ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 19: worker's brthg zone & general area. train welder to keep his eye prot: when welding wear helmet/use fshld w/filter lens. as gen rule, ing 21: weld zone. then go to next lighter shade which gives sufficient ing 22: & flash gogg, if nec, to shield others from arc rays other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp msds toxicity property">
argon bp: -302.6f (-185.9c) mp: -309f,-189c; vp: > critical sup dat: association's pamphlets p-1, p-9, p-14, sfty bulletin sb-2, ing 3: prot cyls from physical dmg. store in cool, dry, well-ventd area ing 4: exits. do not allow temp where cyls are stored to exceed 125f ing 7: firmly secured to pvnt falling/being knocked over. full & ing 6: first out" inventory sys to pvnt full cyls being stored for excess ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 19: worker's brthg zone & general area. train welder to keep his eye prot: when welding wear helmet/use fshld w/filter lens. as gen rule, ing 21: weld zone. then go to next lighter shade which gives sufficient ing 22: & flash gogg, if nec, to shield others from arc rays other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp msds toxicity property">
MSDS
:
BLUESHIELD 1.2
CAS
:
7440-59-7 7440-37-1
NAME
:
helium bp: -452.1f(-268.9c) mp: -456f,-271c; vp: > critical argon bp: -302.6f (-185.9c) mp: -309f,-189c; vp: > critical sup dat: association's pamphlets p-1, p-9, p-14, sfty bulletin sb-2, ing 3: prot cyls from physical dmg. store in cool, dry, well-ventd area ing 4: exits. do not allow temp where cyls are stored to exceed 125f ing 7: firmly secured to pvnt falling/being knocked over. full & ing 6: first out" inventory sys to pvnt full cyls being stored for excess ing 7: & may be used w/any common structural matls. compressed gas ing 8: qualified producers of compressed gases. shipment of compressed ing 9: owner or w/his (written) consent is a violation of fed law ing 10: position before transporting them. never transport cyls in trunks ing 11: in passenger compartments. transport cyls secured in open ing 12: avoid brthg fumes & gases. use adeq vent. see ansi z-49-1 ing 13: american welding society. consult haz warnings on boxes/contrs ing 14: brazing/welding filler metals, fluxes & fusible granular ing 15: "welding, cutting & brazing". also see acgih "tlv (1991-1992) ing 16: appendix b, section b2 "welding fumes" for further info. consult ing 17: related prods for reactivity & hlth haz data, & for vent: when welding, use enough vent, loc exhst at arc/both, to keep ing 19: worker's brthg zone & general area. train welder to keep his eye prot: when welding wear helmet/use fshld w/filter lens. as gen rule, ing 21: weld zone. then go to next lighter shade which gives sufficient ing 22: & flash gogg, if nec, to shield others from arc rays other prot equip: wear head, hand & body prot which help to pvnt ing 24: z-49-1. for more specific information, please contact nehc (fp
LIQUID AIR CORP -- BLUESHIELD 1.2
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CDMZH
MSDS NAME: BLUESHIELD 1.2
Responsible Party
Name: LIQUID AIR CORP
Address: 2121 NORTH CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Info Phone: 415-977-6580
Emergency Phone Number: 800-231-1366;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
=======================================================
Ingredients
=======================================================
Cas: 7440-59-7
RTECS #: MH6520000
Name: HELIUM BP: -452.1F(-268.9C) MP: -456F,-271C; VP: > CRITICAL
TEMPERATURE OF -450.2F
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 7440-37-1
RTECS #: CF2300000
Name: ARGON BP: -302.6F (-185.9C) MP: -309F,-189C; VP: > CRITICAL
TEMPERATURE OF -188.1F
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: SUP DAT: ASSOCIATION'S PAMPHLETS P-1, P-9, P-14, SFTY BULLETIN SB-2,
& L'AIR LIQUIDE'S ENCYCLOPEDIA DE GAZ.
