isopropyl alcohol (sara 313). vp:33 @ 20c 2-butanone; (methyl ethyl ketone) (mek) (sara 313) (cercla). vp:7.20 @ pigments supdat:(even empty) because product (even residue) may ignite efts of overexp:cause effects resembling those from inhalation of vapor. spill proc:fumes. keep out of drains, sewers/waterways. cont fire auth. ing 6:agencies. call spill response teams if large spill. other prec:prod residues (vapor, liquid, and/or solid), all hazardous resp prot:and gas and vap. in confined areas use niosh apprvd air line ing 9:necessary in any later mfg operations in which prod may become vent:resp to pvnt overexp. provide general dilution/loc exhaust vent to ing 11: in section below acceptable limit, lel in fire & ing 12:and to remove decomp prods during welding or flame cutting on prot gloves:neoprene buna n or nitrile. hygiene pract:been properly laundered.
LILLY INDUSTRIES INC -- PLASTILEASE 512-B 87-95, 18795
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 01-026-4065
MSDS Num: CDMXT
MSDS NAME: PLASTILEASE 512-B 87-95, 18795
Responsible Party
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Info Phone: 310-352-3087
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Preparer's Name: LEN PULMAN
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LILLY IND INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 310-352-3087
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 213-321-0710
=======================================================
Item Description Information
=======================================================
=======================================================
Ingredients
=======================================================
Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL (SARA 313). VP:33 @ 20C
% Wt: 40
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500 STEL
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). VP:7.20 @
20C
% Wt: 1
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM/300 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Name: PIGMENTS
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT:(EVEN EMPTY) BECAUSE PRODUCT (EVEN RESIDUE) MAY IGNITE
EXPLOSIVELY.
-----------------------------
Name: EFTS OF OVEREXP:CAUSE EFFECTS RESEMBLING THOSE FROM INHALATION OF VAPOR.
-----------------------------
Name: SPILL PROC:FUMES. KEEP OUT OF DRAINS, SEWERS/WATERWAYS. CONT FIRE AUTH.
NOTIFY LOCAL HLTH & POLLUTION CONTROL
-----------------------------
Name: ING 6:AGENCIES. CALL SPILL RESPONSE TEAMS IF LARGE SPILL.
-----------------------------
Name: OTHER PREC:PROD RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARDOUS
PRECAUTIONS GIVEN IN THIS MSDS MUST BE OBSERVED.
-----------------------------
Name: RESP PROT:AND GAS AND VAP. IN CONFINED AREAS USE NIOSH APPRVD AIR LINE
TYPE RESPS/HOODS. RESP PROT MAY ALSO BE
-----------------------------
Name: ING 9:NECESSARY IN ANY LATER MFG OPERATIONS IN WHICH PROD MAY BECOME
AIRBORNE IN FORM OF VAPOR OR DUST.
-----------------------------
Name: VENT:RESP TO PVNT OVEREXP. PROVIDE GENERAL DILUTION/LOC EXHAUST VENT TO
VOL & PATTERN TO KEEP TLV OF MOST HAZ
-----------------------------
Name: ING 11:INGRED IN INGRED SECTION BELOW ACCEPTABLE LIMIT, LEL IN FIRE &
EXPLO HAZ DATA SECTION BELOW STATED LIMIT,
-----------------------------
Name: ING 12:AND TO REMOVE DECOMP PRODS DURING WELDING OR FLAME CUTTING ON
SURFACES COATED WITH THIS PRODUCT.
-----------------------------
Name: PROT GLOVES:NEOPRENE BUNA N OR NITRILE.
-----------------------------
Name: HYGIENE PRACT:BEEN PROPERLY LAUNDERED.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:RPTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO
SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. DO NOT BREATHE
VAPS/S PRAY MIST. THIS PROD CONTAINS ORGANIC SOLVENTS WHICH MAY CAUSE EYE,
SKIN, & RESP TRACT IRRIT. SYMPS OF (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:EXPOS ARE:TEARING EYES; REDNESS,
DRYING & CRACKING OF SKIN; DIZZ, NAUS, & FATG FROM INHAL; & VOMIT
FROM INGEST. BASED ON PRESENCE OF COMPONENTS (02) PROD IS SEV IRRITATING TO
EYES. EXPOS MAY CAUSE EXTENSIVE CORNEAL INJURY. BASED ON PRESENCE OF
COMPONENTS (02) INGEST WILL CAUSE IRRIT OF GI TRACT & MAY
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:FLUSH W/LUKE WARM WATER FOR @ LST 15 MINS. CONT PHYS IMMED.
SKIN:FLUSH W/COPIOUS AMTS OF LUKE WARM WATER. REMOVE CONTAMD CLTHG PROMPTLY.
