| MSDS | : | 379B9500/2904, 379 HIGH SOLIDS GLOSS (SUPP DATA) | | CAS | : | 7727-43-7
110-43-0
123-86-4
75-56-9
13463-67-7
1330-20-7 | | NAME | : | acrylic resin
barium sulfate
2-heptanone; (methyl n-amyl ketone). vp:2.14. ld50:(oral,rat) 1600 mg/kg.
polyol; (modified polyol)
acetic acid, butyl ester; (n-butyl acetate) (cercla). vp:13.
propane, 1,2-epoxy-; (propylene oxide) (sara 302/313) (cercla). vp:440.
titanium oxide; (titanium dioxide). ld50:(rat) >24,000 mg/kg.
xylene (sara 313) (cercla). vp:6. ld50:(oral,rat) >5 gm/kg.
volatile organic compounds: 375.63 g/l.
supdat:cutting torch on/near cntnr (even empty) as prod/its residue may
ing 10:decomp prods may cause a health hazard. symptoms may not be
explan of carcin:be carcinogen. animal:blood & gastrointestinal.
first aid proc:vomiting. aspiration of vomitus can cause chemical
spill proc:absorbent & non-sparking tools. store in closed container
other prec:build-up of vaps by maintaining continuous flow of fresh air.
ing 15:flame. store lg qtys in bldgs to comply w/osha 1910.104. keep
ing 16:contents to bottles/other unlabelled cntnrs. do not reuse empty
ing 17:component product, then mixture of base & converter portions
resp prot:msha apprvd chem/mech filter designed to remove combination of
ing 19:confined areas, wear niosh/msha apprvd air supply resps/use hoods.
ing 20:cutting, welding, brazing & sanding material coated w/this
vent:stds in mixing, application & curing areas & to remove
ing 22:during welding & flame cutting on surfs coated w/this prod.
ing 23:removing heavy solv vaps from lower levels of the work area.
other prot equip:skin contact are recommended.
|
| |
|
|
DEVOE COATINGS CO -- 379B9500/2904, 379 HIGH SOLIDS GLOSS (SUPP DA
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BXXCD
MSDS NAME: 379B9500/2904, 379 HIGH SOLIDS GLOSS (SUPP DATA)
Responsible Party
Name: DEVOE COATINGS CO
Address: 4000 DUPONT CIRCLE
City: LOUISVILLE KY 40207
Info Phone: 502-897-9861
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DEVOE COATINGS CO
Address: 4000 DUPONT CIRCLE
Box: 7600
City: LOUISVILLE KY 40207-4802
Phone: 502-897-9861
=======================================================
Ingredients
=======================================================
Name: ACRYLIC RESIN
% Wt: 30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 7727-43-7
RTECS #: CR0600000
Name: BARIUM SULFATE
% Wt: 10
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 110-43-0
RTECS #: MJ5075000
Name: 2-HEPTANONE; (METHYL N-AMYL KETONE). VP:2.14. LD50:(ORAL,RAT) 1600 MG/KG.
% Wt: 15
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
------------------------------
Name: POLYOL; (MODIFIED POLYOL)
% Wt: <5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 123-86-4
RTECS #: AF7350000
Name: ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA). VP:13.
LD50:(ORAL,RAT) 14 GM/KG.
% Wt: 15
OSHA PEL: 150 PPM
ACGIH TLV: 150 PPM;200 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 75-56-9
RTECS #: TZ2975000
Name: PROPANE, 1,2-EPOXY-; (PROPYLENE OXIDE) (SARA 302/313) (CERCLA). VP:440.
% Wt: <0.5
OSHA PEL: 100 PPM
ACGIH TLV: 20 PPM
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE). LD50:(RAT) >24,000 MG/KG.
% Wt: 25
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). VP:6. LD50:(ORAL,RAT) >5 GM/KG.
% Wt: <5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM;150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 375.63 G/L.
-----------------------------
Name: SUPDAT:CUTTING TORCH ON/NEAR CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE MAY
IGNITE. DURING EMER CNDTNS OVEREXP TO
-----------------------------
Name: ING 10:DECOMP PRODS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.