-----------------------------
Name: ING 3: PROT CYLS FROM PHYSICAL DMG. STORE IN COOL, DRY, WELL-VENTD AREA
AWAY FROM HEAVILY TRAFFICKED AREAS & EMER
-----------------------------
Name: ING 4: EXITS. DO NOT ALLOW TEMP WHERE CYLS ARE STORED TO EXCEED 125F
(52C). CYLS SHOULD BE STORED UPRIGHT &
-----------------------------
Name: ING 7: FIRMLY SECURED TO PVNT FALLING/BEING KNOCKED OVER. FULL &
EMPTY CYLS SHOULD BE SEGREGATED. USE "FIRST IN-
-----------------------------
Name: ING 6: FIRST OUT" INVENTORY SYS TO PVNT FULL CYLS BEING STORED FOR EXCESS
PERIODS OF TIME. THIS MIX IS NONCORR
-----------------------------
Name: ING 7: & MAY BE USED W/ANY COMMON STRUCTURAL MATLS. COMPRESSED GAS
CYLS SHOULD NOT BE REFILLED EXCEPT BY
-----------------------------
Name: ING 8: QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENT OF COMPRESSED
GAS CYL WHICH HAS NOT BEEN FILLED BY THE
-----------------------------
Name: ING 9: OWNER OR W/HIS (WRITTEN) CONSENT IS A VIOLATION OF FED LAW
(49CFR). ALWAYS SECURE CYLS IN AN UPRIGHT
-----------------------------
Name: ING 10: POSITION BEFORE TRANSPORTING THEM. NEVER TRANSPORT CYLS IN TRUNKS
OF VEHICLES, ENCLSD VANS, TRUCK CABS/
-----------------------------
Name: ING 11: IN PASSENGER COMPARTMENTS. TRANSPORT CYLS SECURED IN OPEN
FLATBED/IN OPEN PICK-UP TYPE VEHICLES.
-----------------------------
Name: ING 12: AVOID BRTHG FUMES & GASES. USE ADEQ VENT. SEE ANSI Z-49-1
"SFTY IN WELDING & CUTTING" PUBLISHED BY THE
-----------------------------
Name: ING 13: AMERICAN WELDING SOCIETY. CONSULT HAZ WARNINGS ON BOXES/CONTRS
(OR ON TAGS/LABELS THEREON) CONTAINING
-----------------------------
Name: ING 14: BRAZING/WELDING FILLER METALS, FLUXES & FUSIBLE GRANULAR
MATLS. SEE OSHA SFTY REGS UNDER 29CFR 1910.252
-----------------------------
Name: ING 15: "WELDING, CUTTING & BRAZING". ALSO SEE ACGIH "TLV (1991-1992)
FOR CHEM SUBSTANCES IN WORK ENVIRON",
-----------------------------
Name: ING 16: APPENDIX B, SECTION B2 "WELDING FUMES" FOR FURTHER INFO. CONSULT
MFR'S MSDS ON WELDING CONSUMABLES &
-----------------------------
Name: ING 17: RELATED PRODS FOR REACTIVITY & HLTH HAZ DATA, & FOR
FURTHER INFO REGARDING WELDING FUMES.
-----------------------------
Name: VENT: WHEN WELDING, USE ENOUGH VENT, LOC EXHST AT ARC/BOTH, TO KEEP
WELDING FUMES & GASES BELOW APPLIC TLV'S IN
-----------------------------
Name: ING 19: WORKER'S BRTHG ZONE & GENERAL AREA. TRAIN WELDER TO KEEP HIS
HEAD OUT OF THE FUMES.
-----------------------------
Name: EYE PROT: WHEN WELDING WEAR HELMET/USE FSHLD W/FILTER LENS. AS GEN RULE,
START W/SHADE WHICH IS TOO DARK TO SEE
-----------------------------
Name: ING 21: WELD ZONE. THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT
VIEW OF WELD ZONE. PROVIDE PROT SCREENS
-----------------------------
Name: ING 22: & FLASH GOGG, IF NEC, TO SHIELD OTHERS FROM ARC RAYS
RADIATION WHICH CAN INJURE EYES & BURN SKIN.
-----------------------------
Name: OTHER PROT EQUIP: WEAR HEAD, HAND & BODY PROT WHICH HELP TO PVNT
INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE ANSI
-----------------------------
Name: ING 24: Z-49-1. FOR MORE SPECIFIC INFORMATION, PLEASE CONTACT NEHC (FP
N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EFTS OF EXPOS TO HIGH CONCS SO AS TO DISPLACE
OXYGEN IN AIR NEC FOR LIFE ARE HDCH, DIZZ, LABORED BRTHG & EVENTUAL
UNCON. THESE MIXS ARE NONTOX BUT LIBERATION OF LGE AMT IN CONFINED AREA COULD
D ISPLACE AMT OF OXYGEN IN AIR NEC TO SUPPORT LIFE. WELDING/BRAZING MAY PRDCE
FUMES & GASES HAZ TO HLTH. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: ACUTE OVEREXP TO WELDING FUMES
MAY RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS/DRYNESS/IRRIT OF NOSE, THROAT/EYES.
