US PAINT CORP -- 8P502, AWLGRIP AWLSTAR ANTI-FOULING GOLD (SUP
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Material Safety Data Sheet
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MSDS Num: CDWHN
MSDS NAME: 8P502, AWLGRIP AWLSTAR ANTI-FOULING GOLD (SUPP DATA)
Responsible Party
Name: US PAINT CORP
Address: 831 SOUTH 21ST ST
City: ST LOUIS MO 63103
Info Phone: 314-621-0525
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
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Contractor Summary
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Name: US PAINT CORP
Address: 831 SOUTH 21ST ST
City: ST LOUIS MO 63103
Phone: 314-621-0525
Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
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Ingredients
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Name: WASTE DISP METH:OXIDE PARTICULATE EXPOS TO MOIST AIR AT >100C CAN RSLT
IN SPONT COMBUST (CNDTNS MAY APPLY WHEN SANDING).
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Name: OTHER PREC:THEY RETAIN PROD RESIDUES (VAP, LIQ &/OR SOLID). ALL HAZ
PRECS GIVEN IN THIS MSDS MUST BE OBSERVED.
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Name: ING 22:PROD MAY BE BLENDED W/OTHER PRODS PRIOR TO USE. READ ALL WARNINGS
& PRECS ON LBLS OF ALL PRODS BEING
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Name: ING 23:BLENDED AS COMBINATIONS MAY CNTN HAZS OF EACH COMPONENT. FOR
INDUSTRIAL USE ONLY BY PROFESSIONAL, TRAINED
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Name: ING 24:PERSONNEL USING PROPER EQUIPMENT. NOT INTENDED FOR SALE TO, OR USE
BY, THE GENERAL PUBLIC.
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Cas: 1317-39-1
Name: CUPROUS OXIDE. MP:2255F,1235C. (CONTAINING ING 7)
% Wt: 44-47
OSHA PEL: 10 MG/M3 (MFR)
ACGIH TLV: 10 MG/M3 (MFR)
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA 313) (CERCLA)
% Wt: 10 MIN
OSHA PEL: 0.1MG/M3 FUME;1 DUST
ACGIH TLV: 0.2 MG/M3 FUME
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 397 G/L - MATERIAL.
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Name: SUPDAT:HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING USE
& UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE
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Name: ING 9:EXPLO & SPREAD LONG DISTS/BEYOND CLSD DOORS. PVNT BUILD UP OF
VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH
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Name: ING 10:AIR. WHEN SANDING CARE SHOULD BE TAKEN DUE TO SPONT COMBUST OF
CUPROUS OXIDE PARTICULATES WHEN EXPOS TO
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Name: ING 11:MOIST AIR AT TEMPERATURE OVER 100C.
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Name: EFTS OF OVEREXP:CAUSE IRRIT TO MUC MEMB; CNS DEPRESS; HEMORR INTO VARIOUS
VITAL ORGS; INJURY TO KIDNEYS, LIVER,
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Name: ING 13:LUNG & CVS; CORNEAL EFTS; COMA; GI IRRIT; NARC EFTS; BLOOD
DISORDERS. WARNING:RPTS HAVE ASSOC RPTD/PRLNG
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Name: ING 14:OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG.
INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY
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Name: ING 15:BE HARMFUL/FATAL. THIS PROD CNTNS A CHEM KNOWN BY STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/REPRO HARM.
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Name: SPILL PROC:UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, CNTN
AREA OF SPILL TO PVNT SPREADING, PUMP
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Name: ING 17:LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE ABSORBED W/INERT MATL
SUCH AS SAND, CLAY, EARTH/FLOOR ABSORB &
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Name: ING 18:SHOVELED INTO CNTNRS W/NON-SPARKING TOOLS. PVNT RUN-OFF TO SEWERS,
STREAMS/OTHER BODIES OF WATER. IF
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Name: ING 19:RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED THAT A SPILL
HAS OCCURRED.
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE; (METHYL BENZENE) (SARA 313) (CERCLA). VP:15 @ 20C.
LD50:(ORAL,RAT) 4.3 G/KG.
% Wt: 8
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM;150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 71-36-3
RTECS #: EO1400000
Name: BUTYL ALCOHOL; (1-BUTANOL) (SARA 313) (CERCLA). VP:10 @ 20C.
LD50:(ORAL,RAT) 2.5 G/KG.
% Wt: 11
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM, S, C
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313). VP:5 @ 20C.
% Wt: 1
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM;125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 1314-13-2
RTECS #: ZH4810000
Name: ZINC OXIDE (SARA 313) (CERCLA)
% Wt: 13
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 2
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING &
BLURRED VISION, PAIN & INFLAMM OF TISS. SKIN:CAN CAUSE MOD IRRIT, DEFAT
& DERM. SOLVS CAN PENETRATE CAUSING EFTS AS IN ACUTE INHAL. ING 7:IRRIT
(OXID E POX). INHAL:CAN CAUSE NASAL & RESP IRRIT, CONGESTION, DIZZ, WEAK,
CHILLS, FEVER, FATG, MUSCLE ACHES, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:NAUS, HDCH, POSS UNCON, TIGHTNESS
IN CHEST, FLU-LIKE SYMPS CALLED "METAL-FUME FEVER" & EVEN ASPHY.
INGEST:HARMFUL & CAN CAUSE BURNING SENSATION, SORE THROAT, ABDOM PAIN,
NAUS, VOMIT & DIARR. CHRONIC:PRLNG & RPTD BRTHG OF SPRAY MIST
&/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF LUNGS. CAN
Medical Cond Aggravated By Exposure: PRE-EXISTING LUNG DISEASES MAY BE
AGGRAVATED BY EXPOSURE; MAY RESULT IN RESPIRATORY DISEASE IF OVEREXPOSED ON A
CHRONIC BASIS.
