UNOCAL PETROLEUM PRODUCTS & CH -- HEXANE, 11487
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Material Safety Data Sheet
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MSDS Num: CDZPP
MSDS NAME: HEXANE, 11487
Responsible Party
Name: UNOCAL PETROLEUM PRODUCTS & CHEMICALS
Address: 1701 GOLF ROAD SUITE 1-1101
City: ROLLING MEADOWS IL 60008-4295
Info Phone: 800-967-7601
Emergency Phone Number: 800-967-7601
Published: Y
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Contractor Summary
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Name: 76 PRODUCTS CO
Address: 1201 W 5TH ST
City: LOS ANGELES CA 90017
Phone: 213-977-7589
Name: UNOCAL 76,HYDROCARBON SALES,UNION OIL COMPANY OF CALIFORNIA
Address: 1701 GOLF ROAD SUITE 1-1101
City: ROLLING MEADOWS IL 60008-4295
Phone: 800-967-7601
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Ingredients
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Name: HEXANE ISOMERS (OTHER THAN N-HEXANE); (OTHER HEXANE ISOMERS)
OSHA PEL: 1000 PPM (MFR)
ACGIH TLV: 500 PPM (MFR)
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Cas: 110-54-3
RTECS #: MN9275000
Name: HEXANE; (N-HEXANE) (CERCLA)
OSHA PEL: 500 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA 313) (CERCLA)
OSHA PEL: SEE 1910.1028
ACGIH TLV: 10 PPM
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA)
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 100%; 674 G/L.
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Name: EXPLO HAZ:IGNITE, FLASHBACK/EXPLODE. MAY CREATE VAP/AIR EXPLO HAZ
INDOORS, OUTDOORS/IN SEWERS. VAPS ARE HVR/AIR &
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Name: ING 6:CAN ACCUMULATE IN LOW AREAS. CONTAINER CAN EXPLODE IN HEAT OF FIRE.
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Name: EFTS OF OVEREXP:OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG.
EXCESSIVE EXPOS TO N-HEXANE CAN RSLT IN PERIPHERAL
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Name: ING 8:NEUROPATHIES. INITIAL SYMPS ARE SYMMETRICAL SENSORY NUMB &
PARESTHESIAS OF DISTAL PORTIONS OF EXTREMS.
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Name: ING 9:MOTOR WEAK IS OBSERVED IN MUSCLES OF TOES & FINGERS BUT MAY
ALSO INVOLVE MUSCLES OF ARMS, THIGHS &
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Name: ING 10:FOREARMS. ONSET OF SYMPS MAY BE DELAYED FOR SEVERAL MONTHS TO YR
AFTER BEGINNING OF EXPOS. NOTE:TOLUENE
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Name: ING 11:APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION
FROM APPROP HLTH PROFESSIONALS
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Name: ING 12:CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO
(FP N). FOR MORE SPECIFIC INFO CONT NEHC (FP N).
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Name: FIRST AID PROC:BY QUALIFED PERS. SEEK IMMED MED ATTN. INGEST:ASPIR HAZ:DO
NOT INDUCE VOMIT/GIVE ANYTHING BY
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Name: ING 14:MOUTH BECAUSE MATL CAN ENTER LUNGS & CAUSE SEV LUNG DMG. IF
VICTIM IS DROWSY/UNCON, PLACE ON LEFT SIDE W/
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Name: ING 15:HEAD DOWN. DO NOT LEAVE VICTIM UNATTENDED. SEEK MED ATTN. NOTE TO
MDS:EXPOS TO HIGH CONCS OF MATL MAY BE
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Name: ING 16:ASSOC W/CARD ARRHYS. EPINEPHRINE & OTHER SYMPATHOMIMETIC DRUGS
MAY INITIATE CARD ARRHYS IN PERS EXPOS TO
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Name: ING 17:MATERIAL. OTHER DRUGS W/LESS ARRHYTHMOGENIC POTENTIAL SHOULD BE
CONSIDERED.
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Name: SPILL PROC:STORM DRAINS, DRAINAGE SYS & NATRL WATERWAYS. DIKE. USE
FOAM TO MIN VAPS. SPILLED MATL MAY BE
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Name: ING 19:ABSORBED INTO APPROPRIATE ABSORBENT MATERIAL. FOR MORE SPECIFIC
INFORMATION CONTACT NEHC (FP N).
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Name: OTHER PREC:DMG. OUTDOOR/DETACHED STOR PREF. "EMPTY" CNTNRS RETAIN RESIDUE
& MAY BE DANGEROUS. DO NOT PRESSURIZE,
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Name: ING 21:CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CNTNRS TO HEAT,
FLAME, SPKS/OTHER SOURCES OF IGNIT.
