**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 14779-55-6 |Methylamine-d5 deuteriochloride | 98+ | 238-848-0 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Use with adequate ventilation. Avoid breathing dust.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 593-51-1:
CAS# 14779-55-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 233-235 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 235 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CD5N.DCl
Molecular Weight: 73.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 593-51-1: PA0603000
CAS# 14779-55-6 unlisted.
LD50/LC50:
CAS# 593-51-1: Dermal, guinea pig: LD50 = >2 gm/kg; Oral, rat: LD50
= 1600 mg/kg.
CAS# 14779-55-6.
Carcinogenicity:
Methanamine, hydrochloride -
Not listed by ACGIH, IARC, or NTP.
Methylamine-d5 deuteriochloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 593-51-1: 1
CAS# 14779-55-6: No information available.
Canada
CAS# 593-51-1 is listed on Canada's DSL List.
CAS# 593-51-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 14779-55-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 593-51-1 is listed on the TSCA inventory.
CAS# 14779-55-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 2/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-1-4'-Tosylamino-2-Phenylethyl Chloromethyl Ketone, 99+%
| 402-71-1 |
|
4-Methylumbelliferone phosphate, 99.5% (hplc)
| 3368-04-5 |
|
6-Chloro-meta-anisidine hydrochloride, 98%
| 2401-24-3 |
|
5-Indanol, 99%
| 1470-94-6 |
|
1,1-Dichloroethane,99+%, Stabilized with Nitromethane
| 75-34-3 |
|
2,3-Dihydro-2-Oxo-1H-Imidazol-4-Carbox-Aldehyde, 99%
| 0-00-1 |
|
2,5-Dihydroxy-1,4-Benzenedisulfonic Acid, Dipotassium Salt, 98%
| 15763-57-2 |
|
Phenacyltriphenylphosphonium bromide 96%
| 6048-29-9 |
|
cis-Pinonic acid, 98%
| 473-72-3 |
|
Camphene, 75%, Remainder Mainly Alpha-Fenchene
| 79-92-5 |
|
Scopolamine Hydrobromide Trihydrate, 99.0-101.0% (On The Anhydrous
| 6533-68-2 |
|
n-Methoxymethylaza-18-crown-6, 96%
| |
|
Benzyl Propionate, 98+%
| 122-63-4 |
|
1-Methyl-1-Phenylhydrazine, 98% (titr.)
| 618-40-6 |
|
O-(4-Nitrobenzyl)hydroxylamine hydrochloride, 98%
| 2086-26-2 |
|
alpha-Benzoin oxime, 98%
| 441-38-3 |
|
Oxalyl monoguanylhydrazide, 97% (titr.)
| 89797-67-1 |
|
3-Chlorobenzoic Acid, 98% (Titr.)
| 535-80-8 |
|
(R)-(+)-alpha-(1-Naphthyl)ethylamine 99+%
| 3886-70-2 |
|
Cyanocobalamin
| 68-19-9 |
|
Isopropan(ol-d), 98+ atom % d
| 3979-51-9 |
|
2-Bromostyrene, 98%, Stabilized With 0.005% 4-Tert.-Butylcatechol
| 2039-88-5 |
|
Methylamine-d5 deuteriochloride, 98+ atom % D
| 593-51-1 |
|
3,5-Dimethylphenol, 99+%
| 108-68-9 |
|
2-Chloro-5-nitrobenzonitrile, 99%
| 16588-02-6 |
|
6-Bromoveratraldehyde, 97%
| 5392-10-9 |
|
3,5-Dichlorobenzonitrile, 97%
| 6575-00-4 |
|
Methyl (R)-(-)-3-Hydroxybutyrate, 99%
| 3976-69-0 |
|
4-CHLOROSTYRENE, 98% (GC)
| 1073-67-2 |
|
Ethyl 2-hydroxyethyl sulfide, 98%
| 110-77-0 |
|
2-Bromobutane, 99+% (GC)
| 78-76-2 |
|
4-Bromo-2,2-Diphenylbutyronitrile, 95+%
| 39186-58-8 |
|
Acridine-4, 9-Dicarboxylic Acid Monohydrate
| 27574-29-4 |
|
N-Aminomorpholine, 97%(GC)
| 4319-49-7 |
|
Cyclohexyl Diphenyl Phosphine
| 6372-42-5 |
|
2,4-Diamino-6-Mercaptopyrimidine Hemisulfate, Tech.
| 81012-96-6 |
|
Diethyl Succinate, 99%
| 123-25-1 |
|
1,3-Difluoro-4-iodobenzene, 99+%
| 2265-93-2 |
|
Mono-methyl 5-nitroisophthalate, 98%
| 1955-46-0 |
|
Citric acid monohydrate
| 77-92-9 |
|
3-Pyrrolidino-1,2-Propanediol, 96%
| 85391-19-1 |
|
Delta-Valerolactam, 99%
| 675-20-7 |
|
Cycloheptyl Bromide, 97%
| 2404-35-5 |
|
Penicillin G Potassium Salt
| 113-98-4 |
|
Nicotinic acid hydrazide, 97%
| 553-53-7 |
|
Ethyl (2r,3r)-2,3-epoxy-3-methylpropanoate 96%
| 19780-35-9 |
|
Beta-Sitosterol, ca 75% Beta-Sitosterol, With ca 10% Campesterol
| |
|
3-Hydroxy-4(2-Hydroxy-4-Sulfo-1-Naphtyl Azo)naphthalene-2-Carboxylic
| 3737-95-9 |
|
Streptomycin sulfate
| 3810-74-0 |
|
Cyanogen Bromide
| 506-68-3 |
|
|