-----------------------------
Name: EXPLAN OF CARCIN:BE CARCINOGEN. ANIMAL:BLOOD & GASTROINTESTINAL.
-----------------------------
Name: FIRST AID PROC:VOMITING. ASPIRATION OF VOMITUS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL.
-----------------------------
Name: SPILL PROC:ABSORBENT & NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER
UNTIL PRODUCT DISPOSED OF.
-----------------------------
Name: OTHER PREC:BUILD-UP OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR.
DO NOT STORE >120F/NEAR FIRE/OPEN
-----------------------------
Name: ING 15:FLAME. STORE LG QTYS IN BLDGS TO COMPLY W/OSHA 1910.104. KEEP
CNTNR CLSD WHEN NOT IN USE. DO NOT TRANSFER
-----------------------------
Name: ING 16:CONTENTS TO BOTTLES/OTHER UNLABELLED CNTNRS. DO NOT REUSE EMPTY
CNTNRS. IF THIS MATL IS PART OF A TWO
-----------------------------
Name: ING 17:COMPONENT PRODUCT, THEN MIXTURE OF BASE & CONVERTER PORTIONS
WILL HAVE HAZARDS OF BOTH COMPONENTS.
-----------------------------
Name: RESP PROT:MSHA APPRVD CHEM/MECH FILTER DESIGNED TO REMOVE COMBINATION OF
PARTICULATES & VAP. WHEN USED IN
-----------------------------
Name: ING 19:CONFINED AREAS, WEAR NIOSH/MSHA APPRVD AIR SUPPLY RESPS/USE HOODS.
USE NIOSH/MSHA APPRVD RESP WHEN FLAME
-----------------------------
Name: ING 20:CUTTING, WELDING, BRAZING & SANDING MATERIAL COATED W/THIS
PRODUCT.
-----------------------------
Name: VENT:STDS IN MIXING, APPLICATION & CURING AREAS & TO REMOVE
SANDING DUSTS OF DRIED COATINGS & DECOMP PRODS
-----------------------------
Name: ING 22:DURING WELDING & FLAME CUTTING ON SURFS COATED W/THIS PROD.
VAPS MAY SPREAD LONG DIST. PVNT BUILD-UP BY
-----------------------------
Name: ING 23:REMOVING HEAVY SOLV VAPS FROM LOWER LEVELS OF THE WORK AREA.
ELIMINATE ALL IGNITION SOURCES.
-----------------------------
Name: OTHER PROT EQUIP:SKIN CONTACT ARE RECOMMENDED.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:INHAL:IRRIT OF RESP TRACT; HDCH, NAUS, DIZZ, WEAK
& FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN RESP ARREST. SKIN/EYE
CONT:CAUSES EYE & SKIN IRRIT. MAY BE HARMFUL IF ABSORBED THRU SKIN.
INGEST: CAN CAUSE STOM &/OR INTESTINAL IRRIT, NAUS, VOMIT & DIARR.
CHRONIC:REPORTS HAVE ASSOC RPTD & PRLNG (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: PROPYLENE OXIDE:IARC MONOGRAPHS, SUPP, VOL 7,
PG 328, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO
Signs And Symptions Of Overexposure: HLTH HAZ:OCCUP OVEREXP TO SOLVS W/PERM
BRAIN & NERV SYS DMG. PRLNG/RPTD BRTHG OF SPRAY MIST &/OR SANDING
DUST OVER A PERIOD OF YRS MAY CAUSE DUST DISEASE OF LUNGS. NOTICE:INTENTIONAL
MISUSE BY DELIBER ATELY CONCENTRATING & INHALING THE CONTENTS MAY BE
HARMFUL OR FATAL.
Medical Cond Aggravated By Exposure: NONE, WHEN USED I/A/W SAFE HANDLING &
USE INFORMATION.
First Aid: INHAL:LEAVE AREA TO OBTAIN FRESH AIR. IF CONTINUED DFCLTY IS EXPER,
SUMMON MED ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING APPRVD CPR
TECHNIQUES, SUMMON MED HELP IMMED. EYES:FLUSH IMMED W/LG AMTS OF WATER FOR
AT LST 15 MINS. GET MED ASSISTANCE. SKIN:WASH AFFECTED AREAS W/SOAP &
WATER. REMOVE SOILED CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS.
