UNION CARBIDE CHEMICALS & PLAS -- ANHYDROL SOLVENT SPECIAL, PM-4081, 190 PROOF
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Material Safety Data Sheet
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MSDS Num: CDZLL
MSDS NAME: ANHYDROL SOLVENT SPECIAL, PM-4081, 190 PROOF
Responsible Party
Name: UNION CARBIDE CHEMICALS & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Info Phone: 800-822-4357
Emergency Phone Number: 800-822-4357
Published: Y
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Contractor Summary
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Name: UNION CARBIDE CHEM & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Phone: 203-794-6753/304-744-3487
Name: UNION CARBIDE CORP LINDE DIV
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Phone: 800-822-4357; 304-744-3487
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Ingredients
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Name: FIRST AID PROC:NOTES TO PHYS:THERAPEUTIC INTRAVENOUS ADMIN OF ETHANOL (10
ML PER HR). ACIDOSIS MUST BE
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Name: ING 14:TREATED BY MEANS OF INTRAVENOUS SODIUM BICARBONATE, & METHANOL
ELIM MAY BE INCR BY HEMODIALYSIS, AS
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Name: ING 15:INDICATED. TREATMENT SHOULD BE BASED ON BLOOD METHANOL LEVELS AND
ACID-BASE BALANCE. THE UNABSORBED
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Name: ING 16:ETHANOL SHOULD BE REMOVED BY GASTRIC LAVAGE AFTER INTUBING PATIENT
TO AVOID ASPIR. AVOID USE OF
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Name: ING 17:DEPRESSANT DRUGS/EXCESS ADMIN OF FLUIDS. IN PRESENCE OF
HYPOGLYCEMIA, ADMIN 5%-10% GLUCOSE INTRAVENOUSLY,
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Name: ING 18:PLUS THIAMINE 100 MG INTRAMUSCULARLY. HEMODIALYSIS IS INDICATED IF
THE BLOOD ETHANOL IS ABOVE 5 MG/ML.
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Name: ING 19:FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N) OR POISON
CONTROL CENTER.
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Name: OTHER PREC:CNDTNS. ANY USE OF PRODUCT MAY BE IGNITED BY STATIC SPARKS.
USE PROPER BONDING AND GROUNDING DURING
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Name: ING 21:LIQUID TRANSFER.
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Name: ING 23:VENT:WORKPLACE AIR.
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Cas: 64-17-5
RTECS #: KQ6300000
Name: ETHYL ALCOHOL; (ETHANOL). LEL:3.3%. UEL:19.0%
% Wt: 79.6
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
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Cas: 67-56-1
RTECS #: PC1400000
Name: METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
% Wt: 4.2
OSHA PEL: S, 200 PPM
ACGIH TLV: S, 200 PPM/250 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 108-10-1
RTECS #: SA9275000
Name: 2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA)
% Wt: 0.9
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM/75 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 6.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL (SARA 313)
% Wt: 8.8
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500 STEL
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Cas: 75-07-0
RTECS #: AB1925000
Name: ACETALDEHYDE (SARA 313) (CERCLA)
% Wt: TRACE
OSHA PEL: 200 PPM
ACGIH TLV: C 25PPM, A3
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 775.36 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: SUPDAT:EUPHORIA, ABDOM DISCOMFORT, NAUS, VOMIT, STAGG GAIT, LACK OF
COORDINATION, & COMA. MILD REDNESS & SWELL
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Name: ING 8:OF THE CONJUNCTIVA, SUPERFICIAL INJURY TO CORNEA. CHRONIC:NAUS,
VOMIT, HDCH, RINGING IN EARS, INSOMNIA,
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Name: ING 9:TREMBLING, UNSTEADY GAIT, VERTIGO, CLOUDED & DOUBLE VISION, SEV
EYE DMG. LONG-TERM RPTD ORAL EXPOS MAY
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Name: ING 10:RSLT IN PROGRESSIVE LIVER INJURY W/FIBROSIS. RPTD INGEST BY
PREGNANT MOTHERS PRDCES FETAL ALCOHOL
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Name: ING 11:SYNDROME. MENTAL & PHYSICAL RETARDATION, DISTURB OF LEARNING,
MOTOR & LANGUAGE DEFICIENCIES, BEHAVIORAL
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Name: ING 12:DISORDERS, & SMALL SIZE HEAD OF CHILD.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INGEST:NAUS, ABDOM PAIN, VOMIT, HDCH, DIZZ,
FAINTNESS, DROW, DECR AWARENESS & RESPONSIVENESS, EUPHORIA, STAGG GAIT,
LACK OF COORDINATION, SHORTNESS OF BREATH, WEAK, FATG, LEG CRAMPS,
RESTLESSNES S, CONFUSN, DRUNKEN BEHAVIOR, VISUAL DISTURB, COMA & DEATH.
MAY BE DELAY OF SEVERAL HRS, SIGNS & SYMPS.(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:ACIDOSIS, CEREBRAL EDEMA, BLURRED
VISION, RESTRICTION OF VISUAL FIELDS, & COMPLETE BLINDNESS. 60-200 ML OF
METHANOL IS FATAL DOSE FOR MOST ADULTS. INGEST OF AS LITTLE AS 10 ML HAS
CAUSED BLND NESS. W/MASSIVE OVERDOSES, LIVER, KIDNEY, & HEART MUSCLE
INJURY. SKIN ABSORP:MAY RSLT IN ABSORP OF HARMFUL AMTS.(SUPDAT)
Medical Cond Aggravated By Exposure: MAY AGGRAVATE AN EXISTING SKIN CONDITION,
MAY EXACERBATE EXISTING LIVER AND/OR KIDNEY DISEASES.
