**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 71-41-0 |Amyl alcohol | 75 | 200-752-1 |
|----------------|--------------------------------------|----------|-----------|
| 100-10-7 |Benzaldehyde, 4-(dimethylamino)- | 5.0 | 202-819-0 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrogen chloride | <25 | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause lacrimation (tearing), blurred
vision, and photophobia. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May be absorbed through the skin. Causes
symptoms similar to those of inhalation. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause effects similar to those for inhalation
exposure. Ingestion of large amounts may cause CNS depression.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. Irritation may lead to
chemical pneumonitis and pulmonary edema. May cause kidney damage.
Aspiration may lead to pulmonary edema. Vapors may cause dizziness
or suffocation. May cause burning sensation in the chest.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed. May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Use a spark-proof tool. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with skin and eyes. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Avoid ingestion
and inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 71-41-0:
Germany: 360 mg/m3 TWA
Russia: 10 mg/m3 TWA
CAS# 100-10-7:
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 42.8 deg C ( 109.04 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess
heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71-41-0: SB9800000
CAS# 100-10-7: CU5775000
CAS# 7647-01-0: MW4025000 MW4031000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 71-41-0: Draize test, rabbit, eye: 81 mg Severe; Draize test,
rabbit, eye: 5 uL/24H Severe; Draize test, rabbit, skin: 3200 mg/24H
Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Oral, mouse:
LD50 = 200 mg/kg; Oral, mouse: LD50 = 200 mg/kg; Oral, rat: LD50 =
5660 uL/kg; Oral, rat: LD50 = 370 mg/kg; Skin, rabbit: LD50 = 2830
uL/kg.
CAS# 100-10-7: Oral, mouse: LD50 = 800 mg/kg.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Amyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Benzaldehyde, 4-(dimethylamino)- -
Not listed by ACGIH, IARC, or NTP.
Hydrogen chloride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALCOHOLS, N.O.S. (CONTAINS AMYL ALCOHOL)
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: ALCOHOLS, N.O.S. (CONTAINS AMYL ALCOHOL)
Hazard Class: 3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: ALCOHOLS, N.O.S. (CONTAINS AMYL ALCOHOL)
Hazard Class: 3
UN Number: 1993
Packing group:
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 71-41-0: 1
CAS# 100-10-7: 2
CAS# 7647-01-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 71-41-0 is listed on Canada's DSL List.
CAS# 100-10-7 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 71-41-0 is listed on Canada's Ingredient Disclosure List.
CAS# 100-10-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71-41-0 is listed on the TSCA inventory.
CAS# 100-10-7 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36/37/38 Irritating to eyes, respiratory system and
skin.
MSDS Creation Date: 2/11/2002 Revision #2 Date: 7/26/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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