| MSDS | : | A-189 | | CAS | : | 4420-74-0
2530-87-2
33580-59-5
67-56-1
7783-06-4
108-88-3 | | NAME | : | ing 10:tiss destruction. eye:liq causes irrit, stinging, excess blinking
ing 11:california prop 65:prod contains toluene which the st of ca has
ing 12:other reprod harm. shown to be nephrotoxic in rabbits by 24-hr
ing 13:& @ 4.0ml/kg there was necrotizing cystitis of urinary
ing 14:mercaptopropyltrimethoxysilane & chloropropyltrimethoxysilane.
ing 15:chloropropyltrimethoxysilane, rats were expos to 0, 10, 50, 100
ing 16:4 wks. findings incl adrenal cortical hypertrophy (100 & 200
first aid proc:note to phys:moderately toxic by swallowing & by
ing 18:brief expos, but sustained occluded cont of many hrs may cause
ing 19:intravenous admin of ethanol (10 ml per hr) allows it to be
ing 20:of methanol metabolites. acidosis must be treated by means of
ing 21:elimination may be increased by hemodialysis, as indicated. for
vent:workplace air; a vent scrubber should be used to minimize odors.
propanethiol, trimethoxysilyl-; (1-propanethiol,
3-chloropropyltrimethoxysilane; (gamma-chloropropyltri-methoxysilane)
ether, methyl(3-(trimethoxysilyl) propyl);
related silane esters
methyl alcohol (methanol) (sara 313) (cercla)
hydrogen sulfide (sara 302/313) (cercla)
toluene (sara 313) (cercla)
volatile organic compound:999.86 g/liter & 999.86 g/liter voc's (less
supdat:cause dizziness, drowsiness, disturbance of vision, &
ing 9:& forearms. skin:prolonged contact may cause severe irritation,
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UNION CARBIDE CHEMICAL & PLAST -- A-189
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CDZJV
MSDS NAME: A-189
Responsible Party
Name: UNION CARBIDE CHEMICAL & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Info Phone: 304-744-3487
Emergency Phone Number: 800-822-4357
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: UNION CARBIDE CHEM & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Phone: 203-794-6753/304-744-3487
Name: UNION CARBIDE CORP
Address: 39 OLD RIDGEBURY ROAD
City: DANBURY CT 06817-0001
Phone: 800-822-4357/732-563-5522 (MSDS)
=======================================================
Ingredients
=======================================================
Name: ING 10:TISS DESTRUCTION. EYE:LIQ CAUSES IRRIT, STINGING, EXCESS BLINKING
AND TEAR PRODUCTION, W/EXCESS REDNESS.
-----------------------------
Name: ING 11:CALIFORNIA PROP 65:PROD CONTAINS TOLUENE WHICH THE ST OF CA HAS
FOUND TO CAUSE CANCER, BIRTH DEFECTS OR
-----------------------------
Name: ING 12:OTHER REPROD HARM. SHOWN TO BE NEPHROTOXIC IN RABBITS BY 24-HR
OCCLUDED CONT @ DOSES OF 2.0ML/KG & ABOVE,
-----------------------------
Name: ING 13:& @ 4.0ML/KG THERE WAS NECROTIZING CYSTITIS OF URINARY
BLADDER. NEPHROTOXIC EFFECTS IS DUE TO BOTH
-----------------------------
Name: ING 14:MERCAPTOPROPYLTRIMETHOXYSILANE & CHLOROPROPYLTRIMETHOXYSILANE.
IN REPEATED VAPOR EXPOSURE STUDY WITH
-----------------------------
Name: ING 15:CHLOROPROPYLTRIMETHOXYSILANE, RATS WERE EXPOS TO 0, 10, 50, 100
& 200 PPM FOR 6 HRS/DAY, 5 DAYS A WK FOR
-----------------------------
Name: ING 16:4 WKS. FINDINGS INCL ADRENAL CORTICAL HYPERTROPHY (100 & 200
PPM). FOR MORE SPECIFIC INFO CONT NEHC (FP N).