First Aid: INGEST:DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY (FP N).
INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N).
EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK
ASSISTANCE FROM MD (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP
N). FOR MORE SPECIFIC INFORMATION REGARDING FIRST AID TREATMENT CONTACT NEHC
(FP N).
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Handling and Disposal
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Spill Release Procedures: SM SPILL:ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT
SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT
EQUI P SHOULD BE EXCLUDED FROM AREA OF SPILL
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: ALLOW VOLAT PORTION TO EVAP IN HOOD BEING SURE TO ALLOW
SUFFICIENT TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT WORK. DISP OF CONTAM
ABSORB, CNTNR & UNUSED CONTENTS I/A/W LOC, STATE & FED REGS. DO NOT
INCIN CLSD CNTNRS. LG MASSES OF CUPROUS
Handling And Storage Precautions: CARE SHOULD BE TAKEN WHEN SANDING PIGMENTED
PAINTS. USE ONLY W/ADEQ VENT. DO NOT BREATHE VAPS, SPRAY MISTS/SANDING DUSTS.
DO NOT STORE >120F.
Other Precautions: DO NOT GET IN EYES, ON SKIN/ON CLTHG. KEEP CLOSURE TIGHT
& UPRIGHT TO PVNT LEAKAGE. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT
TRANSFER CONTENTS TO BOTTLES/OTHER UNLABELED CNTNRS. CNTNRS OF THIS MATL MAY
BE HAZ WHEN EMPTIED BECAUSE
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point Text: 82.0F,27.8C
Lower Limits: 1.1%
Upper Limits: 11.2%
Extinguishing Media: IN CASE OF FIRE, USE CO*2, DRY CHEMICAL, FOAM OR OTHER
APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX GASES & SMOKE ARE
IRRITS PRESENT FROM DECOMP/COMBUST.(SUPDAT)
Unusual Fire/Explosion Hazard: FLAMM. VAPS MAY CAUSE FLASH FIRE.
SENSITIVITY/STATIC DISCHARGE-GROUNDING/BONDING REQD. KEEP AWAY FROM HEAT,
SPKS & FLAME. DO NOT SMOKE. EXTING ALL PILOT(SUPDAT)
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Control Measures
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Respiratory Protection: WEAR APPROP, PROPERLY FITTED NIOSH APPRVD RESP DURING
& AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAP, MIST &
PARTICULATE LEVELS ARE BELOW APPLIC LIMS. FOLLOW RESP MFR'S DIRECTIONS FOR
RESP USE. ENGINEERING/ADMIN CONTROLS(SUPDAT)
Ventilation: MAINTAIN CONTINUOUS FLOW OF FRESH AIR. PROVIDE SUFFICIENT MECH
(GEN &/OR LOC EXHST) VENT TO MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). SOLV IMPERMEABLE CLTHG & BOOTS ARE REC TO PREVENT SKIN CONTACT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MFR'S TRADE NAME/PART #:LABEL-DEEP BLUE. FIRE
FIGHT PROC:CLSD CNTNR MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. HAZ DECOMP
PROD:MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN. WHEN HEATED TO DECOMP
EMITS T OX FUMES. RESP PROT:SHOULD BE IMPLEMENTED TO REDUCE EXPOS. EXPLO
HAZ:LIGHTS & TURN OFF ALL SOURCES OF IGNIT, INCL
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Physical/Chemical Properties
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B.P. Text: >241F,>116C
M.P/F.P Text: SEE ING 6
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 1.96
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: VISCOUS LIQUID W/SOLVENT ODOR.
Percent Volatiles by Volume: 47
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXCESS HEAT.
Materials To Avoid: OXIDIZING MATLS; STRONG REACTANTS SUCH AS ACIDS, BASES &
METALS (ALUMINUM, MAGNESIUM). PERMANGANATE, CHROMIUM TRIOXIDE.
Hazardous Decomposition Products: COPPER FUMES WILL BE RELS IF CUPROUS OXIDE IS
TREATED >2255F (MELTING POINT). DECOMPOSES INTO FUMES CNTNG CARBON(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 8P502, AWLGRIP AWLSTAR ANTI-FOULING GOLD (SUPP DATA)
Assigned IND: Y
Company: US PAINT CORP
Street: 831 SOUTH 21ST ST
City: ST LOUIS MO
Zipcode: 63103
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 06/24/1997
Status Code: C
Label Date: 06/24/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM LIQUID. ACUTE:EYES:CAN CAUSE SEV IRRIT, REDNESS,
TEARING & BLURRED VISION, PAIN & INFLAMM OF TISS. SKIN:CAN CAUSE MOD
IRRIT, DEFAT & DERM. SOLVS CAN PENETRATE CAUSING EFTS AS IN ACUTE INHAL.
INH AL:CAN CAUSE NASAL & RESP IRRIT, CONGESTION, DIZZ, WEAK, CHILLS,
FEVER, FATG, MUSCLE ACHES, NAUS, HDCH, UNCON & ASPHY. INHAL OF FUMES MAY
CAUSE "METAL FUME FEVER". INGEST:HARMFUL. CAN CAUSE BURNING SE NSATION, SORE
THROAT, ABDOM PAIN, NAUS, VOMIT & DIARR. CHRONIC:PRLNG BRTHG OF SANDING
DUST MAY CAUSE DUST DISEASE OF LUNGS. MAY CAUSE INJURY TO KIDNEYS, LIVER,
LUNGS & CVS. MAY CAUSE BLOOD DISORDERS. SOLV OVEREXP CAN CAUSE PERM
BRAIN & NERV SYS DMG.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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