ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for efts of overexp: (iron deposits in lungs) & is believed by some ing 19: arc rays can injure eyes and burn skin. electric shock can kill. vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 21: the worker's breathing zone and the general area. train the eye prot: when welding, use faceshield with filter lens. for more other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp msds toxicity property">
argon bp: -302.6f (-185.9c); sol in water: negligible; mp: -309f,-189c; sup dat: association's pamphlets p-1, p-9, p-14, safety bulletin sb-2, ing 3: prot cyls from physical dmg. store in cool, dry, well-ventd area ing 4: exits. do not allow temp where cyls are stored to exceed 125f ing 7: firmly secured to pvnt falling/being knocked over. full & ing 6: first out" inventory sys to pvnt full cyls being stored for excess ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for efts of overexp: (iron deposits in lungs) & is believed by some ing 19: arc rays can injure eyes and burn skin. electric shock can kill. vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 21: the worker's breathing zone and the general area. train the eye prot: when welding, use faceshield with filter lens. for more other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp msds toxicity property">
MSDS
:
BLUESHIELD 6.5
CAS
:
124-38-9 7440-37-1
NAME
:
carbon dioxide bp: -109.3f (-78.5c); sol in water: soluble; mp: argon bp: -302.6f (-185.9c); sol in water: negligible; mp: -309f,-189c; sup dat: association's pamphlets p-1, p-9, p-14, safety bulletin sb-2, ing 3: prot cyls from physical dmg. store in cool, dry, well-ventd area ing 4: exits. do not allow temp where cyls are stored to exceed 125f ing 7: firmly secured to pvnt falling/being knocked over. full & ing 6: first out" inventory sys to pvnt full cyls being stored for excess ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for efts of overexp: (iron deposits in lungs) & is believed by some ing 19: arc rays can injure eyes and burn skin. electric shock can kill. vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 21: the worker's breathing zone and the general area. train the eye prot: when welding, use faceshield with filter lens. for more other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp
LIQUID AIR CORP -- BLUESHIELD 6.5
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CDMZJ
MSDS NAME: BLUESHIELD 6.5
Responsible Party
Name: LIQUID AIR CORP
Address: 2121 NORTH CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Info Phone: 415-977-6580
Emergency Phone Number: 800-231-1366;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
=======================================================
Ingredients
=======================================================
Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE BP: -109.3F (-78.5C); SOL IN WATER: SOLUBLE; MP:
-70F,-57C; VP: 856 PSIA
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 7440-37-1
RTECS #: CF2300000
Name: ARGON BP: -302.6F (-185.9C); SOL IN WATER: NEGLIGIBLE; MP: -309F,-189C;
VP: > CRITICAL TEMPERATURE OF -188.1F
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: SUP DAT: ASSOCIATION'S PAMPHLETS P-1, P-9, P-14, SAFETY BULLETIN SB-2,
& L'AIR LIQUIDE'S ENCYCLOPEDIA DE GAZ.
-----------------------------
Name: ING 3: PROT CYLS FROM PHYSICAL DMG. STORE IN COOL, DRY, WELL-VENTD AREA
AWAY FROM HEAVILY TRAFFICKED AREAS & EMER
-----------------------------
Name: ING 4: EXITS. DO NOT ALLOW TEMP WHERE CYLS ARE STORED TO EXCEED 125F
(52C). CYLS SHOULD BE STORED UPRIGHT &
-----------------------------
Name: ING 7: FIRMLY SECURED TO PVNT FALLING/BEING KNOCKED OVER. FULL &
EMPTY CYLS SHOULD BE SEGREGATED. USE "FIRST IN-
-----------------------------
Name: ING 6: FIRST OUT" INVENTORY SYS TO PVNT FULL CYLS BEING STORED FOR EXCESS
PERIODS OF TIME. THIS MIX IS NONCORR
-----------------------------
Name: ING 7: & MAY BE USED W/ANY COMMON STRUCTURAL MATLS. COMPRESSED GAS
CYLS SHOULD NOT BE REFILLED EXCEPT BY
-----------------------------
Name: ING 8: QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENT OF COMPRESSED
GAS CYL WHICH HAS NOT BEEN FILLED BY THE
-----------------------------
Name: ING 9: OWNER OR W/HIS (WRITTEN) CONSENT IS A VIOLATION OF FED LAW
(49CFR). ALWAYS SECURE CYLS IN AN UPRIGHT
-----------------------------
Name: ING 10: POSITION BEFORE TRANSPORTING THEM. NEVER TRANSPORT CYLS IN TRUNKS
OF VEHICLES, ENCLSD VANS, TRUCK CABS/
-----------------------------
Name: ING 11: IN PASSENGER COMPARTMENTS. TRANSPORT CYLS SECURED IN OPEN
FLATBED/IN OPEN PICK-UP TYPE VEHICLES.
