IMPERIAL ADHESIVES INC -- 4425T01 PERMAGRIP
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Material Safety Data Sheet
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MSDS Num: CDWSJ
MSDS NAME: 4425T01 PERMAGRIP
Responsible Party
Name: IMPERIAL ADHESIVES INC
Address: 6315 WIEHE RD
City: CINCINNATI OH 45237
Info Phone: 513-351-1300
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: AMP INC
Address: UNKNOWN
Box: 3608
City: HARRISBURG PA 17105-3608
Phone: 717-561-8800
Name: IMPERIAL ADHESIVES INC
Address: 6315 WIEHE RD
City: CINCINNATI OH 45237
Phone: 800-365-1301
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Ingredients
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA). VP:22 @ 68F. EVAP RATE:2 (N-BUTYL
ACETATE=1). SOL IN H*2O:NEGLIGIBLE.
% Wt: 36
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 64742-89-8
Name: VM & P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES). VP:180 @ 68F. EVAP
RATE:8.8 (N-BUTYL ACETATE=1). SOL IN H*2O:NEGLIG.
% Wt: 18
OSHA PEL: 400 PPM (MFR)
ACGIH TLV: 400 PPM (MFR)
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Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). VP:70 @ 68F.
EVAP RATE:5 (N-BUAC=1). SOL IN H*2O:27% @ 68F.
% Wt: 18
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM;300 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 3486-35-9
RTECS #: FG3375000
Name: ZINC CARBONATE (SARA 313) (CERCLA). VP:NEGLIGIBLE. EVAP RATE:NEGLIGIBLE.
SOL IN H*2O:NEGLIGIBLE.
% Wt: 1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 1314-13-2
RTECS #: ZH4810000
Name: ZINC OXIDE (SARA 313) (CERCLA). VP:NEGLIGIBLE. EVAP RATE:NEGLIGIBLE. SOL
IN H*2O:NEGLIGIBLE.
% Wt: 0.2
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
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Name: PHENOLIC RESIN. VP:NEGLIGIBLE. EVAP RATE:NEGLIGIBLE. SOL IN
H*2O:NEGLIGIBLE.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 110-54-3
RTECS #: MN9275000
Name: HEXANE; (N-HEXANE) (CERCLA). VP:NEGLIGIBLE. EVAP RATE:NEGLIGIBLE. SOL IN
H*2O:NEGLIGIBLE.
% Wt: 25-35
OSHA PEL: 500 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Name: FIRE FIGHT PROC:EXPOS TO EXTREME HEAT. AVOID SPREADING BURNING LIQS
W/WATER USED FOR COOLING PURPOSES. FIRE PROT
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Name: ING 8:& RESPONSE STRATEGY SHOULD BE PLANNED THRU CONSULTATION W/LOCAL
FIRE PROTECTION AUTHS/APPROPRIATE SPECIALISTS.
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Name: EFTS OF OVEREXP:UNCON & EVEN DEATH IN CONFINED/POORLY VENTED AREAS.
INGEST:GI IRRIT, HDCH, NAUS, VOMIT, DIARR &
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Name: ING 10:SIGNS OF NERV SYS DEPRESS. ASPIR OF MATL INTO LUNGS DURING
SWALLOWING/VOMIT CAN CAUSE CHEM PNEUM (LUNG
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Name: ING 11:INFLAMM & DMG) WHICH CAN BE FATAL. CHRONIC:ING 1:MAY BE
HARMFUL TO FETUS BASE ON LAB ANIMAL STUDIES.
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Name: ING 12:INTENTIONAL MISUSE BY DELIB INHAL HAS BEEN ASSOC W/LIVER, KIDNEY
& BRAIN DMG IN HUMANS. RPTD EXPOS HAS
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Name: ING 13:BEEN ASSOC W/HIGH FREQUENCY HEARING LOSS IN LAB ANIMALS. RSLTS OF
TEST IN WORKERS HAVE SHOWN THAT EXPOS
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Name: ING 14:TO HIGH CONCS CAN CAUSE IRREVERSIBLE CHANGES IN GENETIC MATL (DNA)
OF A CELL. OVEREXP HAS BEEN FOUND TO
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Name: ING 15:CAUSE LIVER ABNORMS, KIDNEY, NASAL & BRAIN DMG IN LAB ANIMALS.
