**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6213-94-1 |Vinyloxytrimethylsilane | 97% | 228-281-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.Moisture sensitive.Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
May cause contact dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed. Ingestion of large amounts
may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration. May be harmful if inhaled. May cause nausea,
dizziness, and headache. Can produce delayed pulmonary edema. May
cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Will be easily ignited by heat, sparks or flame.
Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
Do NOT get water inside containers. For large fires, use water
spray, fog or alcohol-resistant foam. Do NOT use straight streams of
water. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation.
Use with adequate ventilation. Do not allow contact with water. Wash
clothing before reuse. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Refrigerator/flammables. Store under
nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 6213-94-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear straw colored
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 74 - 75 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -10 deg C ( 14.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.77
Molecular Formula: C5H12OSi
Molecular Weight: 116.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at normal temperatures in tightly closed containers under an
inert atmosphere.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6213-94-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vinyloxytrimethylsilane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 6213-94-1: No information available.
Canada
CAS# 6213-94-1 is listed on Canada's NDSL List.
CAS# 6213-94-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6213-94-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/28/2001 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Formaldehyde, reagent ACS, 37 wt% solution, stabilized with 10-15%
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Tin (IV) Oxide, 99.9%
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4-Dimethylaminobenzaldehyde
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4-Cymene (pract), 96% (gc)
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Triphenylcarbenium Pentachlorostannate
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Boc-L-Leucine Hydrate, 99+%
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FMOC-L-Glutamine, 98%
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Bismuth, shot, 99.999%
| 7440-69-9 |
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1,1,2-Trichlorotrifluoroethane, 99+% spectrophotometric grade
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Hydrogen Hexachloroplatinate(IV) Hydrate Reagents ACS (Crystals)
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5-Sulfosalicylic acid dihydrate, reagent ACS
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Thymol blue, reagent acs
| 76-61-9 |
|
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| 7732-18-5 |
|
Potassium fluoride hydrate, 99%
| 13455-21-5 |
|
Silicon Atomic Absorption Standard Solution, 1 mg/ml Si in 2 wt.%
| 1310-73-2 |
|
Starch (Soluble), Reagent ACS
| 9005-84-9 |
|
Titanium(III) chloride, H2 reduced
| 7705-07-9 |
|
(S)-1,2,4-Butanetriol Trimethanesulfonate, 97-99%
| 99520-81-7 |
|
Tween 80
| 9005-65-6 |
|
2,3,5-Triphenyl-2H-tetrazolium chloride, 98%
| 298-96-4 |
|
Titanium (IV) Oxide, 99% Anatase Powder
| 13463-67-7 |
|
DL-Malic acid
| 617-48-1 |
|
Boc-L-Glutamic Acid 5-Benzylester, 99%
| 13574-13-5 |
|
FMOC-L-Phenylalanine, 98%
| 35661-40-6 |
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N-Alfa-Fmoc-N-Epsilon-Boc-L-Lysine, 99%
| 71989-26-9 |
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D-(+)-Glyceraldehyde, 80-90 Wt % Aqueous Solution
| 453-17-8 |
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Mordant Orange 1
| 2243-76-7 |
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| 64-17-5 |
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9,10-Anthracenedicarboxaldehyde, 80%
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|
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Boc-L-Valine, 99+%
| 13734-41-3 |
|
Titanium(IV) Chloride, 99.9%
| 7550-45-0 |
|
Uridine, 99%
| 58-96-8 |
|
Potassium Bisulfate C.P.
| 7646-93-7 |
|
all-trans-Retinyl acetate, 1.5 million IU/g, in sunflower oil,
| 127-47-9 |
|
Cadmium Sulfate, P.A.
| 10124-36-4 |
|
n-Dodecyl-beta-D-maltoside (high purity), 99%
| 69227-93-6 |
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| 521-31-3 |
|
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| 583-57-3 |
|
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| 637-01-4 |
|
FMOC-L-Isoleucine, 99%
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|
Silica gel, 75-300 mesh
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