First Aid: INGEST:IF PATIENT IS FULLY CONSCIOUS, GIVE 2 GLASSES OF WATER.
INDUCE VOMIT. OBTAIN MED ATTN W/OUT DELAY. IF MED ADVICE IS DELAYED, GIVE 3-4
OUNCES OF HARD LIQUOR, SUCH AS WHISKEY. SKIN:REMOVE CONTAMD CLTHG &
FLUSH W/WATER. INHAL:REMOVE TOFRESH AIR. GIVE ARTF RESP IF NOT BRTHG. OBTAIN
MED ATTN. EYES:IMMED FLUSH THOROUGHLY W/WATER & CONTINUE WASHING FOR @
LST 15 MINS. OBTAIN MED ATTN.
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Handling and Disposal
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Spill Release Procedures: EXTINGUISH & DO NOT RUN ON ANY IGNIT SOURCE UNTIL
AREA IS DETERMINED TO BE FREE FROM EXPLO OR FIRE HAZARDS. WEAR SUITABLE PROT
EQUIP. COLLECT LG SPILLS FOR DISP. FLUSH SM SPILLS W/WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: DANGER! MAY BE FATAL OR CAUSE BLINDNESS IF
SWALLOWED. FLAMMABLE. VAP HARMFUL. KEEP AWAY FROM HEAT, SPARKS & FLAME.
KEEP CNTNR CLSD. USE W/ADEQ VENT.
Other Precautions: FOR INDUSTRY USE ONLY. VAPS/MISTS FROM PROCESS EQUIP
OPERATING @ ELEVATED TEMP/AIR INTO VACUUM EQUIP, MAY RSLT IN IGNIT.
"AUTOIGNIT" OR "IGNIT" TEMP VALUES CANNOT BE TREATED AS SAFE IN CHEM
PROCESSES W/OUT ANALYSIS OF ACTUAL PROCESS
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point Text: 61.0F,16.1C
Lower Limits: SEE ING 1
Upper Limits: SEE ING 1
Extinguishing Media: ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAMS FOR LARGE FIRES.
USE CO*2 OR DRY CHEMICAL MEDIA FOR SMALL FIRES.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER SPRAY TO COOL CNTNRS & STRUCTURES. DISPERSE
VAPORS.
Unusual Fire/Explosion Hazard: VAPS MAY TRAVEL & BE IGNITED AT LOCATIONS
DISTANT FROM PROD HNDLG POINT. VAPS MAY SETTLE IN LOW/CONFINED AREAS. MAY
PRDCE FLOATING FIRE HAZ IN EXTREME (SUPDAT)
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Control Measures
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Respiratory Protection: NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IN
HIGH VAPOR CONCENTRATIONS.
Ventilation: PROD SHOULD BE CONFINED W/IN CLSD EQUIP. SPEC, LOC VENT IS NEEDED
@ POINTS WHERE VAPS ARE EXPECTED TO ESCAPE TO
Protective Gloves: NEOPRENE OR PVC COATED GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
CHEMICAL APRON.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: FL PT:61.0F, 16.1C. METH:TCC. FL PT:74.0F,
23.3C. METH:TOC. EXPLO HAZ:FIRE CONDITIONS. EFTS OF OVEREXP:INHAL:MAY CAUSE
DIZZ, DROW, DISTURB OF VISION, & TINGLING, NUMBNESS, BURNING SENSATION IN
THROAT & NOSE, STINGING & WATERING IN EYES, NAUS & VOMIT.
SKIN:REDDENING & DEFAT OF SKIN. EYE:DIZZ, FAINTNESS, DROW,
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Physical/Chemical Properties
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B.P. Text: 171F,77C
M.P/F.P Text: <-130F,<-90
Vapor Pres: 43.6 @ 20C
Vapor Density: 1.5
Spec Gravity: 0.80910(H*2O=1)
Evaporation Rate & Reference: 3.20 (BUTYL ACETATE =1)
Solubility in Water: 100% @ 20C
Appearance and Odor: WATER-WHITE LIQUID; CHARACTERISTIC ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: ALUMINUM, PLASTICS, CONCENTRATED NITRIC AND SULFURIC ACIDS,
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE AND/OR CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ANHYDROL SOLVENT SPECIAL, PM-4081, 190 PROOF
Assigned IND: Y
Company: UNION CARBIDE CHEM & PLASTICS CO INC
Street: 39 OLD RIDGEBURY RD
City: DANBURY CT
Zipcode: 06817-0001
Health Emergency Phone: 800-822-4357
Label Required IND: Y
Date Of Label Review: 06/27/1997
Status Code: C
Label Date: 06/27/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INGEST:NAUS, ABDOM PAIN, VOMIT, HDCH, DIZZ,
FAINTNESS, DROW, DECR AWARENESS & RESPONSIVENESS, EUPHORIA, STAGG GAIT,
LACK OF COORDINATION, SHORTNESS OF BREATH, WEAK, FATG, LEG CRAMPS,
RESTLESSNES S, CONFUSN, DRUNKEN BEHAVIOR, VISUAL DISTURB, COMA & DEATH.
SKIN CONT:MAY CAUSE REDDENING AND DEFATTING. MAY BE ABSORBED THRU ABRADED
SKIN. EYE CONT:MAY CAUSE DIZZINESS, FAINTNESS, NAUSEA, VOMITING, I NCOORD AND
COMA. LIQUID MAY CAUSE REDNESS AND SWELLING. INHAL:MAY CAUSE DIZZ,
DROWSINESS, TINGLING AND NUMBNESS OF ARMS, NAUSEA & VOMITING.
CHRONIC:REPEATED OVEREXPOSURE CAN CAUSE CUMULATIVE EFFECT & MAY RESULT
IN EYE AND LUNG DAMAGE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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