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Name: ING 22:THEY MAY EXPLODE & CAUSE INJURY/DEATH. "EMPTY" DRUMS SHOULD BE
COMPLETELY DRAINED, PROPERLY BUNGED &
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Name: ING 23:PROMPTLY SHIPPED TO SUPPLIER/DRUM RECNDTNR. ALL OTHER CNTNRS
SHOULD BE DISP OF IN AN ENVIRON SAFE MANNER
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Name: ING 24:& I/A/W GOVERNMENTAL REGULATIONS. FOR MORE SPECIFIC
INFORMATION CONTACT NEHC (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: ACUTE:EYE:CONT MAY CAUSE MILD IRRIT, STINGING, WATERING
& REDNESS. SKIN:CONT MAY CAUSE MILD IRRIT, REDNESS, BURNING, DRYING &
CRACKING. NO HARMFUL EFTS FROM ABSORPTION REPORTED. INHAL:LOW DEGREE OF TO X.
INGEST:LOW DEGREE OF TOX. ASPIR HAZ-THIS MATL CAN ENTER LUNGS DURING
SWALLOWING/VOMIT & CAUSE LUNG (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: BENZENE:IARC MONO, SUPP, VOL 7, PG 120,
1987:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. (SUPP
DATA)
Signs And Symptions Of Overexposure: HLTH HAZ:INFLAMM & DMG. EFTS OF
OVEREXP MAY INCL IRRIT OF NOSE & THROAT, IRRIT OF DIGEST TRACT, NAUS,
SIGNS OF NERV SYS DEPRESS, HDCH, DROW, DIZZ, LOSS OF COORD & FATG, GIDD
& LOSS OF APPETITE. INTENT IONAL MISUSE BY DELIB CONC & INHAL MATLMAY
BE HARMFUL/FATAL. CHRONIC:REPORTS HAVE ASSOC RPTD & PRLNG OCCUP
Medical Cond Aggravated By Exposure: MAY INCL SKIN DISORDERS, RESP
(ASTHMA-LIKE) DISORDERS & PERIPHERAL NERVE DISORDERS. HIGH CONCS MAY
CAUSE IRREG HEARTBEATS. PERS W/PRE-EXISTING HEART DISORDERS MAY BE MORE
SUSCEPTIBLE TO THIS EFT.
First Aid: EYE:MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH W/CLEAN WATER
FOR AT LST 15 MINS. IF SYMPS PERSIST, SEEK MED ATTN. SKIN:REMOVE CONTAM SHOES
& CLTHG & CLEANSE AFFECTED AREA(S) BY WASHING W/SOAP & WATE R. IF
IRRIT/REDNESS DEVELS & PERSISTS, SEEK MED ATTN. INHAL:MOVE INTO FRESH
AIR. IF SYMPS PERSIST, SEEK MED ATTN. IF NOT BRTHG, BEGIN ARTF RESP. IF BRTHG
DFCLTIES DEVEL, OXYG SHOULD BE ADMIN
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Handling and Disposal
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Spill Release Procedures: KEEP ALL SOURCES OF IGNIT & HOT METAL SURFS AWAY
FROM SPILL/RELS. USE NON-SPARKING TOOLS & EXPLO-PROOF EQUIP. STAY UPWIND.
ISOLATE DANGER AREA. STOP SPILL/RELS IF CAN W/MIN RISK. WEAR APPROP PROT EQUI
P. PVNT SPILLED MATL FROM ENTERING SEWERS,
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: EPA HAZ WASTE #'S D001 & D018. STATE & LOC
REQUIREMENTS FOR WASTE DISP MAY BE MORE RESTRICTIVE/OTHERWISE DIFF FROM FED
REGS. CONSULT STATE & LOC REGS REGARDING PROPER DISP OF MATL. FOR MORE
SPECIFIC I NFORMATION CONTACT NEHC (FP N).
Handling And Storage Precautions: OPEN CNTNR SLOWLY TO RELIEVE ANY PRESSURE.
BOND & GROUND ALL EQUIPMENT WHEN TRANSFERRING FROM ONE VESSEL TO ANOTHER.
KEEP CNTNRS TIGHTLY CLOSED.
