**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 64-17-5 |Ethanol | 17.0 | 200-578-6 |
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methanol | <1.0 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 107-22-2 |Glyoxal | 10.0 | 203-474-9 |
|----------------|--------------------------------------|----------|-----------|
| 877-24-7 |Potassium hydrogen phthalate | 1.428 | 212-889-4 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 70-71 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 10 36/38 43 20 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes and skin. May cause sensitization by
skin contact. Harmful by inhalation.Possible risk of irreversible
effects.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Vapors may cause
eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause systemic
toxicity with acidosis. May cause liver and kidney damage. May cause
central nervous system depression, characterized by excitement,
followed by headache, dizziness, drowsiness, and nausea. Advanced
stages may cause collapse, unconsciousness, coma and possible death
due to respiratory failure.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney
damage. May cause effects similar to those described for ingestion.
May cause narcotic effects in high concentration. May cause
drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation and ingestion may cause effects similar to those of acute
inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and
water.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. If
breathing has ceased apply artificial respiration using oxygen and a
suitable mechanical device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Flammable Liquid. Can release vapors
that form explosive mixtures at temperatures above the flashpoint.
Use water spray to keep fire-exposed containers cool. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water fog, dry chemical, carbon dioxide, or regular
foam. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce
vapors. Water spray may reduce vapor but may not prevent ignition in
closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 64-17-5:
United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA
United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA
Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE
France - VME: 1000 ppm VME; 1900 mg/m3 VME
France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE
Germany: 500 ppm TWA; 960 mg/m3 TWA
Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA
Netherlands: 500 ppm MAC; 1000 mg/m3 MAC
Russia: 1000 mg/m3 TWA
Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 107-22-2:
CAS# 877-24-7:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Alcoholic odor
pH: 4.0 - 4.3
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 99 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 113 deg F ( 45.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: <1
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of carbon.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 64-17-5: KQ6300000
CAS# 67-56-1: PC1400000
CAS# 107-22-2: MD2625000 MD2650000 MD2700000
CAS# 877-24-7: CZ4326000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat:
LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit:
LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 =
9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 107-22-2: Dermal, guinea pig: LD50 = 6600 mg/kg; Draize test,
rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 100 uL/24H
Moderate; Draize test, rabbit, eye: 100 uL Mild; Draize test, rabbit,
skin: 500 uL/4H Mild; Draize test, rabbit, skin: 10 mg/24H;
Inhalation, rat: LC50 = 2410 mg/m3/4H; Oral, mouse: LD50 = 400 mg/kg;
Oral, mouse: LD50 = 1280 mg/kg; Oral, rabbit: LD50 = >3175 mg/kg;
Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat:
LD50 = 4290 mg/kg; Oral, rat: LD50 = 2960 mg/kg; Skin, rabbit: LD50
= 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10
mL/kg; Skin, rat: LD50 = >2 gm/kg.
CAS# 877-24-7: Dermal, guinea pig: LD50 = >1 gm/kg; Oral, rat: LD50
= >3200 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Ethanol -
Not listed by ACGIH, IARC, or NTP.
Methanol -
Not listed by ACGIH, IARC, or NTP.
Glyoxal -
Not listed by ACGIH, IARC, or NTP.
Potassium hydrogen phthalate -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 107-22-2: 1
CAS# 877-24-7: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 107-22-2 is listed on Canada's DSL List.
CAS# 877-24-7 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 64-17-5 is listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 107-22-2 is listed on Canada's Ingredient Disclosure List.
CAS# 877-24-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 107-22-2 is listed on the TSCA inventory.
CAS# 877-24-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 6/15/1998 Revision #6 Date: 6/01/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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