-----------------------------
Name: FIRST AID PROC:NOTE TO PHYS:MODERATELY TOXIC BY SWALLOWING & BY
ABSORP ACROSS THE SKIN. LOW SKIN IRRITANCY BY
-----------------------------
Name: ING 18:BRIEF EXPOS, BUT SUSTAINED OCCLUDED CONT OF MANY HRS MAY CAUSE
MARKED INFLAMMATORY EFTS. THERAPEUTIC
-----------------------------
Name: ING 19:INTRAVENOUS ADMIN OF ETHANOL (10 ML PER HR) ALLOWS IT TO BE
PREFERENTIALLY OXIDIZED & REDUCES PRODUCTION
-----------------------------
Name: ING 20:OF METHANOL METABOLITES. ACIDOSIS MUST BE TREATED BY MEANS OF
INTRAVENOUS SODIUM BICARBONATE & METHANOL
-----------------------------
Name: ING 21:ELIMINATION MAY BE INCREASED BY HEMODIALYSIS, AS INDICATED. FOR
MORE SPECIFIC NOTE TO PHYS INFO CONT NEHC (FP N).
-----------------------------
Name: VENT:WORKPLACE AIR; A VENT SCRUBBER SHOULD BE USED TO MINIMIZE ODORS.
-----------------------------
Cas: 4420-74-0
RTECS #: TZ7800000
Name: PROPANETHIOL, TRIMETHOXYSILYL-; (1-PROPANETHIOL,
(3-MERCAPTORPROPYL)TRIMETHOXYSILANE)
% Wt: >85
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 2530-87-2
Name: 3-CHLOROPROPYLTRIMETHOXYSILANE; (GAMMA-CHLOROPROPYLTRI-METHOXYSILANE)
% Wt: <15
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 33580-59-5
RTECS #: KO2290000
Name: ETHER, METHYL(3-(TRIMETHOXYSILYL) PROPYL);
(METHOXYPROPYLTRIMETHOXY-SILANE)
% Wt: <2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: RELATED SILANE ESTERS
% Wt: <2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 67-56-1
RTECS #: PC1400000
Name: METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
% Wt: <1
OSHA PEL: S, 200 PPM
ACGIH TLV: S, 200 PPM/250 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 7783-06-4
RTECS #: MX1225000
Name: HYDROGEN SULFIDE (SARA 302/313) (CERCLA)
% Wt: 0.003
OSHA PEL: C, 20 PPM
ACGIH TLV: 10 PPM/15 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA)
OSHA PEL: 200 PPM; Z-2
ACGIH TLV: S, 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND:999.86 G/LITER & 999.86 G/LITER VOC'S (LESS
WATER & EXEMPT COMPOUNDS)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT:CAUSE DIZZINESS, DROWSINESS, DISTURBANCE OF VISION, &
TINGLING, NUMBNESS, & SHOOTING PAINS IN HANDS
-----------------------------
Name: ING 9:& FOREARMS. SKIN:PROLONGED CONTACT MAY CAUSE SEVERE IRRITATION,
LOCAL REDNESS & SWELLING, & POSSIBLE
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD
HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST
HAZARD LIST INFO & SAFE HNDLG & EXPOS INFO (FP N). ACUTE:INGEST:MAY
CAU SE SLIGHT DISCOMFORT IN MOUTH & THROAT & MILD ABDOM DISCOMFORT.
THIS PROD HYDROLYZES IN STOM TO FORM (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:METHANOL. EFTS OF METHANOL INCL
NAUS, ABDOM PAIN, VOMIT, HDCH, DIZZ, SHORTNESS OF BREATH, WEAK, FATG, LEG
CRAMPS, RESTLESSNESS, CONFUSN, DRUNKEN BEHAVIOR, VISUAL DISTURB, DROW, COMA,
& DEATH. VISUAL EFTS INCL BLURRED VISION, RESTRICTION OF VISUAL FIELDS,
& COMPLETE BLINDNESS. ONSET OF SYMPS MAY BE (SUPDAT)
Medical Cond Aggravated By Exposure: MAY AGGRAVATE AN EXISTING LIVER OR KIDNEY
DISEASE.
First Aid: INGEST:IF PATIENT IS FULLY CONSCIOUS, GIVE 2 GLASSES OF WATER.
