**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7646-93-7 |Potassium Bisulfate, C.P. | 100 | 231-594-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Irritating to respiratory system.Corrosive.Hygroscopic
(absorbs moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
Causes digestive tract burns with immediate pain, swelling of the
throat, convulsions, and possible coma.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Contact with metals may evolve flammable hydrogen
gas.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish
surrounding fire. Do NOT get water inside containers. For small
fires, use dry chemical, carbon dioxide, or water spray. For large
fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or
water spray. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Remove all sources of ignition. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get on skin
or in eyes. Do not ingest or inhale. Discard contaminated shoes. Do
not breathe dust or fumes.
Storage:
Store in a cool, dry place. Keep away from water. Corrosives area.
Do not store in metal containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 7646-93-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 214 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >210 deg C
Solubility in water: 490 g/l water (20 c)
Specific Gravity/Density: 2.3220g/cm3
Molecular Formula: HKO4S
Molecular Weight: 136.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, metals, excess heat.
Incompatibilities with Other Materials:
Strong bases; strong oxidizing agents; moist air or water
Hazardous Decomposition Products:
Oxides of sulfur, oxides of potassium, sulfur oxides (SOx), including
sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7646-93-7: TS7200000
LD50/LC50:
CAS# 7646-93-7: Oral, rat: LD50 = 2340 mg/kg.
Carcinogenicity:
Potassium Bisulfate, C.P. -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POTASSIUM HYDROGEN SULPHATE
Hazard Class: 8
UN Number: 2509
Packing Group: II
IMO
Shipping Name: POTASSIUM HYDROGEN SULPHATE
Hazard Class: 8
UN Number: 2509
Packing Group: II
RID/ADR
Shipping Name: POTASSIUM HYDROGEN SULPHATE
Hazard Class: 8
UN Number: 2509
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 37 Irritating to respiratory system.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7646-93-7: 1
Canada
CAS# 7646-93-7 is listed on Canada's DSL List.
CAS# 7646-93-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7646-93-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/27/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chloro-3-methylthiophene
| 14345-97-2 |
|
Formaldehyde, reagent ACS, 37 wt% solution, stabilized with 10-15%
| 50-00-0 |
|
Tin (IV) Oxide, 99.9%
| 18282-10-5 |
|
4-Dimethylaminobenzaldehyde
| 100-10-7 |
|
4-Cymene (pract), 96% (gc)
| 99-87-6 |
|
Triphenylcarbenium Pentachlorostannate
| 15414-98-9 |
|
1,1,1-Trichloroethane, 93% (GC)
| 71-55-6 |
|
N,N,N',N'-Tetramethyl-1,4-butanediamine, 97%
| 111-51-3 |
|
Boc-L-Leucine Hydrate, 99+%
| 13139-15-6 |
|
FMOC-L-Glutamine, 98%
| 71989-20-3 |
|
Bismuth, shot, 99.999%
| 7440-69-9 |
|
1,1,2-Trichlorotrifluoroethane, 99+% spectrophotometric grade
| 76-13-1 |
|
Hydrogen Hexachloroplatinate(IV) Hydrate Reagents ACS (Crystals)
| 16941-12-1 |
|
5-Sulfosalicylic acid dihydrate, reagent ACS
| 97-05-2 |
|
Thymol blue, reagent acs
| 76-61-9 |
|
Tris(1,10-phenanthroline)iron(II) sulfate solution
| 7732-18-5 |
|
Potassium fluoride hydrate, 99%
| 13455-21-5 |
|
Silicon Atomic Absorption Standard Solution, 1 mg/ml Si in 2 wt.%
| 1310-73-2 |
|
Starch (Soluble), Reagent ACS
| 9005-84-9 |
|
Titanium(III) chloride, H2 reduced
| 7705-07-9 |
|
(S)-1,2,4-Butanetriol Trimethanesulfonate, 97-99%
| 99520-81-7 |
|
Tween 80
| 9005-65-6 |
|
2,3,5-Triphenyl-2H-tetrazolium chloride, 98%
| 298-96-4 |
|
Titanium (IV) Oxide, 99% Anatase Powder
| 13463-67-7 |
|
DL-Malic acid
| 617-48-1 |
|
Boc-L-Glutamic Acid 5-Benzylester, 99%
| 13574-13-5 |
|
FMOC-L-Phenylalanine, 98%
| 35661-40-6 |
|
N-Alfa-Fmoc-N-Epsilon-Boc-L-Lysine, 99%
| 71989-26-9 |
|
D-(+)-Glyceraldehyde, 80-90 Wt % Aqueous Solution
| 453-17-8 |
|
Mordant Orange 1
| 2243-76-7 |
|
Etoh, anhydrous, denat. with up to 5% mek and meoh/etoac
| 64-17-5 |
|
9,10-Anthracenedicarboxaldehyde, 80%
| 7044-91-9 |
|
Sulfuric acid, 0.1N standard solution
| 7664-93-9 |
|
Boc-L-Valine, 99+%
| 13734-41-3 |
|
Titanium(IV) Chloride, 99.9%
| 7550-45-0 |
|
Uridine, 99%
| 58-96-8 |
|
Potassium Bisulfate C.P.
| 7646-93-7 |
|
all-trans-Retinyl acetate, 1.5 million IU/g, in sunflower oil,
| 127-47-9 |
|
Cadmium Sulfate, P.A.
| 10124-36-4 |
|
n-Dodecyl-beta-D-maltoside (high purity), 99%
| 69227-93-6 |
|
3-Aminophthalhydrazide, also known as Luminol
| 521-31-3 |
|
1,2-Dimethylcyclohexane, 98%, Mixture of Cis and Trans
| 583-57-3 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride, 99% (titr.)
| 637-01-4 |
|
FMOC-L-Isoleucine, 99%
| 71989-23-6 |
|
Silica gel, 75-300 mesh
| 7631-86-9 |
|
3-Endo-Aminobicyclo(2,2,1,)Heptane-2-Endo-Carboxylic Acid, 98%
| 0-01-1 |
|
6-Chloro-1,3-Dimethyluracil
| 6972-27-6 |
|
Vinyloxytrimethylsilane
| 6213-94-1 |
|
3-Chloro-L-alanine
| 2731-73-9 |
|
Zinc, Dust
| 7440-66-6 |
|
|