INGEST:CONSULT MD IMMED. DO NOT INDUCE
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURFS &
ELEC, STATIC/FRICTIONAL SPKS). PVNT BRTHG OF VAPS. VENTILATE AREA. BEFORE
ATTEMPTING CLEAN-UP, REFER TO HAZ CAUT INFO IN OTHER SECTIONS OF THIS MSDS. C
ONTAIN SPILLED MATL & REMOVE W/INERT
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINERS.
Handling And Storage Precautions: DO NOT BREATHE VAPS, SPRAY MIST/SANDING DUST.
DO NOT GET ON SKIN/EYES. KEEP AWAY FROM HEAT, SPKS & FLAMES. DO NOT
SMOKE. OBSERVE ALL APPLIC PRECS.
Other Precautions: EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT
INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING USE &
UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLOSIVELY. VAPS MAY SPREAD LONG D
ISTS & BEYOND CLSD DOORS. PVNT
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 80.0F,26.7C
Lower Limits: 1%
Extinguishing Media: IN CASE OF FIRE USE CO*2, DRY CHEMICAL, FOAM OR OTHER NFPA
APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP
N). SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF WATER IS
USED, FOG NOZZ PREF. IF (SUPP DATA)
Unusual Fire/Explosion Hazard: KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT,
ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE FLASH FIRE. VAPS MAY IGNITE
EXPLOSIVELY. VAPS MAY SPREAD LONG (SUPP DATA)
=======================================================
Control Measures
=======================================================
Respiratory Protection: WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS & DURING
SANDING/GRINDING OPERATIONS, USE NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE
SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST. WHEN USED IN RESTR
ICTED VENT AREAS, WEAR NIOSH/
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
AIR CONTAM CONC BELOW CURRENT APPLIC SAFETY & HLTH
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). SOLV IMPERMEABLE CLTHG & BOOTS TO PVNT
Work Hygienic Practices: REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS
BEFORE EATING OR SMOKING.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO:ALIPHATIC URETHANE -
HAZE GRAY. FIRE FIGHT PROC:EXPOS TO FIRE/EXTREME HEAT, WATER SHOULD BE USED
TO COOL CLSD CNTNRS & PVNT PRESS BUILD UP/POSS AUTO-IGNIT. EXPLO
HAZ:DISTS & B EYOND CLSD DOORS. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS
TO EXTREME HEAT MAY EXPLODE. NEVER USE WELDING/
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >94F,>34C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 1.28 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 44.32
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONTACT W/STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY CAUSE TOXIC FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 379B9500/2904, 379 HIGH SOLIDS GLOSS (SUPP DATA)
Company: DEVOE COATINGS CO
Street: 4000 DUPONT CIRCLE
PO Box: 7600
City: LOUISVILLE KY
Zipcode: 40207-4802
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 07/06/1995
Status Code: C
Label Date: 07/06/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM LIQ CLASS IC. ACUTE:INHAL:IRRIT OF RESP TRACT;
HDCH, NAUS, DIZZ, WEAK & FATG. EXTREME EXPOS CAN RESULT IN UNCON &
EVEN RESP ARREST. SKIN/EYE CONT:CAUSES EYE & SKIN IRRIT. MAY BE HARMFUL
IF ABSOR BED THRU SKIN. INGEST:CAN CAUSE STOM &/OR INTEST IRRIT, NAUS,
VOMIT & DIARR. CHRONIC:CANCER HAZARD. CONTAINS PROPYLENE OXIDE WHICH IS
AN ANIMAL BLOOD & GI CARCINOGEN (FP N). REPORTS HAVE ASSOC RPTD &
PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. PRLNG/RPTD
BRTHG OF SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF YRS MAY CAUSE DUST
DISEASE OF THE LUNGS. INTENTIONAL MISUSE BY DELIB CONC & INHALING
CONTENTS MAY BE HARMFUL/FATAL.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|