**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 64-19-7 |Acetic acid | 48 | 200-580-7 |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 6131-90-4 |Acetate, sodium, trihydrate | <25 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 9002-93-1 |Ethoxylated p-tert-octylphenol | 5 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible
irreversible eye damage.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Causes severe skin
irritation and burns. May be harmful if absorbed through the skin.
Contact with the skin may cause blackening and hyperkeratosis of the
skin of the hands.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. Causes severe pain, nausea, vomiting,
diarrhea, and shock.
Inhalation:
Effects may be delayed. Irritation may lead to chemical pneumonitis
and pulmonary edema. Causes chemical burns to the respiratory tract.
Exposure may lead to bronchitis, pharyngitis, and dental erosion. May
be absorbed through the lungs.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated
inhalation may cause chronic bronchitis. Repeated exposure may cause
erosion of teeth. May cause reproductive and fetal effects.
Laboratory experiments have resulted in mutagenic effects. Prolonged
exposure may cause corneal erosion, conjunctivitis, and possible
blindness.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Persons with pre-existing skin disorders or impaired respiratory or
pulmonary function may be at increased risk to the effects of this
substance. Treat symptomatically and supportively.
Antidote:
No specific antidote exists.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Wear appropriate protective clothing
to prevent contact with skin and eyes. Wear a self-contained
breathing apparatus (SCBA) to prevent contact with thermal
decomposition products. Reacts with most metals to form highly
flammable hydrogen gas which can form explosive mixtures with air.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water fog, dry
chemical, carbon dioxide, or regular foam. Do NOT get water inside
containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to dilute spill to
a non-flammable mixture. Avoid runoff into storm sewers and ditches
which lead to waterways. Wash area with soap and water. Use water
spray to disperse the gas/vapor. Provide ventilation. Cover with
material such as dry soda ash or calcium carbonate and place into a
closed container for disposal. A vapor suppressing foam may be used
to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not get on skin or in eyes. Do not ingest
or inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store in a
suitable container in a dry area above the substance's freezing
point. Do not store near alkaline substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 64-19-7:
United States OSHA: 10 ppm TWA; 25 mg/m3 TWA
Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE
Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE
France - VLE: 10 ppm VLE; 25 mg/m3 VLE
Germany: 10 ppm TWA; 25 mg/m3 TWA
Japan: 10 ppm OEL; 25 mg/m3 OEL
Malaysia: 10 ppm TWA; 25 mg/m3 TWA
Netherlands: 10 ppm MAC; 25 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED
Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC
CAS# 127-09-3:
CAS# 6131-90-4:
CAS# 7732-18-5:
CAS# 9002-93-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acetaldehyde, 2-aminoethanol, ammonium nitrate, bromine
pentafluoride, chlorine trifluoride, chlorosulfonic acid, chromic
acid anhydride, acetic anhydride, diallyl methyl carbinol + ozone,
ethylene diamine, ethyleneimine, hydrogen peroxides, nitric acid,
nitric acid + acetone, oleum, perchloric acid, permanganates,
phosphorus isocyanate, phosphorus trichloride, potassium hydroxide,
potassium-tert-butoxide, sodium hydroxide, sodium peroxide, xylene,
metals, acid anhydrides, peroxides, amines, alcohols, calcium salts,
sodium salts, Attacks some forms of plastics, rubbers, and coatings.,
chromium trioxide, chromic anhydride, caustics (e.g. ammonia,
ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium
hydroxide), carbonates, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 64-19-7: AF1225000
CAS# 127-09-3: AJ4300010
CAS# 6131-90-4: AJ4580000
CAS# 7732-18-5: ZC0110000
CAS# 9002-93-1: MD0907700 YM0616666 YM0683332
LD50/LC50:
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation,
mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin,
rabbit: LD50 = 1060 uL/kg.
CAS# 127-09-3: Draize test, rabbit, eye: 10 mg Mild; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >30 gm/m3/1H;
Oral, mouse: LD50 = 6891 mg/kg; Oral, rat: LD50 = 3530 mg/kg; Skin,
rabbit: LD50 = >10 gm/kg.
CAS# 6131-90-4.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 9002-93-1: Draize test, rabbit, eye: 10 uL/24H Moderate; Draize
test, rabbit, skin: 500 uL/24H Mild; Oral, rat: LD50 = 1800 mg/kg;
Oral, rat: LD50 = 3800 mg/kg; Oral, rat: LD50 = 1900 mg/kg.
Carcinogenicity:
Acetic acid -
Not listed by ACGIH, IARC, or NTP.
Sodium acetate -
Not listed by ACGIH, IARC, or NTP.
Acetate, sodium, trihydrate -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Ethoxylated p-tert-octylphenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; CAS# 64-19-7:
UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; CAS# 64-19-7:
UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; CAS#
64-19-7: UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 =
8.86-11 mg/L; 5,15,25 min; CAS# 64-19-7: Microtox testFish: Fathead
Minnow: LC50 = 88 mg/L; 96 Hr; CAS# 64-19-7: Static bioassay @
18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; CAS# 64-19-7:
UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; CAS# 64-19-7:
UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; CAS#
64-19-7: UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 =
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ACETIC ACID SOLUTION
Hazard Class: 8
UN Number: 2790
Packing Group: II
IMO
Shipping Name: ACETIC ACID SOLUTION
Hazard Class: 8
UN Number: 2790
Packing Group: II
RID/ADR
Shipping Name: ACETIC ACID SOLUTION
Hazard Class: 8
UN Number: 2790
Packing group: II
USA RQ: CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 2 Keep out of reach of children.
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 64-19-7: 1
CAS# 127-09-3: 1
CAS# 6131-90-4: 1
CAS# 7732-18-5: No information available.
CAS# 9002-93-1: 1
Canada
CAS# 64-19-7 is listed on Canada's DSL List.
CAS# 127-09-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 9002-93-1 is listed on Canada's DSL List.
CAS# 64-19-7 is listed on Canada's Ingredient Disclosure List.
CAS# 127-09-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 6131-90-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 9002-93-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-19-7 is listed on the TSCA inventory.
CAS# 127-09-3 is listed on the TSCA inventory.
CAS# 6131-90-4 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 9002-93-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/23/1999 Revision #3 Date: 10/07/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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