-----------------------------
Name: ING 12: AVOID BRTHG FUMES & GASES. USE ADEQ VENT. SEE ANSI Z-49-1
"SFTY IN WELDING & CUTTING" PUBLISHED BY THE
-----------------------------
Name: ING 13: AMERICAN WELDING SOCIETY. CONSULT HAZ WARNINGS ON BOXES/CONTRS
(OR ON TAGS/LABELS THEREON) CONTAINING
-----------------------------
Name: ING 14: BRAZING/WELDING FILLER METALS, FLUXES & FUSIBLE GRANULAR
MATLS. SEE OSHA SFTY REGS UNDER 29CFR 1910.252
-----------------------------
Name: ING 15: "WELDING, CUTTING & BRAZING". ALSO SEE ACGIH "TLV (1991-1992)
FOR CHEM SUBSTANCES IN WORK ENVIRON",
-----------------------------
Name: ING 16: APPENDIX B, SECTION B2 "WELDING FUMES" FOR FURTHER INFO. CONSULT
MFR'S MSDS ON WELDING CONSUMABLES &
-----------------------------
Name: ING 17: RELATED PRODS FOR REACTIVITY & HLTH HAZ DATA, & FOR
FURTHER INFO REGARDING WELDING FUMES.
-----------------------------
Name: EFTS OF OVEREXP: (IRON DEPOSITS IN LUNGS) & IS BELIEVED BY SOME
INVESTIGATORS TO AFFECT PULMONARY FUNCTION.
-----------------------------
Name: ING 19: ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL.
-----------------------------
Name: VENT: WHEN WELDING, USE ENOUGH VENT, LOC EXHST AT ARC/BOTH, TO KEEP
WELDING FUMES & GASES BELOW APPLIC TLV'S IN
-----------------------------
Name: ING 21: THE WORKER'S BREATHING ZONE AND THE GENERAL AREA. TRAIN THE
WELDER TO KEEP HIS HEAD OUT OF THE FUMES.
-----------------------------
Name: EYE PROT: WHEN WELDING, USE FACESHIELD WITH FILTER LENS. FOR MORE
SPECIFIC INFORMATION PLEASE CONTACT NEHC (FP N).