ING 2:SUGGESTED AS CAUSE OF CNS EFTS IN
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Name: ING 16:HUMANS. ING 7:MAY DMG PERIPHERAL NERVE TISS (THAT OF ARMS &
LEGS); MUSCULAR WEAK & LOSS OF SENSATION IN
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Name: ING 17:EXTREMS. ING 3 MAY POTENTIATE PERIPHERAL NEUROPATHY CAUSED BY ING
7. ING 3:LIVER ABNORMS, KIDNEY, LUNG &
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Name: ING 18:DMG. NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS.
SEEK CONSULTATION FROM APPROP HLTH
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Name: ING 19:PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG
& EXPOS INFO (FP N). FOR MORE INFO CONT NEHC (FP N).
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Name: FIRST AID PROC:CARD ARRYTHS IN PERS EXPOS TO THIS MATL. OTHER DRUGS
W/LESS ARRHYTHMOGENIC POTNTL SHOULD BE
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Name: ING 21:CONSIDERED. IF SYMPATHOMIMETIC DRUGS ARE ADMININSTERED, OBSERVE
FOR DEVELOPMENT OF CARDIAC ARRYTHMIAS.
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Name: ING 22:FOR MORE SPECIFIC INFORMATION REGARDING FIRST AID TREATMENT
CONTACT NEHC (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:EYES:IRRIT. DIRECT CONT W/LIQ OR OVEREXP TO ITS
VAPS/MISTS CAN CAUSE SEV IRRIT, PAIN, BURNING, TEARING, REDNESS, SWELL &
BLURRED VISION. ACCENTUATED IF MATL IS NOT PROMPTLY REMOVED. SKIN:IRRIT.
PRLNG/RPTD CONT - IRRIT, PAIN, BURNING,REDNESS, DEFAT (DRYING,
CRACKING/FLAKING) & DERM (INFLAMM). (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:ACCENTUATED BY LIQ BECOMING
TRAPPED AGAINST SKIN BY CONTAM CLTHG & SHOES. CAN BE ABSORBED IN TOX AMTS
(INCL MUC MEMBS & EYES), ESP FROM PRLNG, RPTD/WIDESPREAD EXPOS.
INHAL:NASAL & RESP IRRIT, HDCH, NAUS, SIGNS OF NERV SYS DEPRESS (LT
HEAD, DIZZ, LOSS OF COORD & EQUILIBRIUM, DROW, WEAK, FATG), POSS
Medical Cond Aggravated By Exposure: PERS W/LUNG, HEART, LIVER & KIDNEY
DISORDERS, DERM, ABNORMAL CNDTNS OF EYES, SKIN, NOSE, THROAT & RESP SYS
MAY BE MORE SUSCEPTIBLE TO EFTS OF THIS MATL. FOR MORE INFORMATION CONTACT
NEHC (FP N).
First Aid: INGEST:CALL MD IMMED (FP N). INHAL:REMOVE TO FRESH AIR. SUPPORT
BRTHG(GIVE O*2/ARTF RESP) (FP N). EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF
15 MINS, SEEK ASSISTANCE FROM MD (FP N). SKIN:FLUSH W/COPI OUS AMTS OF WATER.
CALL MD (FP N). NOTETO MD:EXPOS TO HIGH CONCS(E.G., IN ENCLSD SPACES OR
W/DELIB ABUSE) MAY BE ASSOC W/CARDIAC ARRHYS. EPINEPHRINE & OTHER
SYMPATOMIMETIC DRUGS MAY INITIATE
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Handling and Disposal
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Spill Release Procedures: WEAR APPROP PROT. SM SPILLS:ABSORB ON ABSORB MATL
& TRANSFER TO HOOD. ALLOW TO EVAP. TRANSFER REMAINING MATL TO APPROP
MARKED CNTNR. LG SPILL:ELIM ALL IGNIT SOURCES. STOP SPILL AT SOURCE. DIKE
AREA. F OR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF MATERIAL I/A/W APPLICABLE LOCAL, COUNTY,
STATE & FEDERAL REGULATIONS. AS PRODUCED, THIS MATERIAL IS A PRODUCT
& NOT A WASTE.
Handling And Storage Precautions: HANDLE W/REAS CARE. KEEP CNTNRS COOL, DRY
& AWAY FROM SOURCES OF IGNIT. USE & STORE W/ADEQ VENT. AVOID BRTHG
VAPS & SPRAY MIST. FOR INDUS USE ONLY.
