| MSDS | : | HEAVY DRIP CHECK SEALER 08531 | | CAS | : | 108-88-3
9003-18-3
68611-24-5
628-63-7
112945-52-5
69-72-7
1314-13-2
13463-67-7 | | NAME | : | toluene (sara 313) (cercla) bp: 232f,111c.
acrylonitrile butadiene polymer
magnesium resinate; (phenol, polymer with formaldehyde, magnesium oxide
acetic acid, pentyl ester; (n-amyl acetate) (cercla)
silicon dioxide; (silica)
salicylic acid
zinc oxide (sara 313) (cercla)
titanium oxide; (titanium dioxide)
volatile organic compound & voc less h*2o & exempt solvents: 587
supdat: dizz, drow, musc weak, inccordination, slowed rxn time, fatigue,
ing 10: tremors & convls. aspir pneum: signs/symps can incl cough,
ing 11: pneumonia, which can be fatal.
spill proc: tools. cover w/inorganic absorbent material. place in u.s.
prot gloves: alcohol, polyvinyl alcohol, polytetrafluoroethylene
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3M GENERAL OFFICES -- HEAVY DRIP CHECK SEALER 08531
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Material Safety Data Sheet
=======================================================
MSDS Num: BXWRL
MSDS NAME: HEAVY DRIP CHECK SEALER 08531
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
=======================================================
Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
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Ingredients
=======================================================
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA) BP: 232F,111C.
% Wt: 40-50
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 9003-18-3
Name: ACRYLONITRILE BUTADIENE POLYMER
% Wt: 10-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 68611-24-5
Name: MAGNESIUM RESINATE; (PHENOL, POLYMER WITH FORMALDEHYDE, MAGNESIUM OXIDE
COMPLEX)
% Wt: 10-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 628-63-7
RTECS #: AJ1925000
Name: ACETIC ACID, PENTYL ESTER; (N-AMYL ACETATE) (CERCLA)
% Wt: 10-20
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICON DIOXIDE; (SILICA)
% Wt: 1-5
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 69-72-7
RTECS #: VO0525000
Name: SALICYLIC ACID
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1314-13-2
RTECS #: ZH4810000
Name: ZINC OXIDE (SARA 313) (CERCLA)
% Wt: 1-5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 1-5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND & VOC LESS H*2O & EXEMPT SOLVENTS: 587
G/L SCAQMD RULE 443.1, CALCULATED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: DIZZ, DROW, MUSC WEAK, INCCORDINATION, SLOWED RXN TIME, FATIGUE,
BLURRED VISION, SLURRED SPEECH, GIDD,
-----------------------------
Name: ING 10: TREMORS & CONVLS. ASPIR PNEUM: SIGNS/SYMPS CAN INCL COUGH,
DFCLTY BRTHG, WHEEZ, COUGHING UP BLOOD &
-----------------------------
Name: ING 11: PNEUMONIA, WHICH CAN BE FATAL.
-----------------------------
Name: SPILL PROC: TOOLS. COVER W/INORGANIC ABSORBENT MATERIAL. PLACE IN U.S.
DOT-APPROVED CONTAINER & SEAL.
-----------------------------
Name: PROT GLOVES: ALCOHOL, POLYVINYL ALCOHOL, POLYTETRAFLUOROETHYLENE
(TEFLON), FLUOROELASTOMER (VITON) ARE RECOM MATLS.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOLEUNE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS.
SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST
INFO & SAFE HNDLG & EXPOS INFO(FP N). EYES:MOD IRRIT: SIGNS/SYMPS
CAN INCL REDNESS, SWELL, PAIN, TEARING& HAZY VISION. SKIN:MILD IRRIT
(AFTER PRLNG/RPTD CNTCT): (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: SIGNS/SYMPS CAN INCL REDNESS,
SWELL & ITCH. INHAL:CNS DEPRESS: SIGNS/SYMPS CAN INCL HDCH, DIZZ, DROW,
INCOORDINATION, SLOWED RXN TIME, SLURRED SPEECH, GIDD & UNCON. IRRIT
(UPPER RESP): SIGNS /SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGH,
SNEEZING. INGEST:MAY CAUSE IRRIT OF GI TISS: SIGNS/SYMPS CAN (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMED FLUSH W/LARGE AMOUNTS OF WATER. GET IMMED MEDICAL
ATTENTION. SKIN: FLUSH W/LARGE AMOUNTS OF WATER. IF IRRIT PERSISTS, GET
MEDICAL ATTENTION. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, G IVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GET IMMED MEDICAL
ATTENTION. INGEST: CALL MD IMMED. ONLY INDUCE VOMITING AT INSTRUCTION OF MD.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSSON.