-----------------------------
Name: OTHER PROT EQUIP: WEAR HEAD, HAND & BODY PROT WHICH HELP TO PVNT
INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE ANSI
-----------------------------
Name: ING 24: Z-49-1. FOR MORE SPECIFIC INFORMATION, PLEASE CONTACT NEHC (FP
N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: CONCS OF 20-30% OF THESE MIXS WHEN INHALED W/ADEQ
OXYGEN IN AIR WILL CAUSE INCR IN RESP RATE. HIGHER CONCS WILL CAUSE HDCH,
NAUS & EVENTUAL UNCON. CARBON DIOXIDE IS THE MOST POWERFUL CEREBRAL V
ASOLIDATOR KNOWN. INHALING LGE CONCS CAUSES RAPID CIRCULATORY INSUFFICIENCY
LEADING TO COMA & DEATH. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CHRONIC HARMFUL EFTS ARE NOT
KNOWN FROM RPTD INHAL OF LOW (20-30%) CONCS OF THIS MIX. CAUTION:
WELDING/BRAZING MAY PRDCE FUMES & GASES HAZ TO HLTH. ACUTE OVEREXP TO
WELDING FUMES MAY RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS/DRYNESS/IRRIT OF
NOSE, THROAT/EYES. CHRONIC OVEREXP MAY LEAD TO SIDEROSIS
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO THESE MIXTURES SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THESE PRODUCTS.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP. RESCUE PERS
SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA. INHAL: CONSCIOUS PERS SHOULD BE
ASSISTED TO UNCONTAM AREA & INHALE FRESH AIR. QUICK REMOVAL FR OM CONTAM
AREA IS MOST IMPORTANT. UNCONPERS SHOULD BE MOVED TO UNCONTAM AREA, GIVEN
ASSISTED RESP & SUPP OXYGEN. FURTHER TREATMENT SHOULD BE SYMPTOMATIC
& SUPPORTIVE. EYES: FLUSH W/POTABLE (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE,
CONTACT THE CLOSES LIQUID AIR CORPORATION LOCATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT ATTEMPT TO DISP OF WASTE/UNUSED QTYS. RETURN IN
SHIPPING CONTR PROPERLY LABELED, W/ANY VALVE OUTLET PLUGS/CAPS SECURED TO MFR
FOR PROPER DISP. FOR EMER DISP, CONT CLOSEST MFR LOCATION. DISP OF I/A/W
LOC, STATE & FED REGULATIONS (FP N).
Handling And Storage Precautions: USE ONLY IN WELL-VENTD AREAS. VALVE PROT CAPS
MUST REMAIN IN PLACE UNLESS CYL IS SECURED W/VALVE OUTLET PIPED TO USE POINT.
Other Precautions: DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR
CYL MOVEMENT. USE PRESS REDUCING REGULATOR WHEN CONNECTING CYL TO LOWER PRESS
(<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR D ISCHARGE
RATE OF PROD FROM CYL.(SUP DAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-FLAMMABLE GAS MIXTURE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPRVD POS PRESS AIR LINE W/MASK/SCBA SHOULD BE
AVAIL FOR EMER USE. WHEN WELDING IN CONFINED SPACE/WHERE LOC EXHST/VENT DOES
NOT KEEP EXPOS BELOW WELDING FUME TLV'S, USE NIOSH APPRVD POSS PRESS AIR
LINE W/MASK/SCBA.
Ventilation: TO PVNT ACCUM OF HIGH CONCS OF GASES SO AS TO REDUCE OXYGEN LEVEL
IN AIR TO LESS THAN 18 MOLAR PERCENT.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD SFTY GOGG/GLASSES.
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WHEN WELDING, WEAR SFTY SHOES & APPROP HEAD & EYE PROT,
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: WATER FOR AT LEAST 15 MIN. SEE
MD (FP N). SKIN: FLUSH W/COPIOUS AMTS OF WATER. SEE MD (FP N). INGEST: CALL
MD IMMED (FP N). OTHER PREC: USE CHECK VALVE/TRAP IN DISCHARGE LINE TO PREVEN
T HAZARDOUS BACK FLOW INTO CYLINDER. FOR ADDITIONAL HANDLING RECOMMENDATIONS,
CONSULT COMPRESSED GAS
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
M.P/F.P Text: SEE INGS
Vapor Pres: SEE INGS
Spec Gravity: 1.39 (AIR=1)
Solubility in Water: SEE INGS
Appearance and Odor: COLORLESS, ODORLESS GAS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BLUESHIELD 6.5
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: 800-231-1366;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/21/1997
Status Code: C
Label Date: 03/21/1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: CONCENTRATIONS OF 20-30% OF THESE MIXTURES WHEN
INHALED WITH ADEQUATE OXYGEN IN AIR WILL CAUSE INCREASE IN RESPIRATORY RATE.
HIGHER CONCENTRATIONS WILL CAUSE HEADACHE, NAUSEA AND EVENTUAL UNCON
SCIOUSNESS. CARBON DIOXIDE IS THE MOST POWERFUL CEREBRAL VASOLIDATOR KNOWN.
INHALING LARGE CONCENTRATIONS CAUSES RAPID CIRCULATORY INSUFFICIENCY LEADING
TO COMA AND DEATH. CHRONIC: NONE SPECIFIED BY M ANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.