 500 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 625 mg/m3 VLA-EC
CAS# 762-48-1:
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: not available
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9050g/cm3
Molecular Formula: C3H8F3OB
Molecular Weight: 127.90
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agens, water, moist air, and amines.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, oxides of
boron.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71-23-8: UH8225000
CAS# 762-48-1 unlisted.
LD50/LC50:
CAS# 71-23-8: Draize test, rabbit, eye: 20 mg/24H Moderate;
Inhalation, mouse: LC50 = 48 gm/m3; Inhalation, mouse: LC50 = 48000
mg/m3; Oral, mouse: LD50 = 6800 mg/kg; Oral, rabbit: LD50 = 2825
mg/kg; Oral, rat: LD50 = 1870 mg/kg; Oral, rat: LD50 = 2200 mg/kg;
Skin, rabbit: LD50 = 5040 mg/kg.
CAS# 762-48-1.
Carcinogenicity:
Propanol -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Boron trifluoride-propanol, 14% BF3 w/v in propanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 71-23-8: 1
CAS# 762-48-1: No information available.
Canada
CAS# 71-23-8 is listed on Canada's DSL List.
CAS# 71-23-8 is listed on Canada's Ingredient Disclosure List.
CAS# 762-48-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71-23-8 is listed on the TSCA inventory.
CAS# 762-48-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 14 Reacts violently with water.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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