**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 57458-41-0 |Vinylbenzyl Chloride | 96 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Air sensitive.Light sensitive.Corrosive.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Produces irritation, characterized by a burning
sensation, redness, tearing, inflammation, and possible corneal
injury. Lachrymator (substance which increases the flow of tears).
May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause central nervous system effects. May cause cardiac
abnormalities. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects. May cause Central Nervous System Effects
characterized by apathy, mental confusion, blurred vision, and
tremors.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode if exposed to fire. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not breathe dust, vapor, mist, or gas. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Store protected from light. Handle under an
inert atmosphere. Store protected from air. Use only in a chemical
fume hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Corrosives area. Keep
refrigerated. (Store below 4C/39F.) Do not expose to air. Store
protected from light. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 57458-41-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 229 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: 614 deg C ( 1,137.20 deg F)
Flash Point: 104 deg C ( 219.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0740g/cm3
Molecular Formula: C9H9Cl
Molecular Weight: 152.62
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Air sensitive. Light
sensitive.
Conditions to Avoid:
Incompatible materials, light, exposure to air, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Air, direct light, acids, bases, activated carbon, metals.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 57458-41-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vinylbenzyl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 57458-41-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 57458-41-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 57458-41-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Formic acid-d2, 99+ atom % D (95% in D2O)
| 64-18-6 |
|
Barium fluoride
| 7787-32-8 |
|
m-Tolyl isothiocyanate, 98%
| 621-30-7 |
|
2,5-Dimethyl-2,5-hexanediol, 99%
| 110-03-2 |
|
Dibenz[a,h]anthracene, 99% (UV-Vis)
| 53-70-3 |
|
Basic Fuchsin, high purity biological stain, special for flagella
| 58969-01-0 |
|
1-Chloro-3,5-Difluorobenzene
| 1435-43-4 |
|
Decanoic Acid, 99+%
| 334-48-5 |
|
Cholesteryl N-Heptylate, 97%
| 1182-07-6 |
|
N-(1-Adamantyl)-Urea
| 13072-69-0 |
|
2-Thiopheneacetic acid, 98%
| 1918-77-0 |
|
N-Formylmorpholine, 99+%
| 4394-85-8 |
|
2-Thiophenecarboxaldehyde, 98%
| 98-03-3 |
|
Poly(tetrafluoroethylene)
| 9002-84-0 |
|
1,1-Dimethyl-2-Selenourea, 97%
| 5117-16-8 |
|
2-Bromopropionyl chloride, tech.
| 7148-74-5 |
|
Cyclopropanecarboxylic Acid Chloride, 98% (GC)
| 4023-34-1 |
|
Diethyl 3-oxopimelate, 97%
| 40420-22-2 |
|
2,4-Dichlorophenylhydrazine Hydrochloride 99%
| 5446-18-4 |
|
4-Aminobenzonitrile,98%
| 873-74-5 |
|
1-Adamantanecarboxylic Acid Chloride, 97+%
| 2094-72-6 |
|
4-Methoxycinnamonitrile 98% Mixture of Cis/Trans
| 28446-68-6 |
|
1,4-Epoxy-1,4-dihydronaphthalene, 99%
| 573-57-9 |
|
3-Cyclohexylpropionic Acid, 99+%
| 701-97-3 |
|
Thymidine, 99+%
| 50-89-5 |
|
1-Chloro-3-fluorobenzene, 99%
| 625-98-9 |
|
4-Bromo-2-fluoroaniline, 99%
| 367-24-8 |
|
4-(4-Nitrophenylazo)-resorcinol dye content ~90%
| 74-39-5 |
|
Vinylcyclohexane, 98%
| 695-12-5 |
|
Diethyl propylmalonate, 99%
| 2163-48-6 |
|
N,N-Bis-(2-Chloroethyl)-P-Toluenesulfonamide, Tech.
| 42137-88-2 |
|
Pyrazole, 98%
| 288-13-1 |
|
Carbon Tetrachloride, 99+%, Spectrophotometric Grade
| 56-23-5 |
|
1,1-Dimethylcyclohexane, 97%
| 590-66-9 |
|
Dimethyl 4,5-imidazoledicarboxylate, 93% (uv-vis)
| 3304-70-9 |
|
Cyclooctylamine, 97%
| 5452-37-9 |
|
Tolylene-2,6-Diisocyanate, 97%
| 91-08-7 |
|
3-Fluorophenylhydrazine Hydrochloride 97%
| 2924-16-5 |
|
1-Iodonaphthalene, 97.5% (GC)
| 90-14-2 |
|
L-(+)-Amethopterin hydrate, 99%
| 133073-73-1 |
|
Cyclopentanone
| 120-92-3 |
|
n-Phenylbenzohydroxamic acid, 98% (titr.)
| 304-88-1 |
|
3-Benzoylacrylic acid
| 583-06-2 |
|
Phenylhydroquinone, 96%
| 1079-21-6 |
|
BOC-L-Histidine, 99+%
| 17791-52-5 |
|
3-Methyl-2-Nitroanisole, 99%
| 5345-42-6 |
|
Cytidine, 99.5%
| 65-46-3 |
|
Ethyl (2s)-2,3-epoxypropanoate, 97%
| 111058-34-5 |
|
Vinylbenzyl Chloride (Mixt. of m-and p-Isomers), 96% (GC), Stabilized
| 57458-41-0 |
|
3-Ethyl-2,5-dihydrothiophene-1,1-dioxide, 98%
| 62157-91-9 |
|
|