CONT PHYS IMMED. INHAL:REMOVE EXPOS INDIVIDUAL TO FRESH AIR . RESTORE BRTHG
IF REQD. RINSE MOUTH IMMED. GIVE EXPOS INDIVIDUAL 6-8 OUNCES OF LIQ. (NEVER
GIVE ANYTHING BY MOUTH TO UNCON PERSON). DO NOT INDUCE VOMIT UNLESS ADVISED
BY PHYS. CONT PHYS IMMED.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: STAY UPWIND & AWAY FROM SPILL UNLESS WEARING
APPROP PROT EQUIP. STOP AND/OR CONTAIN DISCHARGE IF IT MAY BE DONE SAFELY.
KEEP ALL SOURCES OF IGNIT AWAY. VENTILATE AREA OF SPILL. USE NON-SPARKING
TOOLS FOR CLEANUP. COVER W/INERT MATL TO REDUCE
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT FLUSH TO SEWER, WATERSHED, OR WATERWAY. DISPOSE
OF I/A/W LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
Handling And Storage Precautions: KEEP PROD CNTNRS COOL, DRY, AND AWAY FROM
SOURCES OF IGNIT. USE & STORE THIS PROD W/ADEQ VENT. DO NOT SMOKE IN
STORAGE AREAS.
Other Precautions: PERS SHOULD AVOID INHAL OF VAPS. PERSONAL CONT W/PROD SHOULD
BE AVOIDED. SHOULD CONT BE MADE, REMOVE SATURATED CLTHG & FLUSH AFFECTED
SKIN AREAS W/WATER. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED. S INCE
EMPTIED CNTNRS RETAIN
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 62.0F,16.7C
Lower Limits: 1.8%
Upper Limits: 12.0%
Extinguishing Media: USE CO*2, DRY CHEM/FOAM EXTINGUISHER. THE NFPA CLASS B
EXTING IS DESIGNED TO EXTING FIRES/IGNITING FROM BURNING LIQS.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER
SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS
BUILDUP & POSS AUTOIGNIT (SUPDAT)
Unusual Fire/Explosion Hazard: KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT,
ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNR MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. DO NOT APPLY TO HOT (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: IN OUTDOOR/OPEN AREAS USE NIOSH APPRVD MECH FILTER RESP
TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLIC. IN
RESTRICTED VENT AREAS USE NIOSH APPRVD CHEM-MECH FILTERS DESIGNED TO REM OVE
COMBINATION OF PARTICULATE
Ventilation: USE VENT AS REQD TO CONTROL VAP CONCS. AVOID PRLNGD/RPTD BRTHG OF
VAPS. IF EXPOS EXCEEDS TLV, USE NIOSH APPRVD
Protective Gloves: RESIST SUCH AS NATURAL RUBBER,
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: AN APRON SHOULD BE WORN TO AVOID SKIN CONTACT. ANSI
APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: WASH HANDS THOROUGHLY BEFORE EATING & USING WASHROOM.
REMOVE CONTAMD CLTHG IMMED & DO NOT WEAR UNTIL IT HAS
Supplemental Safety and Health: % VOLAT:94.06 (WT). FIRE FIGHT PROC:OR EXPLO
WHEN EXPOS TO EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF. HEAT PROT
PROC:CNTNRS EXPOS TO INTENSE HEAT FROM FIRES SHOULD BE COOLED W/WATER TO PVNT
VA P PRESS BUILDUP WHICH COULD RSLT IN CNTNR RUPTURE. EXPLO HAZ:SURFS. NEVER
USE WELDING/CUTTING TORCH ON/NEAR CNTNR
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >176F,>80C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Evaporation Rate & Reference: FASTER THAN BUTYL ACETATE
Solubility in Water: NOT KNOWN
Percent Volatiles by Volume: SUPDAT
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID EXPOSURE TO SPARKS, OPEN FLAME, HOT
SURFACES, AND ALL SOURCES OF HEAT AND IGNITION.
Materials To Avoid: THIS PRODUCT IS INCOMPATIBLE WITH STRONG ACIDS.
Hazardous Decomposition Products: MAY PRDCE HAZ FUMES WHEN HEATED TO DECOMP AS
IN WELDING. FUMES MAY CONTAIN CO, CO*2, & OXIDES OF NITROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PLASTILEASE 512-B 87-95, 18795
Assigned IND: Y
Company: LILLY INDUSTRIES INC
Street: 210 E ALONDRA BLVD
City: GARDENA CA
Zipcode: 90248
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 02/25/1997
Status Code: C
Label Date: 02/25/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE:DO NOT BREATHE VAPORS OR
SPRAY MIST. THIS PRODUCT CONTAINS ORGANIC SOLVENTS WHICH MAY CAUSE EYE, SKIN,
AND RESPIRATORY IRRITATION. MAY CAUSE VOMITING. CHRONIC:REPORTS HAVE A
SSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING CONTENTS MAY BE HAR MFUL OR FATAL.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.