CHRONIC OVEREXP MAY LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNGS) & IS
BELIEVED BY S OME INVESTIGATORS TO AFFECT PULM FUNC. ARC RAYS CAN INJURE EYES
& BURN SKIN. ELEC SHOCK CAN KILL.
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO THESE MIXTURES SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THESE PRODUCTS.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP. RESCUE PERS
SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA. INHAL: CONSCIOUS PERS SHOULD BE
ASSISTED TO UNCONTAM AREA & INHALE FRESH AIR. QUICK REMOVAL FR OM CONTAM
AREA IS MOST IMPORTANT. UNCONPERS SHOULD BE MOVED TO UNCONTAM AREA, GIVEN
ASSISTED RESP & SUPP OXYGEN. FURTHER TREATMENT SHOULD BE SYMPTOMATIC
& SUPPORTIVE. EYES: FLUSH W/POTABLE (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE,
CONTACT THE CLOSES LIQUID AIR CORPORATION LOCATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT ATTEMPT TO DISP OF WASTE/UNUSED QTYS. RETURN IN
SHIPPING CONTR PROPERLY LABELED, W/ANY VALVE OUTLET PLUGS/CAPS SECURED TO MFR
FOR PROPER DISP. FOR EMER DISP, CONT CLOSEST MFR LOCATION. DISP OF I/A/W
LOC, STATE & FED REGULATIONS (FP N).
Handling And Storage Precautions: USE ONLY IN WELL-VENTD AREAS. VALVE PROT CAPS
MUST REMAIN IN PLACE UNLESS CYL IS SECURED W/VALVE OUTLET PIPED TO USE POINT.
Other Precautions: DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR
CYL MOVEMENT. USE PRESS REDUCING REGULATOR WHEN CONNECTING CYL TO LOWER PRESS
(<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR D ISCHARGE
RATE OF PROD FROM (SUP DAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-FLAMMABLE GAS MIXTURE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST
OR VENTILATION DOES NOT KEEP EXPOSURE BELOW WELDING FUME TLV, USE NIOSH
APPROVED POSITIBE PRESSURE AIR LINE WITH MASK OR SCBA.
Ventilation: TO PVNT ACCUM OF HIGH CONCS OF GASES SO AS TO REDUCE OXYGEN LEVEL
IN AIR TO LESS THAN 18 MOLAR PERCENT.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD SFTY GOGG/GLASSES.
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
SFTY SHOES & APPROP HEAD & EYE PROT WHEN WELDING. WHEN WELDING,
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: SPEC GRAV: 1.13-1.32 (AIR=1). FIRST AID PROC:
WATER FOR AT LEAST 15 MIN. SEE MD (FP N). SKIN: FLUSH W/COPIOUS AMTS OF
WATER. SEE MD (FP N). INGEST: CALL MD IMMED (FP N). OTHER PREC: CYL. USE
CHECK VAL VE/TRAP IN DISCHARGE LINE TO PVNT HAZ BACK FLOW INTO CYL. FOR ADDNL
HNDLG RECS, CONSULT COMPRESSED GAS
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
M.P/F.P Text: SEE INGS
Vapor Pres: SEE INGS
Spec Gravity: SUP DAT
Solubility in Water: NEGLIGIBLE
Appearance and Odor: COLORLESS, ODORLESS GAS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BLUESHIELD 1.2
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: 800-231-1366;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/20/1997
Status Code: C
Label Date: 03/20/1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EFFECTS OF EXPOSURE TO HIGH CONCENTRATIONS SO AS
TO DISPLACE OXYGEN IN AIR NECESSARY FOR LIFE ARE HEADACHE, DIZZINESS, LABORED
BREATHING AND EVENTUAL UNCONSCIOUSNESS. THESE MIXTURES ARE NONTOXI C BUT
LIBERATION OF LARGE AMOUNT IN CONFINED AREA COULD DISPLACE AMOUNT OF OXYGEN
IN AIR NECESSARY TO SUPPORT LIFE. WELDING OR BRAZING MAY PRODUCE FUMES AND
GASES HAZARDOUS TO HEALTH. INHALATION: DIZZ INESS, NAUSEA, DRYNESS,
IRRITATION OF NOSE, THROAT/EYES. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.