Other Precautions: USE & STORE IN COOL, DRY, WELL-VENTED AREAS AWAY FROM
HEAT, DIRECT SUNLIGHT, HOT METAL SURFS & ALL SOURCES OF IGNIT. POST AREA
"NO SMOKING/OPEN FLAME". STORE ONLY IN APPRVD CNTNRS. KEEP AWAY FROM INCO
MPAT MATL. PROT AGAINST PHYSICAL
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point Text: -20F,-29C
Lower Limits: 1%
Upper Limits: 8%
Extinguishing Media: DRY CHEM, CARBON DIOXIDE, HALON/FOAM. WATER SPRAY IS REC
TO COOL/PROT EXPOS MATLS/STRUCTURES. USE CAUT WHEN (SUPP DATA)
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP(FP N).
COOL EQUIP EXPOS TO FIRE W/WATER. AVOID SPREADING BURNING LIQ W/WATER USED
FOR COOLING PURPOSES. FOR MORE(SUPDAT)
Unusual Fire/Explosion Hazard: EXTREMELY FLAMM & CAN BE IGNITED BY HEAT,
SPKS, FLAMES/OTHER SOURCES OF IGNIT. VAPS MAY TRAVEL CONSIDERABLE DISTS TO
SOURCE OF IGNIT WHERE THEY CAN
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Control Measures
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Respiratory Protection: RESPIRATORY PROTECTION IS ADVISED WHEN CONCENTRATIONS
ARE EXPECTED TO EXCEED ESTABLISHED EXPOSURE LIMITS. USE NIOSH APPROVED
RESPIRATOR OR GAS MASK W/APPROPRIATE CARTRIDGES & CANNISTERS OR
SUPPLIED-AI R EQUIPMENT.
Ventilation: VENT ADEQ TO MAINTAIN AIRBORNE CONCS BELOW ESTABLISHED EXPOS LIMS.
WHERE EXPLO MIXTS MAY BE PRESENT, ELEC SYS (SUPDAT)
Protective Gloves: IMPERMEABLE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. DO NOT WEAR
CONTAMINATED CLOTHING OR SHOES. USE GOOD PERSONAL HYGIENE PRACTICE.
Supplemental Safety and Health: EXTING MEDIA:APPLYING HALON/CARBON DIOXIDE IN
CONFINED SPACES. FOR MORE SPECIFIC INFO CONT NEHC (FP N). FIRE FIGHT
PROC:SPECIFIC INFO CONT NEHC (FP N). EXPLAN OF CARCIN:OSHA REGULATED:29 CFR
1910.1028 . HUMAN:MYELOID LEUKEMIA, HODGKINS DISEASE, LYMPHOMA. VENT:SAFE FOR
SUCH LOCATIONS MUST BE USED.
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Physical/Chemical Properties
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B.P. Text: >150F,>66C
Vapor Pres: 140
Vapor Density: 3
Spec Gravity: 0.674
Evaporation Rate & Reference: 8.1 (N-BUTYL ACETATE=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: WATER-WHITE LIQUID; LIGHT HYDROCARBON ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID ALL POSSIBLE SOURCES OF IGNITION.
Materials To Avoid: AVOID CONTACT W/STRONG OXIDIZING AGENTS & REDUCING AGENTS.
Hazardous Decomposition Products: COMBUSTION CAN YIELD CAROBN DIOXIDE & CARBON
MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: HEXANE, 11487
Assigned IND: Y
Company: UNOCAL 76,HYDROCARBON SALES,UNION OIL COMPANY OF CALIFORNIA
Street: 1701 GOLF ROAD SUITE 1-1101
City: ROLLING MEADOWS IL
Zipcode: 60008-4295
Health Emergency Phone: 800-967-7601
Label Required IND: Y
Date Of Label Review: 07/10/1997
Status Code: C
Label Date: 07/10/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE:EYE:CONTACT MAY CAUSE MILD IRRITATION,
STINGING, WATERING & REDNESS. SKIN:CONTACT MAY CAUSE MILD IRRITATION,
REDNESS, BURNING, DRYING & CRACKING. INHAL:LOW DEGREE OF TOXICITY.
INGEST: LOW DEGREE OF TOXICITY. ASPIR HAZ-THIS MATL CAN ENTER LUNGS DURING
SWALLOWING/VOMIT & CAUSE LUNG INFLAMM & DMG. EFTS OF EXPOS MAY INCL
IRRIT OF NOSE & THROAT, IRRIT OF GI TRACT, NAUS, CNS DEPRESS, HDC H,
DROW, DIZZ & FATG. CHRONIC:CANCER HAZ. CONTAINS BENZENE WHICH IS LISTED
AS AHUMAN BLOOD CARCIN (FP N). REPORTS HAVE ASSOC RPTD EXPOS W/PERM BRAIN
& NERV SYS DMG. TOLUENE APPEARS ON THE NAVY OCCUPAT IONAL CHEMICAL
REPRODUCTIVE HAZARDS LIST (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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