**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7790-98-9 |Ammonium Perchlorate | 99.8 | 232-235-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O
Risk Phrases: 44 9
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Risk of explosion if heated under confinement. Explosive when mixed
with combustible material.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal
opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause kidney damage. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown colored blood.
Overexposure may cause methemoglobinemia. May cause burns to the
gastrointestinal tract. May cause nausea, vomiting, and diarrhea,
possibly with blood.
Inhalation:
May cause methemoglobinemia, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), convulsions,
tachycardia, dyspnea (labored breathing), and death.
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown blood. May cause acute pulmonary edema, asphyxia,
chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before
reuse. Get medical aid if symptoms occur.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May be ignited by friction, heat, sparks, or
flame. May accelerate burning if involved in a fire. Containers may
explode when heated.
Extinguishing Media:
Use water only! Do NOT get water inside containers. Contact
professional fire-fighters immediately. Cool containers with
flooding quantities of water until well after fire is out. Do NOT use
dry chemicals, CO2, Halon or foams.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not use combustible materials such
as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with clothing and other
combustible materials. Do not get on skin or in eyes. Avoid
ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Keep container
closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7790-98-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: None reported.
pH: 5
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 210 C
Solubility in water: 10 g/100ml (0 C)
Specific Gravity/Density: 1.9500
Molecular Formula: H4ClNO4
Molecular Weight: 117.4853
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, ammonia and/or derivatives.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7790-98-9: SC7520000
LD50/LC50:
CAS# 7790-98-9: Oral, mouse: LD50 = 1900 mg/kg; Oral, rabbit: LD50 =
1900 mg/kg; Oral, rat: LD50 = 4200 mg/kg.
Carcinogenicity:
Ammonium Perchlorate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMMONIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1442
Packing Group: II
IMO
Shipping Name: AMMONIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1442
Packing Group: II
RID/ADR
Shipping Name: AMMONIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1442
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 44 Risk of explosion if heated under confinement.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 14B Keep away from organic material and metal
powders.
S 16 Keep away from sources of ignition - No
smoking.
S 27 Take off immediately all contaminated clothing.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 7790-98-9: 1
Canada
CAS# 7790-98-9 is listed on Canada's DSL List.
CAS# 7790-98-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7790-98-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 2/09/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
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Methyl trifluoroacetate, 99%
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| 24815-24-5 |
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3-Hydroxypropionitrile, P.A.
| 109-78-4 |
|
Dl-m-tyrosine, 98.5%
| 775-06-4 |
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Benzyl Isocyanate, 98%
| 3173-56-6 |
|
d-(-)-Erythrose, 85%
| 583-50-6 |
|
6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoli ne hydrochloride, 98%
| 2328-12-3 |
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2,3,4,5,6-Pentafluorobenzyl alcohol, 96-98%
| 440-60-8 |
|
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| 149-57-5 |
|
L-2-Pyrrolidone-5-carboxylic acid, 98%
| 98-79-3 |
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Tetramethylammonium perchlorate
| 2537-36-2 |
|
5-Iodovanillin, 97%
| 5438-36-8 |
|
(-)-Myrtenol, 97+%
| 515-00-4 |
|
p-Toluamide
| 619-55-6 |
|
7-??(Chlorocarbonyl)methoxy??-4-Methylcoumarin
| 91454-65-8 |
|
Methyl 3,5-dihydroxybenzoate, 97%
| 2150-44-9 |
|
Aluminum fluoride trihydrate, 97%
| 15098-87-0 |
|
Boc-L-Arginine, 99+%
| 13726-76-6 |
|
2-Mesitylenesulfonic acid dihydrate, 97%
| 3453-83-6 |
|
2-Bromo-2',4'-Dimethoxyacetophenone, 98%
| 60965-26-6 |
|
Pentamethylbenzyl Chloride, 97% (Titr.)
| 484-65-1 |
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cis-1,4-Dichloro-2-butene, 95%
| 1476-11-5 |
|
Aniline hydrochloride, 99%
| 142-04-1 |
|
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| 7790-98-9 |
|
Poly(N,N-dimethyl-3,5-dimethylene-piperidinium chloride) 20 wt.%
| 7732-18-5 |
|
Samarium atomic absorption standard solution, 1 mg/ml Sm in 2% HNO3
| 7440-19-9 |
|
3-Chloro-5-Methoxyphenol, 99%
| 65262-96-6 |
|
Ethyl 2-furoate, 99%
| 614-99-3 |
|
Cresol Red, Water Soluble, Indicator Grade
| 62625-29-0 |
|
L-Buthionine-S,R-Sulfoximine, 99%
| 83730-53-4 |
|
gamma-Butyrolactone, 99+%
| 96-48-0 |
|
Ethoxyamine Hydrochloride, 99+% (Titr.)
| 3332-29-4 |
|
2-Tert-Butylcyclohexanol, Mixture of Isomers, 99%
| 13491-79-7 |
|
L-(+)-Glutamic Acid Hydrochloride, 99%
| 138-15-8 |
|
Bis(trimethylsilyl)sulfate, 98%
| 18306-29-1 |
|
Alpha-Methyl-Alpha-Propylsuccinimide 99+%
| 1497-19-4 |
|
3-Bromopyridine, 99%
| 626-55-1 |
|
3-Nitrosalicylaldehyde, 98%
| 5274-70-4 |
|
5-Hydroxydopamine Hydrochloride, 99%
| 5720-26-3 |
|
n,n-bis(Trimethylsilyl)acetamide
| 10416-58-7 |
|
1,4-Diphenyl-1,3-butadiene, scintillation grade
| 886-65-7 |
|
Benzyl Chloride
| 100-44-7 |
|
2-Methyl-5-Nitroindole, 95+%
| 7570-47-0 |
|
2,5-Dimethyl-1H-benzimidazole, 99%
| 1792-41-2 |
|
2,4-Dimethoxybenzylamine Hydrochloride, 97%
| 20781-21-9 |
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3',4'-(Didecyloxy)Acetophenone, 98%
| 118468-33-0 |
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| 20780-53-4 |
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Metrizamide p.a.
| 31112-62-6 |
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|