Other Precautions: AVOID EYE & RPTD/PRLNG SKIN CONT. KEEP CNTNRS TIGHTLY
CLSD WHEN NOT IN USE. WHEN OPENING CNTNRS, REMOVE TOP SLOWLY TO RELIEVE PRESS
BUILD-UP. WHEN DISPENSING, FOLLOW ACCEPT STATIC GROUNDING/BONDING PR OCS FOR
FLAMM LIQS. CONT NEHC (FP N).
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: <20F,<-7C
Lower Limits: 1%
Upper Limits: 10%
Extinguishing Media: DRY CHEM, CARBON DIOXIDE, FOAM, WATER SPRAY/FOG &
VAPORIZING LIQ TYPE EXTING AGENTS. WATER MAY BE INEFT EXTING (SUPDAT)
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
WATER MAY BE USED TO KEEP FIRE-EXPOS CNTNRS COOL TO PVNT PRESS BUILD-UP &
POSS AUTO-IGNIT/EXPLO WHEN
Unusual Fire/Explosion Hazard: SOLV IN PROD IS FLAMM & HIGHLY VOLAT. VAPS
OF SOLV ARE HVR/AIR & MAY TRAVEL ALONG GROUND/MAY BE MOVED BY VENT &
IGNITED BY PILOT LIGHTS, ETC. CONT NEHC (FP N).
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Control Measures
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Respiratory Protection: IF TLV OF PROD/ANY COMPONENT IS EXCEEDED/IF PROD IS
USED IN SUCH A MANNER AS TO GENERATE PARTICULATES (FUME, DUST, MIST), NIOSH
APPRVD RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL (SEE YOUR SF TY
EQUIP SUPPLIER). ENGINEERING/(SUPDAT)
Ventilation: GEN MECH VENT MAY BE SUFFICIENT TO KEEP PROT VAP &/OR MIST
CONCS W/IN SPECIFIED TLV RANGES. IF GEN VENT PROVES (SUPDAT)
Protective Gloves: IMPERMEABLE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER(FP
N). WHERE CONT CAN OCCUR, COVERALLS, APRON & RUB FOOT COVERING ARE REC.
Work Hygienic Practices: PRACTICE SAFE WORKING PROCS & GOOD PERSONAL HYGIENE.
WASH THORO AFTER HNDLG & BEFORE EATING, DRINKING, SMOKING/ (SUPDAT)
Supplemental Safety and Health: EXTING MEDIA:AGENTS UNLESS USED UNDER FAVORABLE
CNDTNS. CONT NEHC FOR MORE SPECIFIC INFO (FP N). HAZ DECOMP PROD:UNIDENTIFIED
TOX MATLS. RESP PROT:ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS.
VENT:INADEQ TO MAINTAIN SAFE VAPS &/ORMIST CONCS, SUPP LOC EXHST MAY BE
REQD. HYGIENE PRACT:USING TOILET FACILITIES.
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Physical/Chemical Properties
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B.P. Text: >140F,>60C
Vapor Pres: SEE INGS
Vapor Density: >1
Spec Gravity: 0.886 (H*2O=1)
Evaporation Rate & Reference: SEE INGREDIENTS
Solubility in Water: SEE INGREDIENTS
Appearance and Odor: LIGHT TAN LIQUID.
Percent Volatiles by Volume: 72(WT)
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS, OPEN FLAMES & OTHER IGNITION
SOURCES WHICH INDUCE COMBUSTION &/OR THERMAL DECOMPOSITION.
Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG ACIDS & STRONG ALKALIES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, ACRID
(CHOKING) SMOKE & FUMES, HYDROGEN CHLORIDE, VARIOUS HYDROCARBONS, OTHER
(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 4425T01 PERMAGRIP
Assigned IND: Y
Company: IMPERIAL ADHESIVES INC
Street: 6315 WIEHE RD
City: CINCINNATI OH
Zipcode: 45237
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 07/07/1997
Status Code: C
Label Date: 07/07/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE:EYE:IRRITATION, BURNING, TEARING,
REDNESS, SWELLING AND BLURRED VISION. SKIN:IRRITATION, PAIN, DEFATTING,
BURNING, DERMATITIS. INHALATION:IRRITATION, HEADACHE, NAUSEA, CENTRAL NERVOUS
SYSTEM DEPRESSION, UNCONSCIOUSNESS, DEATH. INGESTION:IRRITATION; HEADACHE,
NAUSEA, VOMITING, DIARRHEA, NERVOUS SYSTEM DEPRESSION. ASPIRATION HAZARD -
FATAL. CHRONIC:LIVER, KIDNEY AND BRAIN DAMAGE, HE ARING LOSS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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