**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 367-24-8 |4-Bromo-2-fluoroaniline | 99 | 206-685-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death. May cause central nervous system depression.
May cause cardiac abnormalities.
Inhalation:
Causes respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored
breathing), and death. May cause cardiac abnormalities. Can produce
delayed pulmonary edema.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 367-24-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: gray brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 39-42 deg C
Autoignition Temperature: Not available.
Flash Point: 104 deg C ( 219.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H5BrFN
Molecular Weight: 190.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 367-24-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromo-2-fluoroaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 367-24-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 367-24-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 367-24-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 7/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Formic acid-d2, 99+ atom % D (95% in D2O)
| 64-18-6 |
|
Barium fluoride
| 7787-32-8 |
|
m-Tolyl isothiocyanate, 98%
| 621-30-7 |
|
2,5-Dimethyl-2,5-hexanediol, 99%
| 110-03-2 |
|
Dibenz[a,h]anthracene, 99% (UV-Vis)
| 53-70-3 |
|
Basic Fuchsin, high purity biological stain, special for flagella
| 58969-01-0 |
|
1-Chloro-3,5-Difluorobenzene
| 1435-43-4 |
|
Decanoic Acid, 99+%
| 334-48-5 |
|
Cholesteryl N-Heptylate, 97%
| 1182-07-6 |
|
N-(1-Adamantyl)-Urea
| 13072-69-0 |
|
2-Thiopheneacetic acid, 98%
| 1918-77-0 |
|
N-Formylmorpholine, 99+%
| 4394-85-8 |
|
2-Thiophenecarboxaldehyde, 98%
| 98-03-3 |
|
Poly(tetrafluoroethylene)
| 9002-84-0 |
|
1,1-Dimethyl-2-Selenourea, 97%
| 5117-16-8 |
|
2-Bromopropionyl chloride, tech.
| 7148-74-5 |
|
Cyclopropanecarboxylic Acid Chloride, 98% (GC)
| 4023-34-1 |
|
Diethyl 3-oxopimelate, 97%
| 40420-22-2 |
|
2,4-Dichlorophenylhydrazine Hydrochloride 99%
| 5446-18-4 |
|
4-Aminobenzonitrile,98%
| 873-74-5 |
|
1-Adamantanecarboxylic Acid Chloride, 97+%
| 2094-72-6 |
|
4-Methoxycinnamonitrile 98% Mixture of Cis/Trans
| 28446-68-6 |
|
1,4-Epoxy-1,4-dihydronaphthalene, 99%
| 573-57-9 |
|
3-Cyclohexylpropionic Acid, 99+%
| 701-97-3 |
|
Thymidine, 99+%
| 50-89-5 |
|
1-Chloro-3-fluorobenzene, 99%
| 625-98-9 |
|
4-Bromo-2-fluoroaniline, 99%
| 367-24-8 |
|
4-(4-Nitrophenylazo)-resorcinol dye content ~90%
| 74-39-5 |
|
Vinylcyclohexane, 98%
| 695-12-5 |
|
Diethyl propylmalonate, 99%
| 2163-48-6 |
|
N,N-Bis-(2-Chloroethyl)-P-Toluenesulfonamide, Tech.
| 42137-88-2 |
|
Pyrazole, 98%
| 288-13-1 |
|
Carbon Tetrachloride, 99+%, Spectrophotometric Grade
| 56-23-5 |
|
1,1-Dimethylcyclohexane, 97%
| 590-66-9 |
|
Dimethyl 4,5-imidazoledicarboxylate, 93% (uv-vis)
| 3304-70-9 |
|
Cyclooctylamine, 97%
| 5452-37-9 |
|
Tolylene-2,6-Diisocyanate, 97%
| 91-08-7 |
|
3-Fluorophenylhydrazine Hydrochloride 97%
| 2924-16-5 |
|
1-Iodonaphthalene, 97.5% (GC)
| 90-14-2 |
|
L-(+)-Amethopterin hydrate, 99%
| 133073-73-1 |
|
Cyclopentanone
| 120-92-3 |
|
n-Phenylbenzohydroxamic acid, 98% (titr.)
| 304-88-1 |
|
3-Benzoylacrylic acid
| 583-06-2 |
|
Phenylhydroquinone, 96%
| 1079-21-6 |
|
BOC-L-Histidine, 99+%
| 17791-52-5 |
|
3-Methyl-2-Nitroanisole, 99%
| 5345-42-6 |
|
Cytidine, 99.5%
| 65-46-3 |
|
Ethyl (2s)-2,3-epoxypropanoate, 97%
| 111058-34-5 |
|
Vinylbenzyl Chloride (Mixt. of m-and p-Isomers), 96% (GC), Stabilized
| 57458-41-0 |
|
3-Ethyl-2,5-dihydrothiophene-1,1-dioxide, 98%
| 62157-91-9 |
|
|