**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 99-08-1 |3-Nitrotoluene | 99 | 202-728-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.Toxic.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Effects of contact may be delayed.
Ingestion:
Aspiration hazard. May cause digestive tract disturbances. May be
harmful if swallowed.
Inhalation:
May be fatal if inhaled. Aspiration may cause respiratory swelling
and pneumonitis. Aspiration may lead to pulmonary edema. Effects of
inhalation may be delayed.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Effects may be delayed. Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT use straight
streams of water. For small fires, use dry chemical, carbon dioxide,
or water spray. For large fires, use water spray, fog or regular
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 99-08-1:
United States OSHA: 5 ppm TWA; 30 mg/m3 TWA (Listed under
'Nitrotoluene')
France - VME: 2 ppm VME; 11 mg/m3 VME
Germany: 5 ppm TWA; 28 mg/m3 TWA
Germany: Skin absorber
Malaysia: 2 ppm TWA; 11 mg/m3 TWA
Netherlands: 1 ppm MAC; 6 mg/m3 MAC
Spain: 5 ppm VLA-ED; 29 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 1 mm Hg @50.2 C
Viscosity: Not available.
Boiling Point: 230 - 231 deg C
Freezing/Melting Point: 15 - 16 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: 1.6%
Explosion Limits, upper: Not available.
Decomposition Temperature: 270 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.1570g/cm3
Molecular Formula: C7H7NO2
Molecular Weight: 137.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 99-08-1: XT2975000
LD50/LC50:
CAS# 99-08-1: Inhalation, mouse: LC50 = 425 mg/m3; Inhalation, rat:
LC50 = 693 mg/m3; Oral, mouse: LD50 = 330 mg/kg; Oral, rabbit: LD50
= 1750 mg/kg; Oral, rat: LD50 = 1072 mg/kg.
Carcinogenicity:
3-Nitrotoluene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROTOLUENES, LIQUID
Hazard Class: 6.1
UN Number: 1664
Packing Group: II
IMO
Shipping Name: NITROTOLUENES, LIQUID
Hazard Class: 6.1
UN Number: 1664
Packing Group: II
RID/ADR
Shipping Name: NITROTOLUENES
Hazard Class: 6.1
UN Number: 1664
Packing group: II
USA RQ: CAS# 99-08-1: 1000 lb final RQ (Listed under Nitrotoluene); 454 kg final
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 99-08-1: 2
Canada
CAS# 99-08-1 is listed on Canada's DSL List.
CAS# 99-08-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-08-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/16/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Monomethyl monopotassiummalonate, 98%
| 38330-80-2 |
|
4-Bromomandelic Acid, 96% (HPLC)
| 6940-50-7 |
|
Stigmasterol, 95%
| 83-48-7 |
|
2-Chloro-6-Nitrotoluene, 99%
| 83-42-1 |
|
[Tris(trimethylsilyl)]arsenide, 98%
| 17729-30-5 |
|
1-Ethylquinaldinium Iodide, 97% (titr.)
| 606-55-3 |
|
L-Aspartyl-L-Phenylalanine Methyl Ester, 98%
| 22839-47-0 |
|
Primaquine diphosphate, 99+%
| 63-45-6 |
|
Ethyl 5-Hydroxy-2-Methylindole-3- Carboxylate
| 7598-91-6 |
|
(R)-(-)-1-Amino-2-Propanol, 98+%
| 2799-16-8 |
|
N-Methylthiourea, 97%
| 598-52-7 |
|
2,3,4,5,6-Pentafluoroanisole, 97+%
| 389-40-2 |
|
Cyclohexene Oxide, 98%
| 286-20-4 |
|
5-beta-Pregnane-3-alpha,20-alpha-diol, 99%
| 80-92-2 |
|
Cyclooctene Oxide, 99%
| 286-62-4 |
|
2-(4-Methoxyphenyl)-4,6-Diphenylpyrylium Tetrafluoroborate
| 2907-13-3 |
|
Sodium Hexafluoroantimonate, 98% (Titr.)
| 16925-25-0 |
|
Ethylene/Acrylic Acid Copolymer
| 9010-77-9 |
|
4-Fluoro-2-Nitrotoluene, 98%
| 446-10-6 |
|
N-Carbethoxy-4-Piperidone, 97+%
| 29976-53-2 |
|
3-Methylhippuric acid,98+%
| 27115-49-7 |
|
Amberlite cg-400 ion-exchange resin
| 37247-87-3 |
|
3-Nitrotoluene, 99%
| 99-08-1 |
|
1,3-Diphenylguanidine, 99% (uv-vis)
| 102-06-7 |
|
2-Bromo-4-Methylaniline, 98%
| 583-68-6 |
|
2,2'-Bithiophene
| 492-97-7 |
|
5,6-Dimethylbenzimidazole, 99+%
| 582-60-5 |
|
4-Butoxyaniline, 99% (titr.)
| 4344-55-2 |
|
Alpha-Cyano-O-Tolunitrile, Tech.
| 3759-28-2 |
|
DL-Laudanosoline Hydrobromide Trihydrate, 98%
| 485-33-6 |
|
4-Chloro-6-Nitro-Meta-Cresol, 99%
| 7147-89-9 |
|
2-Butanone oxime, 99%
| 96-29-7 |
|
Hexachloropropene, 96%
| 1888-71-7 |
|
Isopropyl Chloroacetate, 99%
| 105-48-6 |
|
3-Methylpentane, 99+%
| 96-14-0 |
|
1,4-Cyclohexanedicarboxylic Acid, 96% (Titr.)
| 1076-97-7 |
|
Azoxybenzene, 97%
| 495-48-7 |
|
l-(+)-Lactic acid, lithium salt
| 27848-80-2 |
|
4-Hexylresorcinol, 99%
| 136-77-6 |
|
Tantalum (V) Chloride, 99.9%
| 7721-01-9 |
|
2,4,5-Trimethylthiazole, 99%
| 13623-11-5 |
|
Cycloheptane, 99%
| 291-64-5 |
|
Phenylglyoxal monohydrate, 97%
| 1074-12-0 |
|
Ethyl Carbazate, 97%
| 4114-31-2 |
|
bis(Methylthio)methane, 99+%
| 1618-26-4 |
|
1-Bromo-4-Tert-Butylbenzene, 97+%
| 3972-65-4 |
|
(S)-(+)-2-Amino-2-methylbutanoic acid monohydrate, 99+% (>99% e.e.)
| 0-00-0 |
|
2-Furonitrile, 99%
| 617-90-3 |
|
l-Adrenaline, 97% (titr.)
| 51-43-4 |
|
4-(3-Methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid, 98+%
| 60875-16-3 |
|
|