**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7550-45-0 |Titanium(IV) chloride | 99.9% | 231-441-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Causes skin burns. Causes redness and pain.
Ingestion:
Causes gastrointestinal tract burns. May cause severe digestive
tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Inhalation:
Effects may be delayed. May cause irritation of the respiratory
tract with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema. Causes chemical burns to
the respiratory tract. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood. Keep from
contact with moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7550-45-0:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: light yellow
Odor: penetrating odor
pH: Not available.
Vapor Pressure: 12 hPa @ 20 deg C
Viscosity: 0.08 mPas 20 deg C
Boiling Point: 136.5 deg C @ 760.00mm Hg
Freezing/Melting Point: -24 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.7260g/cm3
Molecular Formula: TiCl4
Molecular Weight: 189.71
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, moist air.
Incompatibilities with Other Materials:
Water, strong oxidizing agents, alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, titanium/titanium oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7550-45-0: XR1925000
LD50/LC50:
CAS# 7550-45-0: Inhalation, mouse: LC50 = 100 mg/m3/2H; Inhalation,
rat: LC50 = 400 mg/m3.
Carcinogenicity:
Titanium(IV) chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TITANIUM TETRACHLORIDE
(forbidden to ship via passenger or cargo air)
Hazard Class: 8
UN Number: 1838
Packing Group: II
IMO
Shipping Name: TITANIUM TETRACHLORIDE
Hazard Class: 8
UN Number: 1838
Packing Group: II
RID/ADR
Shipping Name: TITANIUM TETRACHLORIDE
Hazard Class: 8
UN Number: 1838
Packing group: II
USA RQ: CAS# 7550-45-0: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7550-45-0: 1
Canada
CAS# 7550-45-0 is listed on Canada's DSL List.
CAS# 7550-45-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7550-45-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/29/1998 Revision #2 Date: 6/24/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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2-Chloro-3-methylthiophene
| 14345-97-2 |
|
Formaldehyde, reagent ACS, 37 wt% solution, stabilized with 10-15%
| 50-00-0 |
|
Tin (IV) Oxide, 99.9%
| 18282-10-5 |
|
4-Dimethylaminobenzaldehyde
| 100-10-7 |
|
4-Cymene (pract), 96% (gc)
| 99-87-6 |
|
Triphenylcarbenium Pentachlorostannate
| 15414-98-9 |
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1,1,1-Trichloroethane, 93% (GC)
| 71-55-6 |
|
N,N,N',N'-Tetramethyl-1,4-butanediamine, 97%
| 111-51-3 |
|
Boc-L-Leucine Hydrate, 99+%
| 13139-15-6 |
|
FMOC-L-Glutamine, 98%
| 71989-20-3 |
|
Bismuth, shot, 99.999%
| 7440-69-9 |
|
1,1,2-Trichlorotrifluoroethane, 99+% spectrophotometric grade
| 76-13-1 |
|
Hydrogen Hexachloroplatinate(IV) Hydrate Reagents ACS (Crystals)
| 16941-12-1 |
|
5-Sulfosalicylic acid dihydrate, reagent ACS
| 97-05-2 |
|
Thymol blue, reagent acs
| 76-61-9 |
|
Tris(1,10-phenanthroline)iron(II) sulfate solution
| 7732-18-5 |
|
Potassium fluoride hydrate, 99%
| 13455-21-5 |
|
Silicon Atomic Absorption Standard Solution, 1 mg/ml Si in 2 wt.%
| 1310-73-2 |
|
Starch (Soluble), Reagent ACS
| 9005-84-9 |
|
Titanium(III) chloride, H2 reduced
| 7705-07-9 |
|
(S)-1,2,4-Butanetriol Trimethanesulfonate, 97-99%
| 99520-81-7 |
|
Tween 80
| 9005-65-6 |
|
2,3,5-Triphenyl-2H-tetrazolium chloride, 98%
| 298-96-4 |
|
Titanium (IV) Oxide, 99% Anatase Powder
| 13463-67-7 |
|
DL-Malic acid
| 617-48-1 |
|
Boc-L-Glutamic Acid 5-Benzylester, 99%
| 13574-13-5 |
|
FMOC-L-Phenylalanine, 98%
| 35661-40-6 |
|
N-Alfa-Fmoc-N-Epsilon-Boc-L-Lysine, 99%
| 71989-26-9 |
|
D-(+)-Glyceraldehyde, 80-90 Wt % Aqueous Solution
| 453-17-8 |
|
Mordant Orange 1
| 2243-76-7 |
|
Etoh, anhydrous, denat. with up to 5% mek and meoh/etoac
| 64-17-5 |
|
9,10-Anthracenedicarboxaldehyde, 80%
| 7044-91-9 |
|
Sulfuric acid, 0.1N standard solution
| 7664-93-9 |
|
Boc-L-Valine, 99+%
| 13734-41-3 |
|
Titanium(IV) Chloride, 99.9%
| 7550-45-0 |
|
Uridine, 99%
| 58-96-8 |
|
Potassium Bisulfate C.P.
| 7646-93-7 |
|
all-trans-Retinyl acetate, 1.5 million IU/g, in sunflower oil,
| 127-47-9 |
|
Cadmium Sulfate, P.A.
| 10124-36-4 |
|
n-Dodecyl-beta-D-maltoside (high purity), 99%
| 69227-93-6 |
|
3-Aminophthalhydrazide, also known as Luminol
| 521-31-3 |
|
1,2-Dimethylcyclohexane, 98%, Mixture of Cis and Trans
| 583-57-3 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride, 99% (titr.)
| 637-01-4 |
|
FMOC-L-Isoleucine, 99%
| 71989-23-6 |
|
Silica gel, 75-300 mesh
| 7631-86-9 |
|
3-Endo-Aminobicyclo(2,2,1,)Heptane-2-Endo-Carboxylic Acid, 98%
| 0-01-1 |
|
6-Chloro-1,3-Dimethyluracil
| 6972-27-6 |
|
Vinyloxytrimethylsilane
| 6213-94-1 |
|
3-Chloro-L-alanine
| 2731-73-9 |
|
Zinc, Dust
| 7440-66-6 |
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|