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MSDS 
:
 4-Methylumbelliferone phosphate, 99.5% (hplc)
CAS 
:
 3368-04-5
SYNONYMS 
:
 
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 3368-04-5 |2h-1-benzopyran-2-one,4-methyl-7-(phos| 99.5 | 222-137-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | <1.0 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.

Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.)

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3368-04-5:

CAS# 7732-18-5:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 210 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H9O6P
Molecular Weight: 256.14

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Not available.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 3368-04-5 unlisted.
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
2h-1-benzopyran-2-one,4-methyl-7-(phosphonooxy)- -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3368-04-5: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 3368-04-5 is listed on Canada's NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 3368-04-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3368-04-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

Text for R-phrases from Section 2
MSDS Creation Date: 1/16/1998 Revision #3 Date: 3/04/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
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4-Methylumbelliferone phosphate, 99.5% (hplc) 3368-04-5
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5-Indanol, 99% 1470-94-6
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cis-Pinonic acid, 98% 473-72-3
Camphene, 75%, Remainder Mainly Alpha-Fenchene 79-92-5
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O-(4-Nitrobenzyl)hydroxylamine hydrochloride, 98% 2086-26-2
alpha-Benzoin oxime, 98% 441-38-3
Oxalyl monoguanylhydrazide, 97% (titr.) 89797-67-1
3-Chlorobenzoic Acid, 98% (Titr.) 535-80-8
(R)-(+)-alpha-(1-Naphthyl)ethylamine 99+% 3886-70-2
Cyanocobalamin 68-19-9
Isopropan(ol-d), 98+ atom % d 3979-51-9
2-Bromostyrene, 98%, Stabilized With 0.005% 4-Tert.-Butylcatechol 2039-88-5
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3,5-Dimethylphenol, 99+% 108-68-9
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6-Bromoveratraldehyde, 97% 5392-10-9
3,5-Dichlorobenzonitrile, 97% 6575-00-4
Methyl (R)-(-)-3-Hydroxybutyrate, 99% 3976-69-0
4-CHLOROSTYRENE, 98% (GC) 1073-67-2
Ethyl 2-hydroxyethyl sulfide, 98% 110-77-0
2-Bromobutane, 99+% (GC) 78-76-2
4-Bromo-2,2-Diphenylbutyronitrile, 95+% 39186-58-8
Acridine-4, 9-Dicarboxylic Acid Monohydrate 27574-29-4
N-Aminomorpholine, 97%(GC) 4319-49-7
Cyclohexyl Diphenyl Phosphine 6372-42-5
2,4-Diamino-6-Mercaptopyrimidine Hemisulfate, Tech. 81012-96-6
Diethyl Succinate, 99% 123-25-1
1,3-Difluoro-4-iodobenzene, 99+% 2265-93-2
Mono-methyl 5-nitroisophthalate, 98% 1955-46-0
Citric acid monohydrate 77-92-9
3-Pyrrolidino-1,2-Propanediol, 96% 85391-19-1
Delta-Valerolactam, 99% 675-20-7
Cycloheptyl Bromide, 97% 2404-35-5
Penicillin G Potassium Salt 113-98-4
Nicotinic acid hydrazide, 97% 553-53-7
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Streptomycin sulfate 3810-74-0
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