INDUCE VOMIT. OBTAIN MED ATTN W/OUT DELAY. IF MED ADVICE IS DELAYED, GIVE 3-4
OUNCES OF HARD LIQUOR, SUCH AS WHISKEY. SKIN:REMOVE CONTAMD CLTHG. WASH
W/SOAP & WATER. OBTAIN MEDATTN. INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP
IF NOT BRTHG. OBTAIN MED ATTN. EYES:IMMED FLUSH W/WATER & CONTINUE FOR @
LST 15 MINS. OBTAIN MED ATTN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WEAR SUITABLE PROTECTIVE EQUIPMENT. COLLECT FOR
DISPOSAL. AVOID RUNOFF TO SEWERS OR WATERWAYS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE IN A FURNACE WHERE PERMITTED UNDER FEDERAL,
STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: DANGER!! HARMFUL OR FATAL IF SWALLOWED.
COMBUSTIBLE. MAY CAUSE DIZZ, DROW, HEART MUSCLE DMG & LIVER & KIDNEY
INJURY. KEEP AWAY FROM HEAT AND FLAME.
Other Precautions: TOXIC TO AQUATIC LIFE. AVOID DISCHARGE TO SEWERS/NATURAL
WATERS. ANY PROPOSED USE OF THIS PROD IN ELEVATED-TEMP PROCESSES SHOULD BE
THOROUGHLY EVALUATED TO ASSURE THAT SAFE OPERATING CNDTNS ARE ESTABL ISHED
AND MAINTAINED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 190F,88C
Extinguishing Media: APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAM FOR LARGE
FIRES. USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). USE REMOTE SPRAY MONITORS OR FIGHT FIRE FROM BEHIND
BARRIERS.
Unusual Fire/Explosion Hazard: REACTION WITH WATER OR OTHER AQUEOUS MEDIA IS
RAPID AND EXOTHERMIC.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE EXPECTED TO BE NEEDED. NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: STORED & HNDLD IN CLSD EQUIP. SPEC, LOC VENT IS NEEDED AT
POINTS WHERE VAPORS CAN BE EXPECTED TO ESCAPE TO
Protective Gloves: NEOPRENE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
CHEMICAL APRON.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: EFTS OF OVEREXP:DELAYED UP TO 48 HRS. 60-200 ML
OF METHANOL CAN BE FATAL. INGEST OF AS LITTLE AS 10 ML HAS CAUSED BLNDNESS.
KIDNEY INJURY MAY OCCUR. HEART MUSCLE & LIVER DMG MAY BE PRESENT. SKIN
ABSOR P:PRLNGD/WIDESPREAD CONT MAY RSLT IN ABSORP OF POTNTLY HARMFUL AMTS OF
MATL. KIDNEY DMG MAY OCCUR. INHAL:MAY
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 414F,212C
M.P/F.P Text: <32F,<0C
Vapor Pres: <1 @ 20C
Vapor Density: 6.8
Spec Gravity: 1.05 (H*2O=1)
Solubility in Water: REACTS RAPIDLY
Appearance and Odor: TRANSPARENT COLORLESS LIQUID, MERCAPTO-ESTER ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: RXN W/WATER/OTHER AQUEOUS MEDIA IS RAPID & EXOTHERMIC. IF
WATER SOLN IS DESIRED, ADD PROD TO WATER, & NOT VICE VERSA.
Hazardous Decomposition Products: OXIDES OF CARBON, SULFUR, AND SILICON.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
=======================================================
MSDS NAME: A-189
Assigned IND: Y
Company: UNION CARBIDE CHEM & PLASTICS CO INC
Street: 39 OLD RIDGEBURY RD
City: DANBURY CT
Zipcode: 06817-0001
Health Emergency Phone: 800-822-4357
Label Required IND: Y
Date Of Label Review: 06/27/1997
Status Code: C
Label Date: 06/27/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INGEST:MAY CAUSE SLIGHT DISCOMFORT IN MOUTH &
THROAT & MILD ABDOMINAL DISCOMFORT. THIS PRODUCT HYDROLYZES IN STOMACH TO
FORM METHANOL WHICH CAN CAUSE NAUSEA, VOMITING, HEADACHE, DIZZINESS, WEAKN
ESS, VISUAL DISTURBANCES, COMA AND DEATH. SKIN CONT:MAY CAUSE SEVERE
IRRITATION, REDNESS AND SWELLING. CAN BE ABSORBED CAUSING KIDNEY DAMAGE. EYE
CONT:CAUSES IRRITATION, STINGING, REDNESS AND TEARING. CHRONIC:TOLUENE
APPEARS ON NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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