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MSDS  : Menthol
CAS  : 89-78-1
SYNONYMS  : * Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1-alpha,2-beta,5-alpha)- * Cyclohexanol, 2-isopropyl-5-methyl- * Hexahydrothymol * p-Menthan-3-ol * Menthol, cis-1,3,trans-1,4- * Menthol * Menthomenthol * 5-Methyl-2-(1-methylethyl)cyclohexanol * Peppermint camphor * Tra-kill tracheal mite killer
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : OT0350000
CHEMICAL NAME : Menthol
CAS REGISTRY NUMBER : 89-78-1
BEILSTEIN REFERENCE NO. : 1902288
REFERENCE : 2-06-00-00052 (Beilstein Handbook Reference)
LAST UPDATED : 199701
DATA ITEMS CITED : 11
MOLECULAR FORMULA : C10-H20-O
MOLECULAR WEIGHT : 156.30
WISWESSER LINE NOTATION : L6TJ AY1&1 BQ D1
COMPOUND DESCRIPTOR : Agricultural Chemical
Natural Product
Primary Irritant
SYNONYMS/TRADE NAMES :
* Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1-alpha,2-beta,5-alpha)-
* Cyclohexanol, 2-isopropyl-5-methyl-
* Hexahydrothymol
* p-Menthan-3-ol
* Menthol, cis-1,3,trans-1,4-
* Menthol
* Menthomenthol
* 5-Methyl-2-(1-methylethyl)cyclohexanol
* Peppermint camphor
* Tra-kill tracheal mite killer

*** HEALTH HAZARD DATA ***

** SKIN/EYE IRRITATION DATA **

TYPE OF TEST : Standard Draize test
ROUTE OF EXPOSURE : Administration into the eye
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 250 ug
REACTION SEVERITY : Severe
REFERENCE :
AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N.
Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918-
Volume(issue)/page/year: 29,1363,1946

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 3180 mg/kg
TOXIC EFFECTS :
Behavioral - ataxia
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For
publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 1500 mg/kg
TOXIC EFFECTS :
Behavioral - sleep
Behavioral - hallucinations, distorted perceptions
Behavioral - muscle weakness
REFERENCE :
APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil,
France) V.1- 1943- Volume(issue)/page/year: 10,481,1952

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intramuscular
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher
information, see NSAPCC. Volume(issue)/page/year: 222,244,1954

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 1800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4-
1898- Volume(issue)/page/year: 63,43,1939

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Mammal - cat
DOSE/DURATION : 1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
Ger. Dem. Rep.) Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intravenous
SPECIES OBSERVED : Mammal - cat
DOSE/DURATION : 37 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4-
1898- Volume(issue)/page/year: 63,43,1939

** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 22400 mg/kg/28D-I
TOXIC EFFECTS :
Behavioral - fluid intake
Liver - changes in liver weight
Blood - changes in other cell count (unspecified)
REFERENCE :
TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE
Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 19,207,1983

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - 44440
No. of Facilities: 3689 (estimated)
No. of Industries: 36
No. of Occupations: 35
No. of Employees: 25754 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 44440
No. of Facilities: 2880 (estimated)
No. of Industries: 28
No. of Occupations: 33
No. of Employees: 44233 (estimated)
No. of Female Employees: 31143 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY