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Handling and Disposal
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Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HEALTH HAZS, RESP PROT, VENT & PERSONAL PROT EQUIP. CALL
612-733-1110 OR 612-733-6100 FOR 24-HR SPILL ASSISTANCE. VENT AREA. EXTING
ALL IG NIT SOURCES. COLLECT USING NON-SPARKING
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCIN IN PERMITTED HAZ WASTE INCINERATOR IN PRESENCE OF
COMBUST MATL. DISP OF WASTE PROD IN FACILITY PERMITTED TO ACCEPT CHEM WASTE.
SINCE REGS VARY, CONSULT APPLIC FED, STATE & LOC REGS OR AUTHS BEFO RE
DISP. U.S. EPA HAZ WASTE NUMBER=D001(IGNIT).
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF THE REACH OF CHILDREN.
Other Precautions: KEEP CONTAINER TIGHTLY CLOSED. FLAMMABLE LIQUID AND VAPOR.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF IGNITION.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point Text: 40.0F,4.4C
Lower Limits: 1.00%
Upper Limits: 7.00%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FPN),
INCL HELMET, BUNKER COAT & PANTS, BAND AROUND ARMS, WAIST & LEGS,
FACE MASK & PROT COVER FOR EXPOS AREAS OF HEAD.
Unusual Fire/Explosion Hazard: CLSD CNTNRS EXPOSED TO HEAT FROM FIRE MAY BUILD
PRESS & EXPLODE. VAPS MAY TRAVEL LONG DISTANCES ALONG GROUND OR FLOOR TO
AN IGNITION SOURCE & FLASH BACK.
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Control Measures
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Respiratory Protection: AVOID PROLONGED BREATHING OF VAPORS. NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: USE IN WELL-VENT AREA. PROVIDE SUFFICIENT VENTILATION TO MAINTAIN
EMISSIONS BELOW RECOMMENDED EXPOSURE LIMITS.
Protective Gloves: POLYETHYLENE/ETHYLENE VINYL
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: AVOID SKIN CONTACT. DO NOT INGEST.
Supplemental Safety and Health: EFTS OF OVEREXP: INCL PAIN, VOMIT, ABDOM
TENDERNESS, NAUS, BLOOD IN VOMITUS & IN FECES. WHILE FOLLOWING EFTS ARE
ASSOC W/ONE OR MORE INGREDS IN PROD & ARE REQD TO BE INCL ON MSDS BY OSHA
STDS, THEY AR E NOT EXPECTED EFTS DURING FORESEEABLE USE OF PROD: INGEST MAY
CAUSE: CNS DEPRESS: SIGNS/SYMPS CAN INCL HDCH,
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE ING 1
Vapor Pres: 25.19 @68F
Vapor Density: 4.00
Spec Gravity: 0.970 (H*2O=1)
Evaporation Rate & Reference: 6.00 (ETHER =1)
Solubility in Water: VERY SLIGHT
Appearance and Odor: HEAVY SYRUP; SOLVENT ODOR.
Percent Volatiles by Volume: 52 WT
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Reactivity Data
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Stability Indicator: YES
Hazardous Decomposition Products: CARBON MMONOXIDE AND CARBON DIOIXDE, TOXIC
VAPORS, GASES OR PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: HEAVY DRIP CHECK SEALER 08531
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 05/24/1995
Status Code: C
Label Date: 05/24/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. DECOMPOSITION PRODUCTS MAY BE TOXIC. ACUTE:
EYES: MODERATE IRRITATION WITH REDNESS, SWELLING, PAIN, TEARING & HAZY
VISION. SKIN: MILD IRRITATION WITH REDNESS, SWELLING & ITCH. INHALATION:
C NS DEPRESSION WITH HEADACHE, DIZZINESS,DROWSINESS, INCOORDINATION, SLOWED
REACTION TIME, SLURRED SPEECH, GIDDINESS & UNCONSCIOUSNESS. UPPER
RESPIRATORY IRRITATION CAN INCLUDE SORENESS OF NOSE & THROAT , COUGHING
& SNEEZING. INGESTION: MAY CAUSE IRRITATION OF GI TISSUES WITH PAIN,
VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS & IN FECES.
CHRONIC: TOLUENE APPEARS ON THE NAVY OCCUPATIONAL C HEMICAL REPRODUCTIVE
HAZARDS LIST (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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