**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7148-74-5 |2-BROMOPROPIONYL CHLORIDE | | 230-466-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. The toxicological properties of
this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7148-74-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 131 - 133 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 51 deg C ( 123.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.7000g/cm3
Molecular Formula: C3H4BrClO
Molecular Weight: 171.42
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Alcohols, oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide,
hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7148-74-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-BROMOPROPIONYL CHLORIDE -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7148-74-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7148-74-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7148-74-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Formic acid-d2, 99+ atom % D (95% in D2O)
| 64-18-6 |
|
Barium fluoride
| 7787-32-8 |
|
m-Tolyl isothiocyanate, 98%
| 621-30-7 |
|
2,5-Dimethyl-2,5-hexanediol, 99%
| 110-03-2 |
|
Dibenz[a,h]anthracene, 99% (UV-Vis)
| 53-70-3 |
|
Basic Fuchsin, high purity biological stain, special for flagella
| 58969-01-0 |
|
1-Chloro-3,5-Difluorobenzene
| 1435-43-4 |
|
Decanoic Acid, 99+%
| 334-48-5 |
|
Cholesteryl N-Heptylate, 97%
| 1182-07-6 |
|
N-(1-Adamantyl)-Urea
| 13072-69-0 |
|
2-Thiopheneacetic acid, 98%
| 1918-77-0 |
|
N-Formylmorpholine, 99+%
| 4394-85-8 |
|
2-Thiophenecarboxaldehyde, 98%
| 98-03-3 |
|
Poly(tetrafluoroethylene)
| 9002-84-0 |
|
1,1-Dimethyl-2-Selenourea, 97%
| 5117-16-8 |
|
2-Bromopropionyl chloride, tech.
| 7148-74-5 |
|
Cyclopropanecarboxylic Acid Chloride, 98% (GC)
| 4023-34-1 |
|
Diethyl 3-oxopimelate, 97%
| 40420-22-2 |
|
2,4-Dichlorophenylhydrazine Hydrochloride 99%
| 5446-18-4 |
|
4-Aminobenzonitrile,98%
| 873-74-5 |
|
1-Adamantanecarboxylic Acid Chloride, 97+%
| 2094-72-6 |
|
4-Methoxycinnamonitrile 98% Mixture of Cis/Trans
| 28446-68-6 |
|
1,4-Epoxy-1,4-dihydronaphthalene, 99%
| 573-57-9 |
|
3-Cyclohexylpropionic Acid, 99+%
| 701-97-3 |
|
Thymidine, 99+%
| 50-89-5 |
|
1-Chloro-3-fluorobenzene, 99%
| 625-98-9 |
|
4-Bromo-2-fluoroaniline, 99%
| 367-24-8 |
|
4-(4-Nitrophenylazo)-resorcinol dye content ~90%
| 74-39-5 |
|
Vinylcyclohexane, 98%
| 695-12-5 |
|
Diethyl propylmalonate, 99%
| 2163-48-6 |
|
N,N-Bis-(2-Chloroethyl)-P-Toluenesulfonamide, Tech.
| 42137-88-2 |
|
Pyrazole, 98%
| 288-13-1 |
|
Carbon Tetrachloride, 99+%, Spectrophotometric Grade
| 56-23-5 |
|
1,1-Dimethylcyclohexane, 97%
| 590-66-9 |
|
Dimethyl 4,5-imidazoledicarboxylate, 93% (uv-vis)
| 3304-70-9 |
|
Cyclooctylamine, 97%
| 5452-37-9 |
|
Tolylene-2,6-Diisocyanate, 97%
| 91-08-7 |
|
3-Fluorophenylhydrazine Hydrochloride 97%
| 2924-16-5 |
|
1-Iodonaphthalene, 97.5% (GC)
| 90-14-2 |
|
L-(+)-Amethopterin hydrate, 99%
| 133073-73-1 |
|
Cyclopentanone
| 120-92-3 |
|
n-Phenylbenzohydroxamic acid, 98% (titr.)
| 304-88-1 |
|
3-Benzoylacrylic acid
| 583-06-2 |
|
Phenylhydroquinone, 96%
| 1079-21-6 |
|
BOC-L-Histidine, 99+%
| 17791-52-5 |
|
3-Methyl-2-Nitroanisole, 99%
| 5345-42-6 |
|
Cytidine, 99.5%
| 65-46-3 |
|
Ethyl (2s)-2,3-epoxypropanoate, 97%
| 111058-34-5 |
|
Vinylbenzyl Chloride (Mixt. of m-and p-Isomers), 96% (GC), Stabilized
| 57458-41-0 |
|
3-Ethyl-2,5-dihydrothiophene-1,1-dioxide, 98%
| 62157-91-9 |
|
|