*** END OF RECORD ***
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ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
para-Menth-1-en-4-ol 562-74-3
p-Menth-1-en-8-ol, (+-)- 2438-12-2
p-Menth-8-en-1-ol 138-87-4
p-Menth-8-en-2-ol 619-01-2
p-Menth-8-en-3-ol 7786-67-6
p-Menth-1-en-8-ol, acetate 80-26-2
Mandelamide, alpha-methyl- 2019-68-3
p-Menth-8-en-2-ol, acetate 20777-49-5
p-Menth-1-en-8-ol, formate (mixed isomers) 2153-26-6
p-Menth-1-en-3-one 89-81-6
p-Menth-4(8)-en-3-one 15932-80-6
p-Menth-4(8)-en-3-one, (R)-(+)- 89-82-7
p-Menth-8-en-2-one 7764-50-3
p-Menth-8-en-3-one, trans- 29606-79-9
L-Methionine, N-(1-oxo-3-phenyl-2-propenyl)-, methylester, (E)- 127750-59-8
Menthol 89-78-1
Menthol, (+)-neo- 63975-60-0
Mandelamide, N-(4-methyl-2-pyridyl)-, hydrochloride 3372-94-9
Menthol, trans-1,3,cis-1,4-, (+)- 63903-52-6
dl-Menthol 15356-70-4
l-Menthol 2216-51-5
Menthol, cis-1,3-cis-1,4-(+-)- 3623-52-7
Menthol, trans-1,3-cis-1,4-(+-)- 3623-51-6
Menthol, isovalerate 16409-46-4
Mentor 28 63148-53-8
Mentzelia decapetala (pursh.) Urb. & Gilg., alkaloidextractSUBSTANCE DEFINITION :Alkaloids obtained from the plant belonging to the family LoasaceaeREFERENCE :JNPRDF Journal of Natural Products. (Spahr & Glenn Co., 225 E. Spring St.,Columbus, OH 43215) V.42- 1979- Volume(issue)/page/year: 44,693,1981 63148-53-8
p-Mercapto sulfadiazine 67479-03-2
Mercurate(1-), acetatophenyl-, ammonium salt 34604-38-1
Mandelamide, N-(5-methyl-2-pyridyl)-, hydrochloride 1086-88-0
Mercurate(1-), (acetato-O)amidophenyl-, hydrogen 53404-67-4
Mercurate(1-), amidophenyl(propanoato-O)-, hydrogen 53404-68-5
Mercurate(4-),bis(N,N-bis(carboxymethyl)glycinato(3-)-N,O,O',O'')-,tetrahydrogen 73128-65-1
Mercurate(1-), butyl(mercaptoacetato(2-)-O,S-),sodium 64048-05-1
Mercurate(1-),(3-(5-carboxylato-1,2-dihydro-2-oxo-1-pyridinyl)-2-methoxypropyl)hydroxy-, sodium, compd. with3,7-dihydro-1,3-dimethyl-1H-purine-2,6-dione 7097-62-3
Mercurate(1-)-,(3-(4-(carboxylatomethoxy)phenyl)-2-hydroxypropyl)hydroxy-, sodium 63907-33-5
Mercurate(1-),(3-((((3-carboxylato-1-oxopropyl)amino)carbonyl)amino)-2-methoxypropyl) hydroxy-, sodium, mixed with3,7-dihydro-1,3-dimethyl-1H-purine-2,6-dione 8069-64-5
Mercurate(2-), ((cyclohexylenedinitrilo)tetracetato)- 8069-64-5
Mercurate(1-), (L-cysteinato(2-)-S)methyl-, hydrogen 32754-35-1
Mercurate(1-), ethyl(mercaptoacetato(2-)-O,S)-,potassium 64048-06-2
Mandelamide, N-phenyl-alpha-propyl- 39164-86-8
Mercurate(1-), (mercaptoacetato(2-)-O,S)methyl-,sodium 64048-07-3
Mercurate (2-), tetraiodo-, dipotassium 7783-33-7
Mercury 7439-97-6
Mercury, (3-acetamido-2-methoxypropyl)chloro- 7439-97-6
Mercury,acetato(5-(2-amino-2-carboxyethyl)-2-hydroxyphenyl)- 7439-97-6
Mercury, acetato(2-amino-5-carboxyphenyl)- 7439-97-6
Mercury, acetato(4-amino-2-carboxyphenyl)- 7439-97-6
Mercury, acetato(4-amino-3-carboxyphenyl)- 7439-97-6
Mercury, acetato(5-amino-2-hydroxyphenyl)- 7439-97-6
Mercury,(acetato-O)(3-((4-amino-6-methyl-1,3,5-triazin-2-yl)amino)-2-hydroxypropyl )- 7439-97-6

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